Synthesis And Luminescence Of Rh III (phpy) 2 (S∪E) Complexes With phpy– = Deprotonated 2-Phenylpyridine And S∪E– = Diethyldithiocarbamate, 2-Pyridinethiolate And 2-Quinolinethiolate

Synthesis And Luminescence Of Rh III (phpy) 2 (S∪E) Complexes With phpy– = Deprotonated 2-Phenylpyridine And S∪E– = Diethyldithiocarbamate, 2-Pyridinethiolate And 2-Quinolinethiolate

Complexes of the general composition Rh III (phpy) 2 (S∪E) with phpy − = 2-(2-pyridyl)phenyl and S∪E− = diethyldithiocarbamate, 2-pyridinethiolate and 2-quinolinethiolate were prepared and characterized. The complexes with S∪E − = diethyldithiocarbamate and 2-pyridinethiolate show a low-temperature...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2005-03, Vol.60 (3), p.359-362
Hauptverfasser: Pawlowski, Valeri, Kunkely, Horst, Vogler, Arnd
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container_title Zeitschrift für Naturforschung. B, A journal of chemical sciences
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creator Pawlowski, Valeri
Kunkely, Horst
Vogler, Arnd
description Complexes of the general composition Rh III (phpy) 2 (S∪E) with phpy − = 2-(2-pyridyl)phenyl and S∪E− = diethyldithiocarbamate, 2-pyridinethiolate and 2-quinolinethiolate were prepared and characterized. The complexes with S∪E − = diethyldithiocarbamate and 2-pyridinethiolate show a low-temperature luminescence which originates from a phpy ππ ∗ intraligand triplet. For the complex with S∪E − = 2-quinolinethiolate (or thiooxinate) the lowest-energy excited state is of the quinolinethiolate intraligand type. This complex displays a fluorescence as well as a phosphorescence under ambient conditions
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title Synthesis And Luminescence Of Rh III (phpy) 2 (S∪E) Complexes With phpy– = Deprotonated 2-Phenylpyridine And S∪E– = Diethyldithiocarbamate, 2-Pyridinethiolate And 2-Quinolinethiolate
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