Synthesis and Crystal Structure of a New Cd(II) Coordination Polymer Based on a 1,10-Phenanthroline Derivative
The new coordination polymer [Cd(oct)(L)] (H2oct = octanedioic acid and L = 2-(4-fluorophenyl)-1H-imidazo- [4,5-f][1,10]phenanthroline) has been synthesized under hydrothermal condition and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Crystal data: C CdF...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2011-05, Vol.66 (5), p.538-540 |
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| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
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| creator | Xu, Zhan-Lin Ma, Shuai He, Yu Kong, Zhi-Guo |
| description | The new coordination polymer [Cd(oct)(L)] (H2oct = octanedioic acid and L = 2-(4-fluorophenyl)-1H-imidazo- [4,5-f][1,10]phenanthroline) has been synthesized under hydrothermal condition and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Crystal data: C
CdFN
, monoclinic, space group C2/c, a = 21.391(4), b = 18.180(4), c = 14.031(3) Å , β = 116.50(3), V = 4883(2) Å3, Z = 8. The flexible oct dianions bridge the Cd(II) cations to yield a double-chain structure. The L ligands are attached on both sides of the chains, and their π-π interactions between neighboring chains result in two-dimensional supramolecular layers |
| doi_str_mv | 10.1515/znb-2011-0515 |
| format | Article |
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CdFN
, monoclinic, space group C2/c, a = 21.391(4), b = 18.180(4), c = 14.031(3) Å , β = 116.50(3), V = 4883(2) Å3, Z = 8. The flexible oct dianions bridge the Cd(II) cations to yield a double-chain structure. The L ligands are attached on both sides of the chains, and their π-π interactions between neighboring chains result in two-dimensional supramolecular layers</description><identifier>ISSN: 0932-0776</identifier><identifier>EISSN: 1865-7117</identifier><identifier>DOI: 10.1515/znb-2011-0515</identifier><language>eng</language><publisher>Verlag der Zeitschrift für Naturforschung</publisher><subject>2-(4-Fluorophenyl)-1Himidazo[ 4,5-f][1,10]phenanthroline ; Coordination Polymer ; Crystal Structure ; Octanedioic Acid</subject><ispartof>Zeitschrift für Naturforschung. B, A journal of chemical sciences, 2011-05, Vol.66 (5), p.538-540</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Xu, Zhan-Lin</creatorcontrib><creatorcontrib>Ma, Shuai</creatorcontrib><creatorcontrib>He, Yu</creatorcontrib><creatorcontrib>Kong, Zhi-Guo</creatorcontrib><title>Synthesis and Crystal Structure of a New Cd(II) Coordination Polymer Based on a 1,10-Phenanthroline Derivative</title><title>Zeitschrift für Naturforschung. B, A journal of chemical sciences</title><description>The new coordination polymer [Cd(oct)(L)] (H2oct = octanedioic acid and L = 2-(4-fluorophenyl)-1H-imidazo- [4,5-f][1,10]phenanthroline) has been synthesized under hydrothermal condition and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Crystal data: C
CdFN
, monoclinic, space group C2/c, a = 21.391(4), b = 18.180(4), c = 14.031(3) Å , β = 116.50(3), V = 4883(2) Å3, Z = 8. The flexible oct dianions bridge the Cd(II) cations to yield a double-chain structure. The L ligands are attached on both sides of the chains, and their π-π interactions between neighboring chains result in two-dimensional supramolecular layers</description><subject>2-(4-Fluorophenyl)-1Himidazo[ 4,5-f][1,10]phenanthroline</subject><subject>Coordination Polymer</subject><subject>Crystal Structure</subject><subject>Octanedioic Acid</subject><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNptkEtLAzEUhYMoWKtL91kqGM3NTJIZXOn4KhQttPshnSR2yjSRZNoy_npTdOnqPjjncO-H0CXQW-DA777dkjAKQGiajtAICsGJBJDHaETLjBEqpThFZzGuKYUyz-kIufng-pWJbcTKaVyFIfaqw_M-bJt-Gwz2Fiv8bva40leTyTWuvA-6dapvvcMz3w0bE_CjikbjtFAYboCS2co4lXKD71pn8JMJ7S45duYcnVjVRXPxV8do8fK8qN7I9ON1Uj1MSQNlWRDBVCO1lVYqQS0XJrMFkwys5KUuSmiWkC-Z5FKInFoJllGapW9zobRpWDZG5De2CT7GYGz9FdqNCkMNtD6wqhOr-sCqPrBK-vtf_V51vQnafIbtkJp67bfBpUP_9wnBeVZkP5yqb3g</recordid><startdate>20110501</startdate><enddate>20110501</enddate><creator>Xu, Zhan-Lin</creator><creator>Ma, Shuai</creator><creator>He, Yu</creator><creator>Kong, Zhi-Guo</creator><general>Verlag der Zeitschrift für Naturforschung</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20110501</creationdate><title>Synthesis and Crystal Structure of a New Cd(II) Coordination Polymer Based on a 1,10-Phenanthroline Derivative</title><author>Xu, Zhan-Lin ; Ma, Shuai ; He, Yu ; Kong, Zhi-Guo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1998-62ac7df7f7a60f56e3f82721f759d891cb14b27576640f71f200386546adec23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>2-(4-Fluorophenyl)-1Himidazo[ 4,5-f][1,10]phenanthroline</topic><topic>Coordination Polymer</topic><topic>Crystal Structure</topic><topic>Octanedioic Acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Zhan-Lin</creatorcontrib><creatorcontrib>Ma, Shuai</creatorcontrib><creatorcontrib>He, Yu</creatorcontrib><creatorcontrib>Kong, Zhi-Guo</creatorcontrib><collection>CrossRef</collection><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Zhan-Lin</au><au>Ma, Shuai</au><au>He, Yu</au><au>Kong, Zhi-Guo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Crystal Structure of a New Cd(II) Coordination Polymer Based on a 1,10-Phenanthroline Derivative</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>2011-05-01</date><risdate>2011</risdate><volume>66</volume><issue>5</issue><spage>538</spage><epage>540</epage><pages>538-540</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>The new coordination polymer [Cd(oct)(L)] (H2oct = octanedioic acid and L = 2-(4-fluorophenyl)-1H-imidazo- [4,5-f][1,10]phenanthroline) has been synthesized under hydrothermal condition and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Crystal data: C
CdFN
, monoclinic, space group C2/c, a = 21.391(4), b = 18.180(4), c = 14.031(3) Å , β = 116.50(3), V = 4883(2) Å3, Z = 8. The flexible oct dianions bridge the Cd(II) cations to yield a double-chain structure. The L ligands are attached on both sides of the chains, and their π-π interactions between neighboring chains result in two-dimensional supramolecular layers</abstract><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/znb-2011-0515</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | 2-(4-Fluorophenyl)-1Himidazo[ 4,5-f][1,10]phenanthroline Coordination Polymer Crystal Structure Octanedioic Acid |
| title | Synthesis and Crystal Structure of a New Cd(II) Coordination Polymer Based on a 1,10-Phenanthroline Derivative |
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