Distribution and Origin of Organotin Species in Seawater of the Seto Inland Sea, Japan
Organotin species in seawater, collected by using a ferry between Osaka and Beppu, were determined by gas chromatography combined with inductively coupled plasma mass spectrometry after the ethylation with sodium tetraethylborate. Distributions of 9 organotin species below 1 ng Sn/l in the Seto Inla...
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Veröffentlicht in: | Journal of Environmental Chemistry 1999/09/17, Vol.9(3), pp.661-671 |
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container_title | Journal of Environmental Chemistry |
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creator | TAO, Hiroaki RAJENDRAN, Ramaswamy Babu NAGANAWA, Ryuichi NAKAZATO, Tetsuya MIYAZAKI, Akira KUNUGI, Masayuki HARASHIMA, Akira |
description | Organotin species in seawater, collected by using a ferry between Osaka and Beppu, were determined by gas chromatography combined with inductively coupled plasma mass spectrometry after the ethylation with sodium tetraethylborate. Distributions of 9 organotin species below 1 ng Sn/l in the Seto Inland Sea were clarified for the first time. The concentrations of tributyltin (TBT) and triphenyltin (TPhT) were in the range of 0.21-1.02 ng Sn/l and 0.021.0.096 ng Sn/l, respectively. Three unknown species among them were identified as mono-, di-, and tri-octyltin species, which were used as plastic stabilizers. Butyltin and phenyltin species except for TPhT were found to occur as dissolved form, but di- and tri-octyltin species were found to occur as particular form. Principal component analysis revealed the origin of pollution at each sampling station, i.e., whether it come from antifouling paints or from plastic stabilizers. |
doi_str_mv | 10.5985/jec.9.661 |
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Distributions of 9 organotin species below 1 ng Sn/l in the Seto Inland Sea were clarified for the first time. The concentrations of tributyltin (TBT) and triphenyltin (TPhT) were in the range of 0.21-1.02 ng Sn/l and 0.021.0.096 ng Sn/l, respectively. Three unknown species among them were identified as mono-, di-, and tri-octyltin species, which were used as plastic stabilizers. Butyltin and phenyltin species except for TPhT were found to occur as dissolved form, but di- and tri-octyltin species were found to occur as particular form. 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Distributions of 9 organotin species below 1 ng Sn/l in the Seto Inland Sea were clarified for the first time. The concentrations of tributyltin (TBT) and triphenyltin (TPhT) were in the range of 0.21-1.02 ng Sn/l and 0.021.0.096 ng Sn/l, respectively. Three unknown species among them were identified as mono-, di-, and tri-octyltin species, which were used as plastic stabilizers. Butyltin and phenyltin species except for TPhT were found to occur as dissolved form, but di- and tri-octyltin species were found to occur as particular form. Principal component analysis revealed the origin of pollution at each sampling station, i.e., whether it come from antifouling paints or from plastic stabilizers.</description><subject>GC-ICP-MS</subject><subject>Organotin</subject><subject>Seawater</subject><subject>Seto Inland Sea</subject><subject>TBT</subject><issn>0917-2408</issn><issn>1882-5818</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNo9kEtPwzAQhC0EElXpgX-QKxIp3o2dxMeqvIoq9cDjajnupnVVkso2Qvx7HIp6WO2O5ps9DGPXwKdS1fJuR3aqpmUJZ2wEdY25rKE-ZyOuoMpR8PqSTUJwDeeIWCHAiH3cuxC9a76i67vMdOts5d3GdVnfpmtjuj4m8Xog6yhkw0nm20TyAxC3lHTss0W3H6LJu81ezMF0V-yiNftAk_89Zu-PD2_z53y5elrMZ8vcIgrIkWxbCSzJqKppChKl4IqrgkMriIBkIwRgs0aBksTalChBCSxsLYRsTVuM2c3xr_V9CJ5affDu0_gfDVwPnejUiVY6dZLY2ZHdhWg2dCKNj87uaSBBKUh08Tcpc_Ls1nhNXfEL3vdqzA</recordid><startdate>1999</startdate><enddate>1999</enddate><creator>TAO, Hiroaki</creator><creator>RAJENDRAN, Ramaswamy Babu</creator><creator>NAGANAWA, Ryuichi</creator><creator>NAKAZATO, Tetsuya</creator><creator>MIYAZAKI, Akira</creator><creator>KUNUGI, Masayuki</creator><creator>HARASHIMA, Akira</creator><general>Japan Society for Environmental Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>1999</creationdate><title>Distribution and Origin of Organotin Species in Seawater of the Seto Inland Sea, Japan</title><author>TAO, Hiroaki ; RAJENDRAN, Ramaswamy Babu ; NAGANAWA, Ryuichi ; NAKAZATO, Tetsuya ; MIYAZAKI, Akira ; KUNUGI, Masayuki ; HARASHIMA, Akira</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2241-2ecf7426ea97bb3e4640909301f4ee1e5b4412bd2425e4da62519423c8445faf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>GC-ICP-MS</topic><topic>Organotin</topic><topic>Seawater</topic><topic>Seto Inland Sea</topic><topic>TBT</topic><toplevel>online_resources</toplevel><creatorcontrib>TAO, Hiroaki</creatorcontrib><creatorcontrib>RAJENDRAN, Ramaswamy Babu</creatorcontrib><creatorcontrib>NAGANAWA, Ryuichi</creatorcontrib><creatorcontrib>NAKAZATO, Tetsuya</creatorcontrib><creatorcontrib>MIYAZAKI, Akira</creatorcontrib><creatorcontrib>KUNUGI, Masayuki</creatorcontrib><creatorcontrib>HARASHIMA, Akira</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of Environmental Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>TAO, Hiroaki</au><au>RAJENDRAN, Ramaswamy Babu</au><au>NAGANAWA, Ryuichi</au><au>NAKAZATO, Tetsuya</au><au>MIYAZAKI, Akira</au><au>KUNUGI, Masayuki</au><au>HARASHIMA, Akira</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Distribution and Origin of Organotin Species in Seawater of the Seto Inland Sea, Japan</atitle><jtitle>Journal of Environmental Chemistry</jtitle><addtitle>JEC</addtitle><date>1999</date><risdate>1999</risdate><volume>9</volume><issue>3</issue><spage>661</spage><epage>671</epage><pages>661-671</pages><issn>0917-2408</issn><eissn>1882-5818</eissn><abstract>Organotin species in seawater, collected by using a ferry between Osaka and Beppu, were determined by gas chromatography combined with inductively coupled plasma mass spectrometry after the ethylation with sodium tetraethylborate. Distributions of 9 organotin species below 1 ng Sn/l in the Seto Inland Sea were clarified for the first time. The concentrations of tributyltin (TBT) and triphenyltin (TPhT) were in the range of 0.21-1.02 ng Sn/l and 0.021.0.096 ng Sn/l, respectively. Three unknown species among them were identified as mono-, di-, and tri-octyltin species, which were used as plastic stabilizers. Butyltin and phenyltin species except for TPhT were found to occur as dissolved form, but di- and tri-octyltin species were found to occur as particular form. Principal component analysis revealed the origin of pollution at each sampling station, i.e., whether it come from antifouling paints or from plastic stabilizers.</abstract><pub>Japan Society for Environmental Chemistry</pub><doi>10.5985/jec.9.661</doi><tpages>11</tpages><oa>free_for_read</oa></addata></record> |
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subjects | GC-ICP-MS Organotin Seawater Seto Inland Sea TBT |
title | Distribution and Origin of Organotin Species in Seawater of the Seto Inland Sea, Japan |
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