Rh (I) -catalyzed Cyclizations via Rhodacycle Intermediates : Application to the Synthesis of (±) -Epiglobulol

Rh (I)-catalyzed hydroacylation of 4, 6-dienals proceeded smoothly, giving cycloheptenone derivatives. It was found that the size of the ring formed in this hydroacylation was dependent on the presence of a substituent at C 7 position and the geometry of the olefin. During ongoing investigation of t...

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Veröffentlicht in:	Journal of Synthetic Organic Chemistry, Japan Japan, 2007/03/01, Vol.65(3), pp.183-193
Hauptverfasser:	Oonishi, Yoshihiro, Mori, Miwako, Sato, Yoshihiro
Format:	Artikel
Sprache:	eng ; jpn
Schlagworte:	aldehyde alkene apoaromadendrone cascade reaction cycloisomerization diene epiglobulol hydroacylation rhodium
Online-Zugang:	Volltext
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