Synthesis of ferrocenyl aryl ethers via Cu(I)/phosphine catalyst systems

Ferrocenyl aryl ethers can be synthesized in good yields by Cu(I)/phosphine-catalyzed coupling reactions from iodoferrocene or 1,1′-dibromoferrocene and various phenols in toluene, using Cs CO or K PO as a base. For the first time a solid-state structure of a ferrocenyl-1,1′-diaryl ether [1,1′-di(4-...

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Veröffentlicht in:	Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2015-01, Vol.70 (1), p.65-70
Hauptverfasser:	Frey, Guido D., Hoffmann, Stephan D.
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Sprache:	eng
Schlagworte:	aryl ethers crystal structure ferrocene
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creator	Frey, Guido D. Hoffmann, Stephan D.
description	Ferrocenyl aryl ethers can be synthesized in good yields by Cu(I)/phosphine-catalyzed coupling reactions from iodoferrocene or 1,1′-dibromoferrocene and various phenols in toluene, using Cs CO or K PO as a base. For the first time a solid-state structure of a ferrocenyl-1,1′-diaryl ether [1,1′-di(4- -butylphenoxy)ferrocene] has been determined from single-crystal X-ray data. The mixed ferrocenyl aryl ether 1-(4- -butylphenoxy)-1′-(2,4-dimethylphenoxy)ferrocene was prepared in a two-step synthetic protocol.
doi_str_mv	10.1515/znb-2014-0178
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For the first time a solid-state structure of a ferrocenyl-1,1′-diaryl ether [1,1′-di(4- -butylphenoxy)ferrocene] has been determined from single-crystal X-ray data. The mixed ferrocenyl aryl ether 1-(4- -butylphenoxy)-1′-(2,4-dimethylphenoxy)ferrocene was prepared in a two-step synthetic protocol.</description><identifier>ISSN: 0932-0776</identifier><identifier>EISSN: 1865-7117</identifier><identifier>DOI: 10.1515/znb-2014-0178</identifier><language>eng</language><publisher>De Gruyter</publisher><subject>aryl ethers ; crystal structure ; ferrocene</subject><ispartof>Zeitschrift für Naturforschung. 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For the first time a solid-state structure of a ferrocenyl-1,1′-diaryl ether [1,1′-di(4- -butylphenoxy)ferrocene] has been determined from single-crystal X-ray data. The mixed ferrocenyl aryl ether 1-(4- -butylphenoxy)-1′-(2,4-dimethylphenoxy)ferrocene was prepared in a two-step synthetic protocol.</abstract><pub>De Gruyter</pub><doi>10.1515/znb-2014-0178</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record>
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subjects	aryl ethers crystal structure ferrocene
title	Synthesis of ferrocenyl aryl ethers via Cu(I)/phosphine catalyst systems
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