HYBRID ATOMIC ORBITALS IN ORGANIC CHEMISTRY. PART 1: CRITIQUE OF FORMAL ASPECTS

The importance of hybrid atomic orbitals, both historically and mathematically, is reviewed. Our new analysis of the original derivation of the sp3, sp2, sp model reveals serious errors. Based on a critical survey of the literature, we submit six formal criteria that deprecate the use of hybrid orbi...

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Veröffentlicht in:	Química Nova 2019-08, Vol.42 (7), p.812-816
Hauptverfasser:	Lamoureux, Guy, Ogilvie, John
Format:	Artikel
Sprache:	eng
Schlagworte:	chemical education CHEMISTRY, MULTIDISCIPLINARY hybrid orbitals misconceptions undergraduate Organic Chemistry
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description	The importance of hybrid atomic orbitals, both historically and mathematically, is reviewed. Our new analysis of the original derivation of the sp3, sp2, sp model reveals serious errors. Based on a critical survey of the literature, we submit six formal criteria that deprecate the use of hybrid orbitals in a pedagogical context. A sound mathematical basis of sp3 and sp2 formulae does not exist; hybrid atomic orbitals have hence no legitimate role in the teaching of organic chemistry.
doi_str_mv	10.21577/0100-4042.20170376
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subjects	chemical education CHEMISTRY, MULTIDISCIPLINARY hybrid orbitals misconceptions undergraduate Organic Chemistry
title	HYBRID ATOMIC ORBITALS IN ORGANIC CHEMISTRY. PART 1: CRITIQUE OF FORMAL ASPECTS
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