Synthesis of magnetic Fe3O4/hydroxyapatite nanocomposites and adsorption to Cu2+ ions
In the paper, magnetic Fe3O4/Hydroxyapatite (Fe3O4/HA) nanocomposites were prepared by a mechanical method and an in-situ method. XRD and SEM were used to characterize the microstructure and morphology. The adsorption performance of bare HA as well as the magnetic Fe3O4/HA nanocomposites to Cu2+ ion...
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Veröffentlicht in: | Desalination and water treatment 2019-02, Vol.141, p.229-237 |
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description | In the paper, magnetic Fe3O4/Hydroxyapatite (Fe3O4/HA) nanocomposites were prepared by a mechanical method and an in-situ method. XRD and SEM were used to characterize the microstructure and morphology. The adsorption performance of bare HA as well as the magnetic Fe3O4/HA nanocomposites to Cu2+ ions were investigated and compared. The results showed that the particle size of magnetic Fe3O4/HA nanocomposites synthesized in-situ had a uniform distribution. The crystallinity and the particle size were found to increase with the molar ratio of Fe3O4: HA and the hydrothermal reaction temperature. The magnetic Fe3O4/HA nanocomposites prepared by the two methods both have the ability to absorb Cu2+ ions. The removal efficiency of magnetic Fe3O4/HA nanocomposites in-situ to Cu2+ ions is 95%, higher than those by the mechanical method (91%). The adsorption capacity of Fe3O4/HA in-situ is higher than that mechanically and bare HA. The magnetic Fe3O4/HA nanocomposites can be completely separated by external magnetic field, so it has the potential of practical application in the heavy metal wastewater treatment. |
doi_str_mv | 10.5004/dwt.2019.23475 |
format | Article |
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XRD and SEM were used to characterize the microstructure and morphology. The adsorption performance of bare HA as well as the magnetic Fe3O4/HA nanocomposites to Cu2+ ions were investigated and compared. The results showed that the particle size of magnetic Fe3O4/HA nanocomposites synthesized in-situ had a uniform distribution. The crystallinity and the particle size were found to increase with the molar ratio of Fe3O4: HA and the hydrothermal reaction temperature. The magnetic Fe3O4/HA nanocomposites prepared by the two methods both have the ability to absorb Cu2+ ions. The removal efficiency of magnetic Fe3O4/HA nanocomposites in-situ to Cu2+ ions is 95%, higher than those by the mechanical method (91%). The adsorption capacity of Fe3O4/HA in-situ is higher than that mechanically and bare HA. The magnetic Fe3O4/HA nanocomposites can be completely separated by external magnetic field, so it has the potential of practical application in the heavy metal wastewater treatment.</description><identifier>ISSN: 1944-3986</identifier><identifier>DOI: 10.5004/dwt.2019.23475</identifier><language>eng</language><publisher>Elsevier Inc</publisher><subject>Adsorption ; Cu2 + ions ; Hydroxyapatite ; In-situ synthesis ; Magnetic nanocomposites</subject><ispartof>Desalination and water treatment, 2019-02, Vol.141, p.229-237</ispartof><rights>2019 Elsevier Inc.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c213t-a778507364dad7966cb204eee525b2a95b5fd6c1d7d2ab2bc12747a4438897123</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Hou, Zhaoxia</creatorcontrib><creatorcontrib>Zhang, Chunhan</creatorcontrib><creatorcontrib>Long, Haibo</creatorcontrib><creatorcontrib>Wang, Meihan</creatorcontrib><creatorcontrib>Hu, Xiaodan</creatorcontrib><title>Synthesis of magnetic Fe3O4/hydroxyapatite nanocomposites and adsorption to Cu2+ ions</title><title>Desalination and water treatment</title><description>In the paper, magnetic Fe3O4/Hydroxyapatite (Fe3O4/HA) nanocomposites were prepared by a mechanical method and an in-situ method. XRD and SEM were used to characterize the microstructure and morphology. The adsorption performance of bare HA as well as the magnetic Fe3O4/HA nanocomposites to Cu2+ ions were investigated and compared. The results showed that the particle size of magnetic Fe3O4/HA nanocomposites synthesized in-situ had a uniform distribution. The crystallinity and the particle size were found to increase with the molar ratio of Fe3O4: HA and the hydrothermal reaction temperature. The magnetic Fe3O4/HA nanocomposites prepared by the two methods both have the ability to absorb Cu2+ ions. The removal efficiency of magnetic Fe3O4/HA nanocomposites in-situ to Cu2+ ions is 95%, higher than those by the mechanical method (91%). The adsorption capacity of Fe3O4/HA in-situ is higher than that mechanically and bare HA. The magnetic Fe3O4/HA nanocomposites can be completely separated by external magnetic field, so it has the potential of practical application in the heavy metal wastewater treatment.</description><subject>Adsorption</subject><subject>Cu2 + ions</subject><subject>Hydroxyapatite</subject><subject>In-situ synthesis</subject><subject>Magnetic nanocomposites</subject><issn>1944-3986</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kD1PwzAQhj2ARFW6MntHSf0ZJyOqKCBV6gCdLcd2qBGxI9t85N_jUlZuuXt1ek6nB4AbjGqOEFubr1wThLuaUCb4BVjgjrGKdm1zBVYpvaFSvGwYWYDD8-zz0SaXYBjgqF69zU7DraV7tj7OJobvWU0qu2yhVz7oME4hlZSg8gYqk0Kcsgse5gA3H-QWljldg8tBvSe7-utLcNjev2weq93-4Wlzt6s0wTRXSoiWI0EbZpQRXdPoniBmreWE90R1vOeDaTQ2whDVk15jIphQjNG27QQmdAnq810dQ0rRDnKKblRxlhjJkwtZXMiTC_nrogDtGbDlq09no0zaWa-tcdHqLE1w_6E_kQ9njA</recordid><startdate>201902</startdate><enddate>201902</enddate><creator>Hou, Zhaoxia</creator><creator>Zhang, Chunhan</creator><creator>Long, Haibo</creator><creator>Wang, Meihan</creator><creator>Hu, Xiaodan</creator><general>Elsevier Inc</general><scope>6I.</scope><scope>AAFTH</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201902</creationdate><title>Synthesis of magnetic Fe3O4/hydroxyapatite nanocomposites and adsorption to Cu2+ ions</title><author>Hou, Zhaoxia ; Zhang, Chunhan ; Long, Haibo ; Wang, Meihan ; Hu, Xiaodan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c213t-a778507364dad7966cb204eee525b2a95b5fd6c1d7d2ab2bc12747a4438897123</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Adsorption</topic><topic>Cu2 + ions</topic><topic>Hydroxyapatite</topic><topic>In-situ synthesis</topic><topic>Magnetic nanocomposites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hou, Zhaoxia</creatorcontrib><creatorcontrib>Zhang, Chunhan</creatorcontrib><creatorcontrib>Long, Haibo</creatorcontrib><creatorcontrib>Wang, Meihan</creatorcontrib><creatorcontrib>Hu, Xiaodan</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>CrossRef</collection><jtitle>Desalination and water treatment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hou, Zhaoxia</au><au>Zhang, Chunhan</au><au>Long, Haibo</au><au>Wang, Meihan</au><au>Hu, Xiaodan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of magnetic Fe3O4/hydroxyapatite nanocomposites and adsorption to Cu2+ ions</atitle><jtitle>Desalination and water treatment</jtitle><date>2019-02</date><risdate>2019</risdate><volume>141</volume><spage>229</spage><epage>237</epage><pages>229-237</pages><issn>1944-3986</issn><abstract>In the paper, magnetic Fe3O4/Hydroxyapatite (Fe3O4/HA) nanocomposites were prepared by a mechanical method and an in-situ method. XRD and SEM were used to characterize the microstructure and morphology. The adsorption performance of bare HA as well as the magnetic Fe3O4/HA nanocomposites to Cu2+ ions were investigated and compared. The results showed that the particle size of magnetic Fe3O4/HA nanocomposites synthesized in-situ had a uniform distribution. The crystallinity and the particle size were found to increase with the molar ratio of Fe3O4: HA and the hydrothermal reaction temperature. The magnetic Fe3O4/HA nanocomposites prepared by the two methods both have the ability to absorb Cu2+ ions. The removal efficiency of magnetic Fe3O4/HA nanocomposites in-situ to Cu2+ ions is 95%, higher than those by the mechanical method (91%). The adsorption capacity of Fe3O4/HA in-situ is higher than that mechanically and bare HA. The magnetic Fe3O4/HA nanocomposites can be completely separated by external magnetic field, so it has the potential of practical application in the heavy metal wastewater treatment.</abstract><pub>Elsevier Inc</pub><doi>10.5004/dwt.2019.23475</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Adsorption Cu2 + ions Hydroxyapatite In-situ synthesis Magnetic nanocomposites |
title | Synthesis of magnetic Fe3O4/hydroxyapatite nanocomposites and adsorption to Cu2+ ions |
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