IR and 1H NMR Spectral Studies of some 2-Amino-4-Isopropyl-6-Methoxy-N-Phenylpyrimidine-5-Carboxamides: Assessment of Substituent Effects
A series of 2-Amino-4-isopropyl-6-methoxy-N-phenylpyrimidine-5-carboxamide compounds have been synthesized from various substituted dithioacetal and guanidine. The purities of these compounds were checked by their physical constants, UV, IR, NMR and MASS spectral data. The IR and 1 HNMR spectral dat...
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Veröffentlicht in: | International letters of chemistry, physics and astronomy physics and astronomy, 2014-09, Vol.38, p.15-25 |
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container_title | International letters of chemistry, physics and astronomy |
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creator | Arulkumaran, R. Sundararajan, R. Manikandan, V. Sathiyendiran, V. Pazhamalai, S. Thirunarayanan, Ganesamoorthy |
description | A series of 2-Amino-4-isopropyl-6-methoxy-N-phenylpyrimidine-5-carboxamide compounds have been synthesized from various substituted dithioacetal and guanidine. The purities of these compounds were checked by their physical constants, UV, IR, NMR and MASS spectral data. The IR and
1
HNMR spectral data of these compounds have been correlated with Hammett sigma constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effects of substituents on the spectral group frequencies have been discussed. |
doi_str_mv | 10.56431/p-30khe3 |
format | Article |
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1
HNMR spectral data of these compounds have been correlated with Hammett sigma constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effects of substituents on the spectral group frequencies have been discussed.</description><identifier>ISSN: 2299-3843</identifier><identifier>EISSN: 2299-3843</identifier><identifier>DOI: 10.56431/p-30khe3</identifier><language>eng</language><ispartof>International letters of chemistry, physics and astronomy, 2014-09, Vol.38, p.15-25</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c743-7430ecd2e069ba358189eac264d319a28ea958918746381568661b5af7ad10df3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27926,27927</link.rule.ids></links><search><creatorcontrib>Arulkumaran, R.</creatorcontrib><creatorcontrib>Sundararajan, R.</creatorcontrib><creatorcontrib>Manikandan, V.</creatorcontrib><creatorcontrib>Sathiyendiran, V.</creatorcontrib><creatorcontrib>Pazhamalai, S.</creatorcontrib><creatorcontrib>Thirunarayanan, Ganesamoorthy</creatorcontrib><title>IR and 1H NMR Spectral Studies of some 2-Amino-4-Isopropyl-6-Methoxy-N-Phenylpyrimidine-5-Carboxamides: Assessment of Substituent Effects</title><title>International letters of chemistry, physics and astronomy</title><description>A series of 2-Amino-4-isopropyl-6-methoxy-N-phenylpyrimidine-5-carboxamide compounds have been synthesized from various substituted dithioacetal and guanidine. The purities of these compounds were checked by their physical constants, UV, IR, NMR and MASS spectral data. The IR and
1
HNMR spectral data of these compounds have been correlated with Hammett sigma constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effects of substituents on the spectral group frequencies have been discussed.</description><issn>2299-3843</issn><issn>2299-3843</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpNUM1OwkAY3BhNJMjBN9irh9Xd7g-73ghBIUE0wL3Ztl9Dte02_UpCH8G3togHD5OZucxMhpB7wR-1UVI8NUzyrwPIKzKKIueYtEpe_9O3ZIL4yTkXkXZCqRH5Xm2przMqlnTztqW7BtKu9SXddcesAKQhpxgqoBGbVUUdmGIrDE0bmr5khr1Bdwinnm3YxwHqvmz6tqiKrKiBaTb3bRJOfvCAz3SGCIgV1N05c3dMsCu649ku8nwoxTtyk_sSYfLHY7J_WeznS7Z-f13NZ2uWTpVkAzikWQTcuMRLbYV14NPIqEwK5yML3mnrhJ0qI63QxhojEu3zqc8Ez3I5Jg-X2LQNiC3kcTNs9m0fCx7_vhg38eVF-QODnmVD</recordid><startdate>20140903</startdate><enddate>20140903</enddate><creator>Arulkumaran, R.</creator><creator>Sundararajan, R.</creator><creator>Manikandan, V.</creator><creator>Sathiyendiran, V.</creator><creator>Pazhamalai, S.</creator><creator>Thirunarayanan, Ganesamoorthy</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20140903</creationdate><title>IR and 1H NMR Spectral Studies of some 2-Amino-4-Isopropyl-6-Methoxy-N-Phenylpyrimidine-5-Carboxamides: Assessment of Substituent Effects</title><author>Arulkumaran, R. ; Sundararajan, R. ; Manikandan, V. ; Sathiyendiran, V. ; Pazhamalai, S. ; Thirunarayanan, Ganesamoorthy</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c743-7430ecd2e069ba358189eac264d319a28ea958918746381568661b5af7ad10df3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Arulkumaran, R.</creatorcontrib><creatorcontrib>Sundararajan, R.</creatorcontrib><creatorcontrib>Manikandan, V.</creatorcontrib><creatorcontrib>Sathiyendiran, V.</creatorcontrib><creatorcontrib>Pazhamalai, S.</creatorcontrib><creatorcontrib>Thirunarayanan, Ganesamoorthy</creatorcontrib><collection>CrossRef</collection><jtitle>International letters of chemistry, physics and astronomy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Arulkumaran, R.</au><au>Sundararajan, R.</au><au>Manikandan, V.</au><au>Sathiyendiran, V.</au><au>Pazhamalai, S.</au><au>Thirunarayanan, Ganesamoorthy</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>IR and 1H NMR Spectral Studies of some 2-Amino-4-Isopropyl-6-Methoxy-N-Phenylpyrimidine-5-Carboxamides: Assessment of Substituent Effects</atitle><jtitle>International letters of chemistry, physics and astronomy</jtitle><date>2014-09-03</date><risdate>2014</risdate><volume>38</volume><spage>15</spage><epage>25</epage><pages>15-25</pages><issn>2299-3843</issn><eissn>2299-3843</eissn><abstract>A series of 2-Amino-4-isopropyl-6-methoxy-N-phenylpyrimidine-5-carboxamide compounds have been synthesized from various substituted dithioacetal and guanidine. The purities of these compounds were checked by their physical constants, UV, IR, NMR and MASS spectral data. The IR and
1
HNMR spectral data of these compounds have been correlated with Hammett sigma constants, F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effects of substituents on the spectral group frequencies have been discussed.</abstract><doi>10.56431/p-30khe3</doi><tpages>11</tpages></addata></record> |
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title | IR and 1H NMR Spectral Studies of some 2-Amino-4-Isopropyl-6-Methoxy-N-Phenylpyrimidine-5-Carboxamides: Assessment of Substituent Effects |
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