Hydrogen Evolution from Formic Acid and Hydrodefluorination of Fluoroarenes by Bifunctional Iridium Catalysts—Beyond the Transfer Hydrogenation

A series of half-sandwich ruthenium, rhodium, and iridium complexes with chelating amine ligands have been established as metal-ligand cooperative bifunctional catalysts directed to transfer hydrogenation of ketones. The catalytic functions can be extended to the spontaneous hydrogen evolution from...

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Veröffentlicht in:	Journal of Synthetic Organic Chemistry, Japan Japan, 2018/04/01, Vol.76(4), pp.315-324
Hauptverfasser:	Matsunami, Asuka, Kuwata, Shigeki, Kayaki, Yoshihito
Format:	Artikel
Sprache:	jpn
Schlagworte:	bifunctional catalyst C-F bond cleavage dehydrogenation formic acid hydride hydrodefluorination iridium transfer hydrogenation
Online-Zugang:	Volltext
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