Removal of emerging contaminants of industrial origin by NF/RO - A pilot scale study
In this study a recently built NF/RO pilot unit for removal of emerging contaminants from a plant producing veterinary pharmaceuticals was tested. A wastewater stream of the plant, containing residuals of antibiotics and other organics was treated by three different types of reverse osmosis (RO) and...
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| Veröffentlicht in: | Desalination and water treatment 2009-06, Vol.6 (1-3), p.197-203 |
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| container_title | Desalination and water treatment |
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| creator | Dolar, Davor Košutić, Krešimir Pavlović, Dragana Mutavdžić Kunst, Branko |
| description | In this study a recently built NF/RO pilot unit for removal of emerging contaminants from a plant producing veterinary pharmaceuticals was tested. A wastewater stream of the plant, containing residuals of antibiotics and other organics was treated by three different types of reverse osmosis (RO) and nanofiltration membranes: XLE, NF90 and HL. Target compounds selected for this study included three different classes of antibiotics: sulphonamides, diaminopyrimidine and fluoroquinolone. A developed chromatographic method for determination of pharmaceuticals in a complex wastewater was applied. The method involved a sample pretreatment by solid-phase extraction (SPE) and analytical determination by high performance liquid chromatography (HPLC) with DAD detectors. The results showed the complete removal of all the antibiotics by the typical RO XLE membrane and by the tight nanofiltration membrane NF90. Only the loose nanofiltration membrane element HL incompletely rejected the smaller sulphonamide molecules. The satisfactory rejection of other solutes from a complex wastewater stream was also obtained. |
| doi_str_mv | 10.5004/dwt.2009.636 |
| format | Article |
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A wastewater stream of the plant, containing residuals of antibiotics and other organics was treated by three different types of reverse osmosis (RO) and nanofiltration membranes: XLE, NF90 and HL. Target compounds selected for this study included three different classes of antibiotics: sulphonamides, diaminopyrimidine and fluoroquinolone. A developed chromatographic method for determination of pharmaceuticals in a complex wastewater was applied. The method involved a sample pretreatment by solid-phase extraction (SPE) and analytical determination by high performance liquid chromatography (HPLC) with DAD detectors. The results showed the complete removal of all the antibiotics by the typical RO XLE membrane and by the tight nanofiltration membrane NF90. Only the loose nanofiltration membrane element HL incompletely rejected the smaller sulphonamide molecules. The satisfactory rejection of other solutes from a complex wastewater stream was also obtained.</description><identifier>ISSN: 1944-3986</identifier><identifier>ISSN: 1944-3994</identifier><identifier>EISSN: 1944-3986</identifier><identifier>DOI: 10.5004/dwt.2009.636</identifier><language>eng</language><publisher>L'Aquila: Elsevier Inc</publisher><subject>Applied sciences ; Drinking water and swimming-pool water. 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The satisfactory rejection of other solutes from a complex wastewater stream was also obtained.</description><subject>Applied sciences</subject><subject>Drinking water and swimming-pool water. Desalination</subject><subject>Emerging contaminants</subject><subject>Exact sciences and technology</subject><subject>Pollution</subject><subject>RO/NF pilot treatment</subject><subject>SPE-HPLC-DAD</subject><subject>Veterinary antibiotics</subject><subject>Wastewater</subject><subject>Water treatment and pollution</subject><issn>1944-3986</issn><issn>1944-3994</issn><issn>1944-3986</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNptkE1LAzEQhoMoWGpv_oBcvLltks0mm2MpVgWxUOo5ZJPZEtmPkqSV_nt3qYgH5zIzzDMzLy9C95TMC0L4wn2lOSNEzUUurtCEKs6zXJXi-k99i2YxfpIhCi4LziZot4W2P5kG9zWGFsLed3ts-y6Z1nemS3Ec-M4dYwp-xIIfEFyd8ft6sd3gDC_xwTd9wtGaBnBMR3e-Qze1aSLMfvIUfayfdquX7G3z_LpavmU2pyxlVW1ZZaUjoGrIgTnKSFlRZVUlnSxBlowXpKgklSCHRoBllNtSSFIbTlw-RY-Xuzb0MQao9SH41oSzpkSPpujBFD2aogdTBvzhgh_MKLYOprM-_u4wxiRTYuTEhYNB-8lD0NF66Cw4H8Am7Xr__4NvHZd0Ag</recordid><startdate>20090601</startdate><enddate>20090601</enddate><creator>Dolar, Davor</creator><creator>Košutić, Krešimir</creator><creator>Pavlović, Dragana Mutavdžić</creator><creator>Kunst, Branko</creator><general>Elsevier Inc</general><general>Desalination Publications</general><scope>6I.</scope><scope>AAFTH</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20090601</creationdate><title>Removal of emerging contaminants of industrial origin by NF/RO - A pilot scale study</title><author>Dolar, Davor ; Košutić, Krešimir ; Pavlović, Dragana Mutavdžić ; Kunst, Branko</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c312t-bfc2bc7d0e9fe3e2d1208b19c9b7d78e7824505b717e77826ec214c8670fa40d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Drinking water and swimming-pool water. Desalination</topic><topic>Emerging contaminants</topic><topic>Exact sciences and technology</topic><topic>Pollution</topic><topic>RO/NF pilot treatment</topic><topic>SPE-HPLC-DAD</topic><topic>Veterinary antibiotics</topic><topic>Wastewater</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dolar, Davor</creatorcontrib><creatorcontrib>Košutić, Krešimir</creatorcontrib><creatorcontrib>Pavlović, Dragana Mutavdžić</creatorcontrib><creatorcontrib>Kunst, Branko</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Desalination and water treatment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dolar, Davor</au><au>Košutić, Krešimir</au><au>Pavlović, Dragana Mutavdžić</au><au>Kunst, Branko</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Removal of emerging contaminants of industrial origin by NF/RO - A pilot scale study</atitle><jtitle>Desalination and water treatment</jtitle><date>2009-06-01</date><risdate>2009</risdate><volume>6</volume><issue>1-3</issue><spage>197</spage><epage>203</epage><pages>197-203</pages><issn>1944-3986</issn><issn>1944-3994</issn><eissn>1944-3986</eissn><abstract>In this study a recently built NF/RO pilot unit for removal of emerging contaminants from a plant producing veterinary pharmaceuticals was tested. A wastewater stream of the plant, containing residuals of antibiotics and other organics was treated by three different types of reverse osmosis (RO) and nanofiltration membranes: XLE, NF90 and HL. Target compounds selected for this study included three different classes of antibiotics: sulphonamides, diaminopyrimidine and fluoroquinolone. A developed chromatographic method for determination of pharmaceuticals in a complex wastewater was applied. The method involved a sample pretreatment by solid-phase extraction (SPE) and analytical determination by high performance liquid chromatography (HPLC) with DAD detectors. The results showed the complete removal of all the antibiotics by the typical RO XLE membrane and by the tight nanofiltration membrane NF90. Only the loose nanofiltration membrane element HL incompletely rejected the smaller sulphonamide molecules. 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| ispartof | Desalination and water treatment, 2009-06, Vol.6 (1-3), p.197-203 |
| issn | 1944-3986 1944-3994 1944-3986 |
| language | eng |
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| source | Alma/SFX Local Collection |
| subjects | Applied sciences Drinking water and swimming-pool water. Desalination Emerging contaminants Exact sciences and technology Pollution RO/NF pilot treatment SPE-HPLC-DAD Veterinary antibiotics Wastewater Water treatment and pollution |
| title | Removal of emerging contaminants of industrial origin by NF/RO - A pilot scale study |
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