Pulse- and Gamma-Radiolysis of Aqueous Solutions of Tryptophan

Absorbing transient species are formed by the reaction of ·OH, H·, and ${\rm e}_{{\rm aq}}^{-}$ with tryptophan. The rate constants for the reaction of ·OH and H· with tryptophan are 1.25 ± $0.3\times 10^{10}\ M^{-1}\ {\rm sec}^{-1}$ and 7.4 ± $1\times 10^{9}\ M^{-1}\ {\rm sec}^{-1}$, respectively....

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Veröffentlicht in:	Radiat. Res. 40: 563-79(Dec 1969) 1969-12, Vol.40 (3), p.563-579
Hauptverfasser:	Armstrong, R. C., Swallow, A. J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectra AMINO ACIDS AMMONIA AMMONIA/yields from $gamma$ radiolysis of deaerated solutions of tryptophan Aqueous solutions Atoms CARBON DIOXIDE CARBON DIOXIDES/yields from $gamma$ radiolysis of deaerated solutions of tryptophan ELECTRONS ELECTRONS/effects of pulsed, on aqueous solutions of tryptophan, mechanism and yields from Free Radicals G-VALUE GAMMA RADIATION GAMMA RADIATION/effects on aqueous solutions of tryptophan, mechanism and yields from HYDROGEN HYDROGEN PEROXIDES HYDROGEN PEROXIDES/yields from $gamma$ radiolysis of deaerated solutions of tryptophan Hydrogen-Ion Concentration HYDROGEN/yields from $gamma$ radiolysis of deaerated solutions of tryptophan Hydroxyl radicals Indoles Irradiation N20330 -Chemistry-Radiation & Nuclear Chemistry- Radiolysis PULSES Radiation Effects Radiochemistry RADIOLYSIS REACTION KINETICS SOLUTIONS Spectrum Analysis TRYPTOPHAN Tryptophan - radiation effects TRYPTOPHAN/radiolysis of aqueous solutions of, mechanism and yields from electron pulse and WATER
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