peri-Interactions in Naphthalenes, 14 [1]. Pyramidalization versus Planarization at Nitrogen in 8-Dialkylamino-naphth-1-yl Compounds as a Measure of peri Bond Formation

The degree of pyramidalization at the N atom of the title compounds permits to distinguish between covalent bond type attraction and other attractive forces. Most so-called coordinative bonds exhibit the features of normal covalent bonds. While such bonds emanating from third or higher period atoms...

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Veröffentlicht in:	Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2006-05, Vol.61 (5), p.535-554
1. Verfasser:	Schiemenz, Günter Paulus
Format:	Artikel
Sprache:	eng
Schlagworte:	Coordinative (Dative) Bonds Hydrogen Bonds Hypercoordination Stabilized Silenes van der Waals Radii
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description	The degree of pyramidalization at the N atom of the title compounds permits to distinguish between covalent bond type attraction and other attractive forces. Most so-called coordinative bonds exhibit the features of normal covalent bonds. While such bonds emanating from third or higher period atoms may be rather long, their stretchability is limited, and corresponding interatomic distances are an insufficient criterion for two-electron dative bonds.
doi_str_mv	10.1515/znb-2006-0507
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source	Alma/SFX Local Collection
subjects	Coordinative (Dative) Bonds Hydrogen Bonds Hypercoordination Stabilized Silenes van der Waals Radii
title	peri-Interactions in Naphthalenes, 14 [1]. Pyramidalization versus Planarization at Nitrogen in 8-Dialkylamino-naphth-1-yl Compounds as a Measure of peri Bond Formation
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