Chronopotentiometric evaluation of enhanced counter-ion transport through anion exchange membranes in electromembrane processes

This paper reports the use of chronopotentiometry as a powerful technique to study counter-ion transport properties through ion-exchange membranes. Chronopotentiometry at current values less, equal and greater than the limiting current density has been used to understand the role of ammonia buffer i...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Desalination and water treatment 2017-06, Vol.78, p.34-40
Hauptverfasser: Zerdoumi, Ridha, Chatta, Hadjer, Mellahi, Dhaouadi, Oulmi, Kafia, Ferhat, Mahmoud, Ourari, Ali
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 40
container_issue
container_start_page 34
container_title Desalination and water treatment
container_volume 78
creator Zerdoumi, Ridha
Chatta, Hadjer
Mellahi, Dhaouadi
Oulmi, Kafia
Ferhat, Mahmoud
Ourari, Ali
description This paper reports the use of chronopotentiometry as a powerful technique to study counter-ion transport properties through ion-exchange membranes. Chronopotentiometry at current values less, equal and greater than the limiting current density has been used to understand the role of ammonia buffer in the reduction and elimination of the concentration polarisation phenomena of ion transport through the Neosepta AMX anion exchange membrane (Tokuyama Soda, Japan). The addition of ammonia led to polarisation chronopotentiograms without transition time. The results show that the water dissociation reaction in the boundary layer is catalytically enhanced by ammonia. It shifted the overlimiting current regions towards the ohmic regions by destruction and elimination of the diffusion boundary layer.
doi_str_mv 10.5004/dwt.2017.20871
format Article
fullrecord <record><control><sourceid>elsevier_cross</sourceid><recordid>TN_cdi_crossref_primary_10_5004_dwt_2017_20871</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S1944398624123168</els_id><sourcerecordid>S1944398624123168</sourcerecordid><originalsourceid>FETCH-LOGICAL-c328t-f061fa385eeaf16aa7ea39bfa0f41742a5230c8c85de3373e3799feffc17ccf53</originalsourceid><addsrcrecordid>eNp1kE1PAyEQhjloYlN79cwf2AoLFPZoGr8SEy96JpQdWkwXNkCrnvzrslaPzmEm82beycyD0BUlS0EIv-7fy7IlVNakJD1DM9px3rBOrS7QIuc3UkNwKXg7Q1_rXYohjrFAKD4OUJK3GI5mfzC1Dzg6DGFngoUe23gIBVIz6SWZkMeYCi51w2G7wyZMOnzYOr0FPMCwqTOQsa_qHmxJ8U_DY4oWcoZ8ic6d2WdY_NY5er27fVk_NE_P94_rm6fGslaVxpEVdYYpAWAcXRkjwbBu4wxxnEreGtEyYpVVogfGJAMmu86Bc5ZKa51gc7Q87bUp5pzA6TH5waRPTYmeqOlKTU_U9A-1alAnA9Srjh6SztbDhMGn-ovuo__P-g3-Q3rK</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Chronopotentiometric evaluation of enhanced counter-ion transport through anion exchange membranes in electromembrane processes</title><source>Alma/SFX Local Collection</source><creator>Zerdoumi, Ridha ; Chatta, Hadjer ; Mellahi, Dhaouadi ; Oulmi, Kafia ; Ferhat, Mahmoud ; Ourari, Ali</creator><creatorcontrib>Zerdoumi, Ridha ; Chatta, Hadjer ; Mellahi, Dhaouadi ; Oulmi, Kafia ; Ferhat, Mahmoud ; Ourari, Ali</creatorcontrib><description>This paper reports the use of chronopotentiometry as a powerful technique to study counter-ion transport properties through ion-exchange membranes. Chronopotentiometry at current values less, equal and greater than the limiting current density has been used to understand the role of ammonia buffer in the reduction and elimination of the concentration polarisation phenomena of ion transport through the Neosepta AMX anion exchange membrane (Tokuyama Soda, Japan). The addition of ammonia led to polarisation chronopotentiograms without transition time. The results show that the water dissociation reaction in the boundary layer is catalytically enhanced by ammonia. It shifted the overlimiting current regions towards the ohmic regions by destruction and elimination of the diffusion boundary layer.</description><identifier>ISSN: 1944-3986</identifier><identifier>DOI: 10.5004/dwt.2017.20871</identifier><language>eng</language><publisher>Elsevier Inc</publisher><subject>Buffer solution ; Chronopotentiometry ; Concentration polarisation ; Counter-ion transport ; Ion-exchange membrane ; Water dissociation</subject><ispartof>Desalination and water treatment, 2017-06, Vol.78, p.34-40</ispartof><rights>2017 Elsevier Inc.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c328t-f061fa385eeaf16aa7ea39bfa0f41742a5230c8c85de3373e3799feffc17ccf53</citedby><cites>FETCH-LOGICAL-c328t-f061fa385eeaf16aa7ea39bfa0f41742a5230c8c85de3373e3799feffc17ccf53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Zerdoumi, Ridha</creatorcontrib><creatorcontrib>Chatta, Hadjer</creatorcontrib><creatorcontrib>Mellahi, Dhaouadi</creatorcontrib><creatorcontrib>Oulmi, Kafia</creatorcontrib><creatorcontrib>Ferhat, Mahmoud</creatorcontrib><creatorcontrib>Ourari, Ali</creatorcontrib><title>Chronopotentiometric evaluation of enhanced counter-ion transport through anion exchange membranes in electromembrane processes</title><title>Desalination and water treatment</title><description>This paper reports the use of chronopotentiometry as a powerful technique to study counter-ion transport properties through ion-exchange membranes. Chronopotentiometry at current values less, equal and greater than the limiting current density has been used to understand the role of ammonia buffer in the reduction and elimination of the concentration polarisation phenomena of ion transport through the Neosepta AMX anion exchange membrane (Tokuyama Soda, Japan). The addition of ammonia led to polarisation chronopotentiograms without transition time. The results show that the water dissociation reaction in the boundary layer is catalytically enhanced by ammonia. It shifted the overlimiting current regions towards the ohmic regions by destruction and elimination of the diffusion boundary layer.</description><subject>Buffer solution</subject><subject>Chronopotentiometry</subject><subject>Concentration polarisation</subject><subject>Counter-ion transport</subject><subject>Ion-exchange membrane</subject><subject>Water dissociation</subject><issn>1944-3986</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kE1PAyEQhjloYlN79cwf2AoLFPZoGr8SEy96JpQdWkwXNkCrnvzrslaPzmEm82beycyD0BUlS0EIv-7fy7IlVNakJD1DM9px3rBOrS7QIuc3UkNwKXg7Q1_rXYohjrFAKD4OUJK3GI5mfzC1Dzg6DGFngoUe23gIBVIz6SWZkMeYCi51w2G7wyZMOnzYOr0FPMCwqTOQsa_qHmxJ8U_DY4oWcoZ8ic6d2WdY_NY5er27fVk_NE_P94_rm6fGslaVxpEVdYYpAWAcXRkjwbBu4wxxnEreGtEyYpVVogfGJAMmu86Bc5ZKa51gc7Q87bUp5pzA6TH5waRPTYmeqOlKTU_U9A-1alAnA9Srjh6SztbDhMGn-ovuo__P-g3-Q3rK</recordid><startdate>201706</startdate><enddate>201706</enddate><creator>Zerdoumi, Ridha</creator><creator>Chatta, Hadjer</creator><creator>Mellahi, Dhaouadi</creator><creator>Oulmi, Kafia</creator><creator>Ferhat, Mahmoud</creator><creator>Ourari, Ali</creator><general>Elsevier Inc</general><scope>6I.</scope><scope>AAFTH</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201706</creationdate><title>Chronopotentiometric evaluation of enhanced counter-ion transport through anion exchange membranes in electromembrane processes</title><author>Zerdoumi, Ridha ; Chatta, Hadjer ; Mellahi, Dhaouadi ; Oulmi, Kafia ; Ferhat, Mahmoud ; Ourari, Ali</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-f061fa385eeaf16aa7ea39bfa0f41742a5230c8c85de3373e3799feffc17ccf53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Buffer solution</topic><topic>Chronopotentiometry</topic><topic>Concentration polarisation</topic><topic>Counter-ion transport</topic><topic>Ion-exchange membrane</topic><topic>Water dissociation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zerdoumi, Ridha</creatorcontrib><creatorcontrib>Chatta, Hadjer</creatorcontrib><creatorcontrib>Mellahi, Dhaouadi</creatorcontrib><creatorcontrib>Oulmi, Kafia</creatorcontrib><creatorcontrib>Ferhat, Mahmoud</creatorcontrib><creatorcontrib>Ourari, Ali</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>CrossRef</collection><jtitle>Desalination and water treatment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zerdoumi, Ridha</au><au>Chatta, Hadjer</au><au>Mellahi, Dhaouadi</au><au>Oulmi, Kafia</au><au>Ferhat, Mahmoud</au><au>Ourari, Ali</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chronopotentiometric evaluation of enhanced counter-ion transport through anion exchange membranes in electromembrane processes</atitle><jtitle>Desalination and water treatment</jtitle><date>2017-06</date><risdate>2017</risdate><volume>78</volume><spage>34</spage><epage>40</epage><pages>34-40</pages><issn>1944-3986</issn><abstract>This paper reports the use of chronopotentiometry as a powerful technique to study counter-ion transport properties through ion-exchange membranes. Chronopotentiometry at current values less, equal and greater than the limiting current density has been used to understand the role of ammonia buffer in the reduction and elimination of the concentration polarisation phenomena of ion transport through the Neosepta AMX anion exchange membrane (Tokuyama Soda, Japan). The addition of ammonia led to polarisation chronopotentiograms without transition time. The results show that the water dissociation reaction in the boundary layer is catalytically enhanced by ammonia. It shifted the overlimiting current regions towards the ohmic regions by destruction and elimination of the diffusion boundary layer.</abstract><pub>Elsevier Inc</pub><doi>10.5004/dwt.2017.20871</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1944-3986
ispartof Desalination and water treatment, 2017-06, Vol.78, p.34-40
issn 1944-3986
language eng
recordid cdi_crossref_primary_10_5004_dwt_2017_20871
source Alma/SFX Local Collection
subjects Buffer solution
Chronopotentiometry
Concentration polarisation
Counter-ion transport
Ion-exchange membrane
Water dissociation
title Chronopotentiometric evaluation of enhanced counter-ion transport through anion exchange membranes in electromembrane processes
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-11T22%3A18%3A17IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-elsevier_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Chronopotentiometric%20evaluation%20of%20enhanced%20counter-ion%20transport%20through%20anion%20exchange%20membranes%20in%20electromembrane%20processes&rft.jtitle=Desalination%20and%20water%20treatment&rft.au=Zerdoumi,%20Ridha&rft.date=2017-06&rft.volume=78&rft.spage=34&rft.epage=40&rft.pages=34-40&rft.issn=1944-3986&rft_id=info:doi/10.5004/dwt.2017.20871&rft_dat=%3Celsevier_cross%3ES1944398624123168%3C/elsevier_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rft_els_id=S1944398624123168&rfr_iscdi=true