Distribution and Origin of Organotin Species in Seawater of the Seto Inland Sea, Japan

Organotin species in seawater, collected by using a ferry between Osaka and Beppu, were determined by gas chromatography combined with inductively coupled plasma mass spectrometry after the ethylation with sodium tetraethylborate. Distributions of 9 organotin species below 1 ng Sn/l in the Seto Inla...

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Veröffentlicht in:Journal of Environmental Chemistry 1999/09/17, Vol.9(3), pp.661-671
Hauptverfasser: TAO, Hiroaki, RAJENDRAN, Ramaswamy Babu, NAGANAWA, Ryuichi, NAKAZATO, Tetsuya, MIYAZAKI, Akira, KUNUGI, Masayuki, HARASHIMA, Akira
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container_end_page 671
container_issue 3
container_start_page 661
container_title Journal of Environmental Chemistry
container_volume 9
creator TAO, Hiroaki
RAJENDRAN, Ramaswamy Babu
NAGANAWA, Ryuichi
NAKAZATO, Tetsuya
MIYAZAKI, Akira
KUNUGI, Masayuki
HARASHIMA, Akira
description Organotin species in seawater, collected by using a ferry between Osaka and Beppu, were determined by gas chromatography combined with inductively coupled plasma mass spectrometry after the ethylation with sodium tetraethylborate. Distributions of 9 organotin species below 1 ng Sn/l in the Seto Inland Sea were clarified for the first time. The concentrations of tributyltin (TBT) and triphenyltin (TPhT) were in the range of 0.21-1.02 ng Sn/l and 0.021.0.096 ng Sn/l, respectively. Three unknown species among them were identified as mono-, di-, and tri-octyltin species, which were used as plastic stabilizers. Butyltin and phenyltin species except for TPhT were found to occur as dissolved form, but di- and tri-octyltin species were found to occur as particular form. Principal component analysis revealed the origin of pollution at each sampling station, i.e., whether it come from antifouling paints or from plastic stabilizers.
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subjects GC-ICP-MS
Organotin
Seawater
Seto Inland Sea
TBT
title Distribution and Origin of Organotin Species in Seawater of the Seto Inland Sea, Japan
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