High-pressure Synthesis, Crystal Structure, and Properties of the First Ternary Zirconium Borate β-ZrB 2 O 5
The high-pressure phase β -ZrB 2 O 5 represents the first ternary borate in the system Zr-B-O. The compound was synthesized under high-pressure / high-temperature conditions of 7.5 GPa and 1100 °C in a Walker-type multianvil apparatus. The crystal structure was determined on the basis of single crys...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2008-06, Vol.63 (6), p.707-712 |
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| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
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| creator | Knyrim, Johanna S. Huppertz, Hubert |
| description | The high-pressure phase β -ZrB
2
O
5
represents the first ternary borate in the system Zr-B-O. The compound was synthesized under high-pressure / high-temperature conditions of 7.5 GPa and 1100 °C in a Walker-type multianvil apparatus. The crystal structure was determined on the basis of single crystal X-ray diffraction data, collected at room temperature. The monoclinic zirconium borate crystallizes in the space group P2
1
/c with the lattice parameters a = 439.04(9), b = 691.2(2), c = 896.8(2) pm, and β = 90.96(3)°. The structure is isotypic to the high-pressure phase β -HfB
2
O
5
, which is built up from layers of exclusively corner-sharing BO
4
tetrahedra. Between these layers, the cations are coordinated square-antiprismatically by eight oxygen atoms. |
| doi_str_mv | 10.1515/znb-2008-0617 |
| format | Article |
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2
O
5
represents the first ternary borate in the system Zr-B-O. The compound was synthesized under high-pressure / high-temperature conditions of 7.5 GPa and 1100 °C in a Walker-type multianvil apparatus. The crystal structure was determined on the basis of single crystal X-ray diffraction data, collected at room temperature. The monoclinic zirconium borate crystallizes in the space group P2
1
/c with the lattice parameters a = 439.04(9), b = 691.2(2), c = 896.8(2) pm, and β = 90.96(3)°. The structure is isotypic to the high-pressure phase β -HfB
2
O
5
, which is built up from layers of exclusively corner-sharing BO
4
tetrahedra. Between these layers, the cations are coordinated square-antiprismatically by eight oxygen atoms.</description><identifier>ISSN: 0932-0776</identifier><identifier>EISSN: 1865-7117</identifier><identifier>DOI: 10.1515/znb-2008-0617</identifier><language>eng</language><ispartof>Zeitschrift für Naturforschung. B, A journal of chemical sciences, 2008-06, Vol.63 (6), p.707-712</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c827-6b99da81d2036959b4fd4469540ae07b7ff85136c2896b8ea7d499b3d7fe2ffb3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Knyrim, Johanna S.</creatorcontrib><creatorcontrib>Huppertz, Hubert</creatorcontrib><title>High-pressure Synthesis, Crystal Structure, and Properties of the First Ternary Zirconium Borate β-ZrB 2 O 5</title><title>Zeitschrift für Naturforschung. B, A journal of chemical sciences</title><description>The high-pressure phase β -ZrB
2
O
5
represents the first ternary borate in the system Zr-B-O. The compound was synthesized under high-pressure / high-temperature conditions of 7.5 GPa and 1100 °C in a Walker-type multianvil apparatus. The crystal structure was determined on the basis of single crystal X-ray diffraction data, collected at room temperature. The monoclinic zirconium borate crystallizes in the space group P2
1
/c with the lattice parameters a = 439.04(9), b = 691.2(2), c = 896.8(2) pm, and β = 90.96(3)°. The structure is isotypic to the high-pressure phase β -HfB
2
O
5
, which is built up from layers of exclusively corner-sharing BO
4
tetrahedra. Between these layers, the cations are coordinated square-antiprismatically by eight oxygen atoms.</description><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNotkM1KAzEcxIMoWD-O3v8P0GiSzebjaIu1QqFCe-plye4mNtLuln_SQ30sH8RncoueZmCGYfgR8sDZIy95-fTV1VQwZihTXF-QETeqpJpzfUlGzBaCMq3VNblJ6ZMxbqVkI7Kfx48tPaBP6YgeVqcub32KaQxTPKXsdrDKeGzyEI7BdS28Y3_wmKNP0AcYyjCLmDKsPXYOT7CJ2PRdPO5h0qPLHn6-6QYnIGAJ5R25Cm6X_P2_3pL17GU9ndPF8vVt-rygjRGaqtra1hneClYoW9pahlbKwUnmPNO1DsGUvFCNMFbVxjvdSmvrotXBixDq4pbQv9kG-5TQh-qAcT-8qzirzqiqAVV1RlWdURW_pLtdug</recordid><startdate>20080601</startdate><enddate>20080601</enddate><creator>Knyrim, Johanna S.</creator><creator>Huppertz, Hubert</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20080601</creationdate><title>High-pressure Synthesis, Crystal Structure, and Properties of the First Ternary Zirconium Borate β-ZrB 2 O 5</title><author>Knyrim, Johanna S. ; Huppertz, Hubert</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c827-6b99da81d2036959b4fd4469540ae07b7ff85136c2896b8ea7d499b3d7fe2ffb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Knyrim, Johanna S.</creatorcontrib><creatorcontrib>Huppertz, Hubert</creatorcontrib><collection>CrossRef</collection><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Knyrim, Johanna S.</au><au>Huppertz, Hubert</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High-pressure Synthesis, Crystal Structure, and Properties of the First Ternary Zirconium Borate β-ZrB 2 O 5</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>2008-06-01</date><risdate>2008</risdate><volume>63</volume><issue>6</issue><spage>707</spage><epage>712</epage><pages>707-712</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>The high-pressure phase β -ZrB
2
O
5
represents the first ternary borate in the system Zr-B-O. The compound was synthesized under high-pressure / high-temperature conditions of 7.5 GPa and 1100 °C in a Walker-type multianvil apparatus. The crystal structure was determined on the basis of single crystal X-ray diffraction data, collected at room temperature. The monoclinic zirconium borate crystallizes in the space group P2
1
/c with the lattice parameters a = 439.04(9), b = 691.2(2), c = 896.8(2) pm, and β = 90.96(3)°. The structure is isotypic to the high-pressure phase β -HfB
2
O
5
, which is built up from layers of exclusively corner-sharing BO
4
tetrahedra. Between these layers, the cations are coordinated square-antiprismatically by eight oxygen atoms.</abstract><doi>10.1515/znb-2008-0617</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0932-0776 |
| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 2008-06, Vol.63 (6), p.707-712 |
| issn | 0932-0776 1865-7117 |
| language | eng |
| recordid | cdi_crossref_primary_10_1515_znb_2008_0617 |
| source | Alma/SFX Local Collection |
| title | High-pressure Synthesis, Crystal Structure, and Properties of the First Ternary Zirconium Borate β-ZrB 2 O 5 |
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