Gemini Quaternary Ammonium Surfactants with Different Counterions-modified Montmorillonite for Efficient Removal of Methyl Orange

Organic Na-montmorillonite (OMt-12-2-12·2Y – , Y=CH 3 CO 3 – , C 6 H 5 COO – and Br – ) modified by a series of Gemini quaternary ammonium surfactants with different counterions was prepared for enhancing the adsorption capacity of methyl orange. Compared with the initial adsorption capacity of 5.25...

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Veröffentlicht in:Journal of Oleo Science 2024, Vol.73(3), pp.341-350
Hauptverfasser: Mo, Yuanhua, Cao, Runyu, Hu, Siqi, Guan, Bowen, Fu, Duojiao, Liu, Hongqin, Xu, Baocai, Xiao, Yang
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container_issue 3
container_start_page 341
container_title Journal of Oleo Science
container_volume 73
creator Mo, Yuanhua
Cao, Runyu
Hu, Siqi
Guan, Bowen
Fu, Duojiao
Liu, Hongqin
Xu, Baocai
Xiao, Yang
description Organic Na-montmorillonite (OMt-12-2-12·2Y – , Y=CH 3 CO 3 – , C 6 H 5 COO – and Br – ) modified by a series of Gemini quaternary ammonium surfactants with different counterions was prepared for enhancing the adsorption capacity of methyl orange. Compared with the initial adsorption capacity of 5.251 mg/g of Na-Mt, the adsorption effect of OMts under the optimal conditions increased by about 31~34 times. The adsorption isotherms and kinetics of all adsorption processes were respectively described by Langmuir and pseudo-second-order models. The structure, hydrophobicity and hydration of the counterions, as well as the affinity of the counterions with the long aliphatic chains, had a certain influence on the adsorption performance of OMts for methyl orange.
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subjects Adsorption
Azo Compounds
Bentonite
counterion
methyl orange
modified montmorillonite
Quaternary Ammonium Compounds
title Gemini Quaternary Ammonium Surfactants with Different Counterions-modified Montmorillonite for Efficient Removal of Methyl Orange
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