Degradation of sulfamethoxazole antibacterial by sono-Fenton process using nano-zero valent iron: influence factors, kinetic and toxicity bioassay
This study investigated the efficiency of sono-nano Fenton process in the degradation of sulfamethoxazole (SMX) antibacterial in aqueous solution. The effect of ultrasonic frequency, initial pH, the dose of nZVI, SMX concentration and hydrogen peroxide concentration are investigated. The results sho...
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Veröffentlicht in: | Desalination and water treatment 2019-05, Vol.150, p.220-227 |
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description | This study investigated the efficiency of sono-nano Fenton process in the degradation of sulfamethoxazole (SMX) antibacterial in aqueous solution. The effect of ultrasonic frequency, initial pH, the dose of nZVI, SMX concentration and hydrogen peroxide concentration are investigated. The results show that the oxidation power of Fenton system increases by ultrasonic irradiation. The optimum degradation efficiency of SMX was achieved in the condition of 1 mM H2O2, 80 kHz frequency, 1 g/L nZVI, and pH: 3 after 60 min contact with US/Fenton (about 95%). Also, the degradation kinetics and toxicity test for effluent of US/nZVI /H2O2 system in optimal condition were studied. It was shown that degradation of SMX could be described by a first-order kinetic model and the toxicity of treated SMX solution decreases with treatment by sono Fenton system. This study shows that US/Fenton can be used as an effective method for the treatment of polluted water and wastewater with SMX. |
doi_str_mv | 10.5004/dwt.2019.23626 |
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The effect of ultrasonic frequency, initial pH, the dose of nZVI, SMX concentration and hydrogen peroxide concentration are investigated. The results show that the oxidation power of Fenton system increases by ultrasonic irradiation. The optimum degradation efficiency of SMX was achieved in the condition of 1 mM H2O2, 80 kHz frequency, 1 g/L nZVI, and pH: 3 after 60 min contact with US/Fenton (about 95%). Also, the degradation kinetics and toxicity test for effluent of US/nZVI /H2O2 system in optimal condition were studied. It was shown that degradation of SMX could be described by a first-order kinetic model and the toxicity of treated SMX solution decreases with treatment by sono Fenton system. This study shows that US/Fenton can be used as an effective method for the treatment of polluted water and wastewater with SMX.</description><identifier>ISSN: 1944-3986</identifier><identifier>EISSN: 1944-3986</identifier><identifier>DOI: 10.5004/dwt.2019.23626</identifier><language>eng</language><publisher>Elsevier Inc</publisher><subject>Fenton ; H2O2 ; nZVI ; Sulfamethoxazole ; Toxicity test ; Ultrasound</subject><ispartof>Desalination and water treatment, 2019-05, Vol.150, p.220-227</ispartof><rights>2019 Elsevier Inc.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c328t-747f90744b16697e610858b636637d5f1f3da734abfb6d74a048d86130a199443</citedby><cites>FETCH-LOGICAL-c328t-747f90744b16697e610858b636637d5f1f3da734abfb6d74a048d86130a199443</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Rahmani, Hasan</creatorcontrib><creatorcontrib>Rahmani, Ayat</creatorcontrib><creatorcontrib>Yousefi, Masoud</creatorcontrib><creatorcontrib>Rahmani, Kourosh</creatorcontrib><title>Degradation of sulfamethoxazole antibacterial by sono-Fenton process using nano-zero valent iron: influence factors, kinetic and toxicity bioassay</title><title>Desalination and water treatment</title><description>This study investigated the efficiency of sono-nano Fenton process in the degradation of sulfamethoxazole (SMX) antibacterial in aqueous solution. The effect of ultrasonic frequency, initial pH, the dose of nZVI, SMX concentration and hydrogen peroxide concentration are investigated. The results show that the oxidation power of Fenton system increases by ultrasonic irradiation. The optimum degradation efficiency of SMX was achieved in the condition of 1 mM H2O2, 80 kHz frequency, 1 g/L nZVI, and pH: 3 after 60 min contact with US/Fenton (about 95%). Also, the degradation kinetics and toxicity test for effluent of US/nZVI /H2O2 system in optimal condition were studied. It was shown that degradation of SMX could be described by a first-order kinetic model and the toxicity of treated SMX solution decreases with treatment by sono Fenton system. This study shows that US/Fenton can be used as an effective method for the treatment of polluted water and wastewater with SMX.</description><subject>Fenton</subject><subject>H2O2</subject><subject>nZVI</subject><subject>Sulfamethoxazole</subject><subject>Toxicity test</subject><subject>Ultrasound</subject><issn>1944-3986</issn><issn>1944-3986</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kL9OwzAQhyMEElXpyuwHIMWOHSdhQ4UCUiUWmKOL_xRDale2W5o-Bk-MSxlYuOVOsr-f7r4suyR4WmLMruVnnBaYNNOC8oKfZCPSMJbTpuanf-bzbBLCO05VsqpkxSj7ulNLDxKicRY5jcKm17BS8c3tYO96hcBG04GIyhvoUTeg4KzL58rGBKy9EyoEtAnGLpGF9LJX3qEt9OkDMt7ZG2Ss7jfKCoV0ynE-XKEPY1U0IoVLFN3OCBMH1BkHIcBwkZ1p6IOa_PZx9jq_f5k95ovnh6fZ7SIXtKhjXrFKN7hirCOcN5XiBNdl3XHKOa1kqYmmEirKoNMdlxUDzGpZc0IxkCYJoeNseswV3oXglW7X3qzADy3B7UFqm6S2B6ntj9QE1EdApa22Rvk2CHM4TBqvRGylM_-h33YrgKw</recordid><startdate>201905</startdate><enddate>201905</enddate><creator>Rahmani, Hasan</creator><creator>Rahmani, Ayat</creator><creator>Yousefi, Masoud</creator><creator>Rahmani, Kourosh</creator><general>Elsevier Inc</general><scope>6I.</scope><scope>AAFTH</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201905</creationdate><title>Degradation of sulfamethoxazole antibacterial by sono-Fenton process using nano-zero valent iron: influence factors, kinetic and toxicity bioassay</title><author>Rahmani, Hasan ; Rahmani, Ayat ; Yousefi, Masoud ; Rahmani, Kourosh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-747f90744b16697e610858b636637d5f1f3da734abfb6d74a048d86130a199443</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Fenton</topic><topic>H2O2</topic><topic>nZVI</topic><topic>Sulfamethoxazole</topic><topic>Toxicity test</topic><topic>Ultrasound</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rahmani, Hasan</creatorcontrib><creatorcontrib>Rahmani, Ayat</creatorcontrib><creatorcontrib>Yousefi, Masoud</creatorcontrib><creatorcontrib>Rahmani, Kourosh</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>CrossRef</collection><jtitle>Desalination and water treatment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rahmani, Hasan</au><au>Rahmani, Ayat</au><au>Yousefi, Masoud</au><au>Rahmani, Kourosh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Degradation of sulfamethoxazole antibacterial by sono-Fenton process using nano-zero valent iron: influence factors, kinetic and toxicity bioassay</atitle><jtitle>Desalination and water treatment</jtitle><date>2019-05</date><risdate>2019</risdate><volume>150</volume><spage>220</spage><epage>227</epage><pages>220-227</pages><issn>1944-3986</issn><eissn>1944-3986</eissn><abstract>This study investigated the efficiency of sono-nano Fenton process in the degradation of sulfamethoxazole (SMX) antibacterial in aqueous solution. The effect of ultrasonic frequency, initial pH, the dose of nZVI, SMX concentration and hydrogen peroxide concentration are investigated. The results show that the oxidation power of Fenton system increases by ultrasonic irradiation. The optimum degradation efficiency of SMX was achieved in the condition of 1 mM H2O2, 80 kHz frequency, 1 g/L nZVI, and pH: 3 after 60 min contact with US/Fenton (about 95%). Also, the degradation kinetics and toxicity test for effluent of US/nZVI /H2O2 system in optimal condition were studied. It was shown that degradation of SMX could be described by a first-order kinetic model and the toxicity of treated SMX solution decreases with treatment by sono Fenton system. This study shows that US/Fenton can be used as an effective method for the treatment of polluted water and wastewater with SMX.</abstract><pub>Elsevier Inc</pub><doi>10.5004/dwt.2019.23626</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Fenton H2O2 nZVI Sulfamethoxazole Toxicity test Ultrasound |
title | Degradation of sulfamethoxazole antibacterial by sono-Fenton process using nano-zero valent iron: influence factors, kinetic and toxicity bioassay |
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