Thermoelectric Properties of Cu2Se Synthesized by Hydrothermal Method and Densified by SPS Technique
The aim of the work was to obtain copper (I) selenide Cu2Se material with excellent thermoelectric properties, synthesized using the hydrothermal method and densified by the spark plasma sintering (SPS) method. Chemical and phase composition studies were carried out by X-ray diffraction (XRD), scann...
Gespeichert in:
| Veröffentlicht in: | Materials 2021-06, Vol.14 (13), p.3650, Article 3650 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 13 |
| container_start_page | 3650 |
| container_title | Materials |
| container_volume | 14 |
| creator | Nieroda, Pawel Kusior, Anna Leszczynski, Juliusz Rutkowski, Pawel Kolezynski, Andrzej |
| description | The aim of the work was to obtain copper (I) selenide Cu2Se material with excellent thermoelectric properties, synthesized using the hydrothermal method and densified by the spark plasma sintering (SPS) method. Chemical and phase composition studies were carried out by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) methods. Measurements of thermoelectric transport properties, i.e., electrical conductivity, the Seebeck coefficient, and thermal conductivity in the temperature range from 300 to 965 K were carried out. Based on these results, the temperature dependence of the thermoelectric figure of merit ZT as a function of temperature was determined. The obtained, very high ZT parameter (ZT similar to 1.75, T = 965 K) is one of the highest obtained so far for undoped Cu2Se. |
| doi_str_mv | 10.3390/ma14133650 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_3390_ma14133650</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2548413988</sourcerecordid><originalsourceid>FETCH-LOGICAL-c313t-6700ab009a3300e2859904a966290929cdce4acb832bcbd72125679ea3a11ac13</originalsourceid><addsrcrecordid>eNqNkU1r3DAQhk1paEKSS3-BoJfSsq2-rJUuheKmTSGlgd2ehSyPawVb2kpywubXR2ZD-nHqXDSgZ15m3reqXhL8jjGF30-GcMKYqPGz6oQoJVZEcf78j_64Ok_pBpdijEiqXlTHjFMsFVEnVbcdIE4BRrA5OouuY9hBzA4SCj1qZroBtNn7PEBy99Chdo8u910MeRkzI_oGeQgdMr5Dn8An17sDtLneoC3YwbtfM5xVR70ZE5w_vqfVj88X2-ZydfX9y9fm49XKMsLySqwxNi3GyjCGMVBZK4W5UUJQhRVVtrPAjW0lo61tuzUltBZrBYYZQowl7LT6cNDdze0EhfY5mlHvoptM3OtgnP77x7tB_wy3WlKhRM2LwOtHgRjK3inrySUL42g8hDlpWnNZ3FZSFvTVP-hNmKMv5y2U4pIIygr15kDZGFKK0D8tQ7Be8tO_8yvw2wN8B23ok3XgLTwNlPyKQcUGtkS5HCv_n25cNtkF34TZZ_YAEcSsDA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2549481623</pqid></control><display><type>article</type><title>Thermoelectric Properties of Cu2Se Synthesized by Hydrothermal Method and Densified by SPS Technique</title><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central Open Access</source><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /></source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><creator>Nieroda, Pawel ; Kusior, Anna ; Leszczynski, Juliusz ; Rutkowski, Pawel ; Kolezynski, Andrzej</creator><creatorcontrib>Nieroda, Pawel ; Kusior, Anna ; Leszczynski, Juliusz ; Rutkowski, Pawel ; Kolezynski, Andrzej</creatorcontrib><description>The aim of the work was to obtain copper (I) selenide Cu2Se material with excellent thermoelectric properties, synthesized using the hydrothermal method and densified by the spark plasma sintering (SPS) method. Chemical and phase composition studies were carried out by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) methods. Measurements of thermoelectric transport properties, i.e., electrical conductivity, the Seebeck coefficient, and thermal conductivity in the temperature range from 300 to 965 K were carried out. Based on these results, the temperature dependence of the thermoelectric figure of merit ZT as a function of temperature was determined. The obtained, very high ZT parameter (ZT similar to 1.75, T = 965 K) is one of the highest obtained so far for undoped Cu2Se.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma14133650</identifier><identifier>PMID: 34208919</identifier><language>eng</language><publisher>BASEL: Mdpi</publisher><subject>Chemical composition ; Chemistry ; Chemistry, Physical ; Composite materials ; Copper selenides ; Crystal lattices ; Electrical resistivity ; Electron microscopy ; Figure of merit ; Grain boundaries ; Heat conductivity ; Hot pressing ; Materials Science ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering ; Phase composition ; Physical Sciences ; Physics ; Physics, Applied ; Physics, Condensed Matter ; Plasma sintering ; Science & Technology ; Seebeck effect ; Spark plasma sintering ; Synthesis ; Technology ; Temperature dependence ; Thermal conductivity ; Thermoelectric materials ; Thermoelectricity ; Transport properties</subject><ispartof>Materials, 2021-06, Vol.14 (13), p.3650, Article 3650</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2021 by the authors. 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>16</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000670929300001</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c313t-6700ab009a3300e2859904a966290929cdce4acb832bcbd72125679ea3a11ac13</citedby><cites>FETCH-LOGICAL-c313t-6700ab009a3300e2859904a966290929cdce4acb832bcbd72125679ea3a11ac13</cites><orcidid>0000-0002-2562-6996 ; 0000-0002-1730-7610 ; 0000-0002-4682-8300</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8269654/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8269654/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,315,728,781,785,886,27929,27930,39263,53796,53798</link.rule.ids></links><search><creatorcontrib>Nieroda, Pawel</creatorcontrib><creatorcontrib>Kusior, Anna</creatorcontrib><creatorcontrib>Leszczynski, Juliusz</creatorcontrib><creatorcontrib>Rutkowski, Pawel</creatorcontrib><creatorcontrib>Kolezynski, Andrzej</creatorcontrib><title>Thermoelectric Properties of Cu2Se Synthesized by Hydrothermal Method and Densified by SPS Technique</title><title>Materials</title><addtitle>MATERIALS</addtitle><description>The aim of the work was to obtain copper (I) selenide Cu2Se material with excellent thermoelectric properties, synthesized using the hydrothermal method and densified by the spark plasma sintering (SPS) method. Chemical and phase composition studies were carried out by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) methods. Measurements of thermoelectric transport properties, i.e., electrical conductivity, the Seebeck coefficient, and thermal conductivity in the temperature range from 300 to 965 K were carried out. Based on these results, the temperature dependence of the thermoelectric figure of merit ZT as a function of temperature was determined. The obtained, very high ZT parameter (ZT similar to 1.75, T = 965 K) is one of the highest obtained so far for undoped Cu2Se.</description><subject>Chemical composition</subject><subject>Chemistry</subject><subject>Chemistry, Physical</subject><subject>Composite materials</subject><subject>Copper selenides</subject><subject>Crystal lattices</subject><subject>Electrical resistivity</subject><subject>Electron microscopy</subject><subject>Figure of merit</subject><subject>Grain boundaries</subject><subject>Heat conductivity</subject><subject>Hot pressing</subject><subject>Materials Science</subject><subject>Materials Science, Multidisciplinary</subject><subject>Metallurgy & Metallurgical Engineering</subject><subject>Phase composition</subject><subject>Physical Sciences</subject><subject>Physics</subject><subject>Physics, Applied</subject><subject>Physics, Condensed Matter</subject><subject>Plasma sintering</subject><subject>Science & Technology</subject><subject>Seebeck effect</subject><subject>Spark plasma sintering</subject><subject>Synthesis</subject><subject>Technology</subject><subject>Temperature dependence</subject><subject>Thermal conductivity</subject><subject>Thermoelectric materials</subject><subject>Thermoelectricity</subject><subject>Transport properties</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>HGBXW</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqNkU1r3DAQhk1paEKSS3-BoJfSsq2-rJUuheKmTSGlgd2ehSyPawVb2kpywubXR2ZD-nHqXDSgZ15m3reqXhL8jjGF30-GcMKYqPGz6oQoJVZEcf78j_64Ok_pBpdijEiqXlTHjFMsFVEnVbcdIE4BRrA5OouuY9hBzA4SCj1qZroBtNn7PEBy99Chdo8u910MeRkzI_oGeQgdMr5Dn8An17sDtLneoC3YwbtfM5xVR70ZE5w_vqfVj88X2-ZydfX9y9fm49XKMsLySqwxNi3GyjCGMVBZK4W5UUJQhRVVtrPAjW0lo61tuzUltBZrBYYZQowl7LT6cNDdze0EhfY5mlHvoptM3OtgnP77x7tB_wy3WlKhRM2LwOtHgRjK3inrySUL42g8hDlpWnNZ3FZSFvTVP-hNmKMv5y2U4pIIygr15kDZGFKK0D8tQ7Be8tO_8yvw2wN8B23ok3XgLTwNlPyKQcUGtkS5HCv_n25cNtkF34TZZ_YAEcSsDA</recordid><startdate>20210630</startdate><enddate>20210630</enddate><creator>Nieroda, Pawel</creator><creator>Kusior, Anna</creator><creator>Leszczynski, Juliusz</creator><creator>Rutkowski, Pawel</creator><creator>Kolezynski, Andrzej</creator><general>Mdpi</general><general>MDPI AG</general><general>MDPI</general><scope>BLEPL</scope><scope>DTL</scope><scope>HGBXW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-2562-6996</orcidid><orcidid>https://orcid.org/0000-0002-1730-7610</orcidid><orcidid>https://orcid.org/0000-0002-4682-8300</orcidid></search><sort><creationdate>20210630</creationdate><title>Thermoelectric Properties of Cu2Se Synthesized by Hydrothermal Method and Densified by SPS Technique</title><author>Nieroda, Pawel ; Kusior, Anna ; Leszczynski, Juliusz ; Rutkowski, Pawel ; Kolezynski, Andrzej</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c313t-6700ab009a3300e2859904a966290929cdce4acb832bcbd72125679ea3a11ac13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemical composition</topic><topic>Chemistry</topic><topic>Chemistry, Physical</topic><topic>Composite materials</topic><topic>Copper selenides</topic><topic>Crystal lattices</topic><topic>Electrical resistivity</topic><topic>Electron microscopy</topic><topic>Figure of merit</topic><topic>Grain boundaries</topic><topic>Heat conductivity</topic><topic>Hot pressing</topic><topic>Materials Science</topic><topic>Materials Science, Multidisciplinary</topic><topic>Metallurgy & Metallurgical Engineering</topic><topic>Phase composition</topic><topic>Physical Sciences</topic><topic>Physics</topic><topic>Physics, Applied</topic><topic>Physics, Condensed Matter</topic><topic>Plasma sintering</topic><topic>Science & Technology</topic><topic>Seebeck effect</topic><topic>Spark plasma sintering</topic><topic>Synthesis</topic><topic>Technology</topic><topic>Temperature dependence</topic><topic>Thermal conductivity</topic><topic>Thermoelectric materials</topic><topic>Thermoelectricity</topic><topic>Transport properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nieroda, Pawel</creatorcontrib><creatorcontrib>Kusior, Anna</creatorcontrib><creatorcontrib>Leszczynski, Juliusz</creatorcontrib><creatorcontrib>Rutkowski, Pawel</creatorcontrib><creatorcontrib>Kolezynski, Andrzej</creatorcontrib><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>Web of Science - Science Citation Index Expanded - 2021</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nieroda, Pawel</au><au>Kusior, Anna</au><au>Leszczynski, Juliusz</au><au>Rutkowski, Pawel</au><au>Kolezynski, Andrzej</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermoelectric Properties of Cu2Se Synthesized by Hydrothermal Method and Densified by SPS Technique</atitle><jtitle>Materials</jtitle><stitle>MATERIALS</stitle><date>2021-06-30</date><risdate>2021</risdate><volume>14</volume><issue>13</issue><spage>3650</spage><pages>3650-</pages><artnum>3650</artnum><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>The aim of the work was to obtain copper (I) selenide Cu2Se material with excellent thermoelectric properties, synthesized using the hydrothermal method and densified by the spark plasma sintering (SPS) method. Chemical and phase composition studies were carried out by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) methods. Measurements of thermoelectric transport properties, i.e., electrical conductivity, the Seebeck coefficient, and thermal conductivity in the temperature range from 300 to 965 K were carried out. Based on these results, the temperature dependence of the thermoelectric figure of merit ZT as a function of temperature was determined. The obtained, very high ZT parameter (ZT similar to 1.75, T = 965 K) is one of the highest obtained so far for undoped Cu2Se.</abstract><cop>BASEL</cop><pub>Mdpi</pub><pmid>34208919</pmid><doi>10.3390/ma14133650</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-2562-6996</orcidid><orcidid>https://orcid.org/0000-0002-1730-7610</orcidid><orcidid>https://orcid.org/0000-0002-4682-8300</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1996-1944 |
| ispartof | Materials, 2021-06, Vol.14 (13), p.3650, Article 3650 |
| issn | 1996-1944 1996-1944 |
| language | eng |
| recordid | cdi_crossref_primary_10_3390_ma14133650 |
| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; MDPI - Multidisciplinary Digital Publishing Institute; Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" />; PubMed Central; Free Full-Text Journals in Chemistry |
| subjects | Chemical composition Chemistry Chemistry, Physical Composite materials Copper selenides Crystal lattices Electrical resistivity Electron microscopy Figure of merit Grain boundaries Heat conductivity Hot pressing Materials Science Materials Science, Multidisciplinary Metallurgy & Metallurgical Engineering Phase composition Physical Sciences Physics Physics, Applied Physics, Condensed Matter Plasma sintering Science & Technology Seebeck effect Spark plasma sintering Synthesis Technology Temperature dependence Thermal conductivity Thermoelectric materials Thermoelectricity Transport properties |
| title | Thermoelectric Properties of Cu2Se Synthesized by Hydrothermal Method and Densified by SPS Technique |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-15T10%3A23%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Thermoelectric%20Properties%20of%20Cu2Se%20Synthesized%20by%20Hydrothermal%20Method%20and%20Densified%20by%20SPS%20Technique&rft.jtitle=Materials&rft.au=Nieroda,%20Pawel&rft.date=2021-06-30&rft.volume=14&rft.issue=13&rft.spage=3650&rft.pages=3650-&rft.artnum=3650&rft.issn=1996-1944&rft.eissn=1996-1944&rft_id=info:doi/10.3390/ma14133650&rft_dat=%3Cproquest_cross%3E2548413988%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2549481623&rft_id=info:pmid/34208919&rfr_iscdi=true |