Gemini Quaternary Ammonium Surfactants with Different Counterions-modified Montmorillonite for Efficient Removal of Methyl Orange
Organic Na-montmorillonite (OMt-12-2-12·2Y – , Y=CH 3 CO 3 – , C 6 H 5 COO – and Br – ) modified by a series of Gemini quaternary ammonium surfactants with different counterions was prepared for enhancing the adsorption capacity of methyl orange. Compared with the initial adsorption capacity of 5.25...
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Veröffentlicht in: | Journal of Oleo Science 2024, Vol.73(3), pp.341-350 |
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creator | Mo, Yuanhua Cao, Runyu Hu, Siqi Guan, Bowen Fu, Duojiao Liu, Hongqin Xu, Baocai Xiao, Yang |
description | Organic Na-montmorillonite (OMt-12-2-12·2Y – , Y=CH 3 CO 3 – , C 6 H 5 COO – and Br – ) modified by a series of Gemini quaternary ammonium surfactants with different counterions was prepared for enhancing the adsorption capacity of methyl orange. Compared with the initial adsorption capacity of 5.251 mg/g of Na-Mt, the adsorption effect of OMts under the optimal conditions increased by about 31~34 times. The adsorption isotherms and kinetics of all adsorption processes were respectively described by Langmuir and pseudo-second-order models. The structure, hydrophobicity and hydration of the counterions, as well as the affinity of the counterions with the long aliphatic chains, had a certain influence on the adsorption performance of OMts for methyl orange. |
doi_str_mv | 10.5650/jos.ess23174 |
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Compared with the initial adsorption capacity of 5.251 mg/g of Na-Mt, the adsorption effect of OMts under the optimal conditions increased by about 31~34 times. The adsorption isotherms and kinetics of all adsorption processes were respectively described by Langmuir and pseudo-second-order models. The structure, hydrophobicity and hydration of the counterions, as well as the affinity of the counterions with the long aliphatic chains, had a certain influence on the adsorption performance of OMts for methyl orange.</description><identifier>ISSN: 1345-8957</identifier><identifier>EISSN: 1347-3352</identifier><identifier>DOI: 10.5650/jos.ess23174</identifier><identifier>PMID: 38432998</identifier><language>eng</language><publisher>Japan: Japan Oil Chemists' Society</publisher><subject>Adsorption ; Azo Compounds ; Bentonite ; counterion ; methyl orange ; modified montmorillonite ; Quaternary Ammonium Compounds</subject><ispartof>Journal of Oleo Science, 2024, Vol.73(3), pp.341-350</ispartof><rights>2024 by Japan Oil Chemists' Society</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c411t-c65bd7a236c34c88a325d42facef792cd200b9e10fa40a332bb52b1c84fb3cba3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,864,1881,4022,27922,27923,27924</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38432998$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Mo, Yuanhua</creatorcontrib><creatorcontrib>Cao, Runyu</creatorcontrib><creatorcontrib>Hu, Siqi</creatorcontrib><creatorcontrib>Guan, Bowen</creatorcontrib><creatorcontrib>Fu, Duojiao</creatorcontrib><creatorcontrib>Liu, Hongqin</creatorcontrib><creatorcontrib>Xu, Baocai</creatorcontrib><creatorcontrib>Xiao, Yang</creatorcontrib><title>Gemini Quaternary Ammonium Surfactants with Different Counterions-modified Montmorillonite for Efficient Removal of Methyl Orange</title><title>Journal of Oleo Science</title><addtitle>J Oleo Sci</addtitle><description>Organic Na-montmorillonite (OMt-12-2-12·2Y – , Y=CH 3 CO 3 – , C 6 H 5 COO – and Br – ) modified by a series of Gemini quaternary ammonium surfactants with different counterions was prepared for enhancing the adsorption capacity of methyl orange. Compared with the initial adsorption capacity of 5.251 mg/g of Na-Mt, the adsorption effect of OMts under the optimal conditions increased by about 31~34 times. The adsorption isotherms and kinetics of all adsorption processes were respectively described by Langmuir and pseudo-second-order models. The structure, hydrophobicity and hydration of the counterions, as well as the affinity of the counterions with the long aliphatic chains, had a certain influence on the adsorption performance of OMts for methyl orange.</description><subject>Adsorption</subject><subject>Azo Compounds</subject><subject>Bentonite</subject><subject>counterion</subject><subject>methyl orange</subject><subject>modified montmorillonite</subject><subject>Quaternary Ammonium Compounds</subject><issn>1345-8957</issn><issn>1347-3352</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNo9kE1PwzAMhiME4vvGGeUHUEiTZm2PMD6lTRNf5ypNHZapSVCSgjjyz8k2tott2Y9f2S9CZzm55CNOrhYuXEIIlOVlsYMOc1aUGWOc7q5qnlU1Lw_QUQgLQlKfl_vogFUFo3VdHaLfBzDaavw8iAjeCv-Dr41xVg8Gvw5eCRmFjQF_6zjHt1op8GAjHrvBJl47GzLjOq00dHjqbDTO675P-xGwch7fKaWlXq68gHFfosdO4SnE-U-PZ17YDzhBe0r0AU7_8zF6v797Gz9mk9nD0_h6kskiz2MmR7ztSkHZSLJCVpVglHcFTQeCKmsqO0pIW0NOlCiIYIy2LadtLqtCtUy2gh2ji7Wu9C4ED6r59Nqkh5ucNEsnm-Rks3Ey4edr_HNoDXRbeGNdAm7WwCJE8QFbQPioZQ8rtZI1bBk2qtuhnAvfgGV_RXSMow</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Mo, Yuanhua</creator><creator>Cao, Runyu</creator><creator>Hu, Siqi</creator><creator>Guan, Bowen</creator><creator>Fu, Duojiao</creator><creator>Liu, Hongqin</creator><creator>Xu, Baocai</creator><creator>Xiao, Yang</creator><general>Japan Oil Chemists' Society</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2024</creationdate><title>Gemini Quaternary Ammonium Surfactants with Different Counterions-modified Montmorillonite for Efficient Removal of Methyl Orange</title><author>Mo, Yuanhua ; Cao, Runyu ; Hu, Siqi ; Guan, Bowen ; Fu, Duojiao ; Liu, Hongqin ; Xu, Baocai ; Xiao, Yang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c411t-c65bd7a236c34c88a325d42facef792cd200b9e10fa40a332bb52b1c84fb3cba3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Adsorption</topic><topic>Azo Compounds</topic><topic>Bentonite</topic><topic>counterion</topic><topic>methyl orange</topic><topic>modified montmorillonite</topic><topic>Quaternary Ammonium Compounds</topic><toplevel>online_resources</toplevel><creatorcontrib>Mo, Yuanhua</creatorcontrib><creatorcontrib>Cao, Runyu</creatorcontrib><creatorcontrib>Hu, Siqi</creatorcontrib><creatorcontrib>Guan, Bowen</creatorcontrib><creatorcontrib>Fu, Duojiao</creatorcontrib><creatorcontrib>Liu, Hongqin</creatorcontrib><creatorcontrib>Xu, Baocai</creatorcontrib><creatorcontrib>Xiao, Yang</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Journal of Oleo Science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mo, Yuanhua</au><au>Cao, Runyu</au><au>Hu, Siqi</au><au>Guan, Bowen</au><au>Fu, Duojiao</au><au>Liu, Hongqin</au><au>Xu, Baocai</au><au>Xiao, Yang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Gemini Quaternary Ammonium Surfactants with Different Counterions-modified Montmorillonite for Efficient Removal of Methyl Orange</atitle><jtitle>Journal of Oleo Science</jtitle><addtitle>J Oleo Sci</addtitle><date>2024</date><risdate>2024</risdate><volume>73</volume><issue>3</issue><spage>341</spage><epage>350</epage><pages>341-350</pages><artnum>ess23174</artnum><issn>1345-8957</issn><eissn>1347-3352</eissn><abstract>Organic Na-montmorillonite (OMt-12-2-12·2Y – , Y=CH 3 CO 3 – , C 6 H 5 COO – and Br – ) modified by a series of Gemini quaternary ammonium surfactants with different counterions was prepared for enhancing the adsorption capacity of methyl orange. Compared with the initial adsorption capacity of 5.251 mg/g of Na-Mt, the adsorption effect of OMts under the optimal conditions increased by about 31~34 times. The adsorption isotherms and kinetics of all adsorption processes were respectively described by Langmuir and pseudo-second-order models. The structure, hydrophobicity and hydration of the counterions, as well as the affinity of the counterions with the long aliphatic chains, had a certain influence on the adsorption performance of OMts for methyl orange.</abstract><cop>Japan</cop><pub>Japan Oil Chemists' Society</pub><pmid>38432998</pmid><doi>10.5650/jos.ess23174</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Adsorption Azo Compounds Bentonite counterion methyl orange modified montmorillonite Quaternary Ammonium Compounds |
title | Gemini Quaternary Ammonium Surfactants with Different Counterions-modified Montmorillonite for Efficient Removal of Methyl Orange |
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