Study on Corrosion Protection of Q235 Steel in Simulated Soil Pore Solution by Different Electrodeposited Coatings

Q235 steel as power grounding material was selected as the substrate, and different coatings (Zn-Ni alloy coating, Zn-Ni-W alloy coating and Zn-Ni-W/ZrO2 composite coating) were electrodeposited on its surface. The corrosion behavior of Q235 steel and different electrodeposited coatings in simulated...

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Veröffentlicht in:International journal of electrochemical science 2022-12, Vol.17 (12), p.2212112, Article 2212112
Hauptverfasser: Zou, Junwen, Zhao, Zhoufeng, Zhang, Jie, Zhou, Zhen, Xu, Sheng, Ye, Bo, Zhang, Jun
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container_issue 12
container_start_page 2212112
container_title International journal of electrochemical science
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creator Zou, Junwen
Zhao, Zhoufeng
Zhang, Jie
Zhou, Zhen
Xu, Sheng
Ye, Bo
Zhang, Jun
description Q235 steel as power grounding material was selected as the substrate, and different coatings (Zn-Ni alloy coating, Zn-Ni-W alloy coating and Zn-Ni-W/ZrO2 composite coating) were electrodeposited on its surface. The corrosion behavior of Q235 steel and different electrodeposited coatings in simulated soil pore solution was investigated through electrochemical testing. The results show that Zn-Ni alloy coating, Zn-Ni-W alloy coating and Zn-Ni-W/ZrO2 composite coating can inhibit the corrosion process of Q235 steel in simulated soil pore solution to improve its corrosion resistance. The phase composition of Zn-Ni-W alloy coating is the same as that of Zn-Ni alloy coating, while Zn-Ni-W/ZrO2 composite coating contains Zn phase, Ni5Zn21 phase and ZrO2 phase. ZrO2 particles are uniformly doped in the composite coating. Compared with Zn-Ni alloy coating and Zn-Ni-W alloy coating, Zn- Ni-W/ZrO2 composite coating has the lowest corrosion current density (9.87x10-7 A/cm2) and the highest charge-transfer resistance (7.34×103 Ω·cm2). After being corroded by 15 mA DC stray current for 14 days, it still maintains integrity and high compactness with lightest corrosion degree. Electrodeposition of Zn-Ni-W/ZrO2 composite coating can not only meet the electrical conductivity requirements of power grounding electrode, but also significantly improve the corrosion resistance of carbon steel grounding electrode under the combined action of electrochemical corrosion and stray current corrosion in soil.
doi_str_mv 10.20964/2022.12.107
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The corrosion behavior of Q235 steel and different electrodeposited coatings in simulated soil pore solution was investigated through electrochemical testing. The results show that Zn-Ni alloy coating, Zn-Ni-W alloy coating and Zn-Ni-W/ZrO2 composite coating can inhibit the corrosion process of Q235 steel in simulated soil pore solution to improve its corrosion resistance. The phase composition of Zn-Ni-W alloy coating is the same as that of Zn-Ni alloy coating, while Zn-Ni-W/ZrO2 composite coating contains Zn phase, Ni5Zn21 phase and ZrO2 phase. ZrO2 particles are uniformly doped in the composite coating. Compared with Zn-Ni alloy coating and Zn-Ni-W alloy coating, Zn- Ni-W/ZrO2 composite coating has the lowest corrosion current density (9.87x10-7 A/cm2) and the highest charge-transfer resistance (7.34×103 Ω·cm2). After being corroded by 15 mA DC stray current for 14 days, it still maintains integrity and high compactness with lightest corrosion degree. Electrodeposition of Zn-Ni-W/ZrO2 composite coating can not only meet the electrical conductivity requirements of power grounding electrode, but also significantly improve the corrosion resistance of carbon steel grounding electrode under the combined action of electrochemical corrosion and stray current corrosion in soil.</description><identifier>ISSN: 1452-3981</identifier><identifier>EISSN: 1452-3981</identifier><identifier>DOI: 10.20964/2022.12.107</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Corrosion protection ; Electrodeposition ; Power grounding material ; Zn-Ni alloy coating ; Zn-Ni-W alloy coating ; Zn-Ni-W/ZrO2 composite coating</subject><ispartof>International journal of electrochemical science, 2022-12, Vol.17 (12), p.2212112, Article 2212112</ispartof><rights>2022 The Authors. 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The corrosion behavior of Q235 steel and different electrodeposited coatings in simulated soil pore solution was investigated through electrochemical testing. The results show that Zn-Ni alloy coating, Zn-Ni-W alloy coating and Zn-Ni-W/ZrO2 composite coating can inhibit the corrosion process of Q235 steel in simulated soil pore solution to improve its corrosion resistance. The phase composition of Zn-Ni-W alloy coating is the same as that of Zn-Ni alloy coating, while Zn-Ni-W/ZrO2 composite coating contains Zn phase, Ni5Zn21 phase and ZrO2 phase. ZrO2 particles are uniformly doped in the composite coating. Compared with Zn-Ni alloy coating and Zn-Ni-W alloy coating, Zn- Ni-W/ZrO2 composite coating has the lowest corrosion current density (9.87x10-7 A/cm2) and the highest charge-transfer resistance (7.34×103 Ω·cm2). After being corroded by 15 mA DC stray current for 14 days, it still maintains integrity and high compactness with lightest corrosion degree. 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The corrosion behavior of Q235 steel and different electrodeposited coatings in simulated soil pore solution was investigated through electrochemical testing. The results show that Zn-Ni alloy coating, Zn-Ni-W alloy coating and Zn-Ni-W/ZrO2 composite coating can inhibit the corrosion process of Q235 steel in simulated soil pore solution to improve its corrosion resistance. The phase composition of Zn-Ni-W alloy coating is the same as that of Zn-Ni alloy coating, while Zn-Ni-W/ZrO2 composite coating contains Zn phase, Ni5Zn21 phase and ZrO2 phase. ZrO2 particles are uniformly doped in the composite coating. Compared with Zn-Ni alloy coating and Zn-Ni-W alloy coating, Zn- Ni-W/ZrO2 composite coating has the lowest corrosion current density (9.87x10-7 A/cm2) and the highest charge-transfer resistance (7.34×103 Ω·cm2). After being corroded by 15 mA DC stray current for 14 days, it still maintains integrity and high compactness with lightest corrosion degree. Electrodeposition of Zn-Ni-W/ZrO2 composite coating can not only meet the electrical conductivity requirements of power grounding electrode, but also significantly improve the corrosion resistance of carbon steel grounding electrode under the combined action of electrochemical corrosion and stray current corrosion in soil.</abstract><pub>Elsevier B.V</pub><doi>10.20964/2022.12.107</doi><oa>free_for_read</oa></addata></record>
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subjects Corrosion protection
Electrodeposition
Power grounding material
Zn-Ni alloy coating
Zn-Ni-W alloy coating
Zn-Ni-W/ZrO2 composite coating
title Study on Corrosion Protection of Q235 Steel in Simulated Soil Pore Solution by Different Electrodeposited Coatings
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