Pulsed laser deposition and structural analysis of Ba 2 Ti 6 O 13 epitaxial thin film on the (210) surface of SrTiO 3 single crystal

Pulsed laser deposition and structural analysis of Ba 2 Ti 6 O 13 epitaxial thin film on the (210) surface of SrTiO 3 single crystal

A single crystalline thin film of Ba 2 Ti 6 O 13 was grown on the (210) surface of a SrTiO 3 single-crystal substrate by pulsed laser deposition. Scanning transmission electron microscopy shows that the Ba 2 Ti 6 O 13 thin film grew epitaxially with the a -plane, and the b -/ c -axes of Ba 2 Ti 6 O...

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Veröffentlicht in:Applied physics express 2024-07, Vol.17 (7), p.75503
Hauptverfasser: Kono, Ryota, Hieda, Kohei, Tokunaga, Tomoharu, Tamura, Ryoma, Masamura, Ryotaro, Hikita, Yasuyuki, Kano, Kazuhiko, Yamamoto, Takahisa
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container_issue 7
container_start_page 75503
container_title Applied physics express
container_volume 17
creator Kono, Ryota
Hieda, Kohei
Tokunaga, Tomoharu
Tamura, Ryoma
Masamura, Ryotaro
Hikita, Yasuyuki
Kano, Kazuhiko
Yamamoto, Takahisa
description A single crystalline thin film of Ba 2 Ti 6 O 13 was grown on the (210) surface of a SrTiO 3 single-crystal substrate by pulsed laser deposition. Scanning transmission electron microscopy shows that the Ba 2 Ti 6 O 13 thin film grew epitaxially with the a -plane, and the b -/ c -axes of Ba 2 Ti 6 O 13 parallel to the (210) plane and the [00 1 ¯ ]/[ 1 ¯ 20] directions of SrTiO 3 , respectively. The electrical conductance of the Ba 2 Ti 6 O 13 film was approximately one order larger than that of the reduced SrTiO 3− δ single crystal with oxygen deficiency of roughly δ = 0.05. Electronic structure calculations predict that Ba 2 Ti 6 O 13 is an n-type degenerate semiconductor with spin-split states primarily of Ti 3d orbital.
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title Pulsed laser deposition and structural analysis of Ba 2 Ti 6 O 13 epitaxial thin film on the (210) surface of SrTiO 3 single crystal
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