Organometallic Lewis Acids, Part LVIIII [1]. Directed Synthesis of Dinuclear Metal Carbonyl Complexes of Rhenium, Iron, Chromium, and Tungsten with a Single Unsupported Halide or Pseudohalide Bridge (Cl - , Br - , I - , CN - , C(CN) 3 - , NCS - , PPh 2 - , SH - ) by Use of Re(CO) 5 FBF 3

Organometallic Lewis Acids, Part LVIIII [1]. Directed Synthesis of Dinuclear Metal Carbonyl Complexes of Rhenium, Iron, Chromium, and Tungsten with a Single Unsupported Halide or Pseudohalide Bridge (Cl - , Br - , I - , CN - , C(CN) 3 - , NCS - , PPh 2 - , SH - ) by Use of Re(CO) 5 FBF 3

By use of Re(CO) 5 FBF 3 the complexes with a single unsupported halide or pseudohalide bridge [Cp(OC) 2 Fe-X-Re(CO) 5 ] + BF 4 - (X=Cl, I, PPh 2 ), (OC) 5 M-X-Re(CO) 5 (M=Cr, W; X=Br, I, CN, NCS, SH), (OC)5W-N≡C-C[-C≡N-Re(CO) 5 ] 2 + BF 4 - , Cp(OC)(NC)Fe-C≡N-Re(CO) 5 , and [(OC) 5 Re-N 3 -Re(CO) 5...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2014-12, Vol.69 (11-12), p.1215-1220
Hauptverfasser: Fritz, Peter M., Sacher, Wolfgang, Beck, Wolfgang
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container_title Zeitschrift für Naturforschung. B, A journal of chemical sciences
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creator Fritz, Peter M.
Sacher, Wolfgang
Beck, Wolfgang
description By use of Re(CO) 5 FBF 3 the complexes with a single unsupported halide or pseudohalide bridge [Cp(OC) 2 Fe-X-Re(CO) 5 ] + BF 4 - (X=Cl, I, PPh 2 ), (OC) 5 M-X-Re(CO) 5 (M=Cr, W; X=Br, I, CN, NCS, SH), (OC)5W-N≡C-C[-C≡N-Re(CO) 5 ] 2 + BF 4 - , Cp(OC)(NC)Fe-C≡N-Re(CO) 5 , and [(OC) 5 Re-N 3 -Re(CO) 5 ] + BF 4 - have been synthesized.
doi_str_mv 10.5560/znb.2014-4095
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title Organometallic Lewis Acids, Part LVIIII [1]. Directed Synthesis of Dinuclear Metal Carbonyl Complexes of Rhenium, Iron, Chromium, and Tungsten with a Single Unsupported Halide or Pseudohalide Bridge (Cl - , Br - , I - , CN - , C(CN) 3 - , NCS - , PPh 2 - , SH - ) by Use of Re(CO) 5 FBF 3
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