A Homoleptic Zirconium Complex with Four Bulky η 2 -Pyrazolato Ligands
Two new tetrakisη 2 -pyrazolato) zirconium complexes are prepared from the reaction of Zr(CH 2 Ph) 4 with bulky pyrazolate ligands bearing indenylmethyl (HL 1 ) or fluorenylmethyl (HL 2 ) substituents, respectively. Zr(L 2 ) 4 has been analyzed by X-ray crystallography, which represents the first st...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2002-07, Vol.57 (7), p.773-776 |
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| container_issue | 7 |
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| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
| container_volume | 57 |
| creator | Röder, Jens C Meyer, Franc Pritzkow, Hans |
| description | Two new tetrakisη
2
-pyrazolato) zirconium complexes are prepared from the reaction of Zr(CH
2
Ph)
4
with bulky pyrazolate ligands bearing indenylmethyl (HL
1
) or fluorenylmethyl (HL
2
) substituents, respectively. Zr(L
2
)
4
has been analyzed by X-ray crystallography, which represents the first structural characterisation of a homoleptic η
2
-pyrazolato zirconium compound. |
| doi_str_mv | 10.1515/znb-2002-0709 |
| format | Article |
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with bulky pyrazolate ligands bearing indenylmethyl (HL
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2
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2
-pyrazolato) zirconium complexes are prepared from the reaction of Zr(CH
2
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4
with bulky pyrazolate ligands bearing indenylmethyl (HL
1
) or fluorenylmethyl (HL
2
) substituents, respectively. Zr(L
2
)
4
has been analyzed by X-ray crystallography, which represents the first structural characterisation of a homoleptic η
2
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2
-pyrazolato) zirconium complexes are prepared from the reaction of Zr(CH
2
Ph)
4
with bulky pyrazolate ligands bearing indenylmethyl (HL
1
) or fluorenylmethyl (HL
2
) substituents, respectively. Zr(L
2
)
4
has been analyzed by X-ray crystallography, which represents the first structural characterisation of a homoleptic η
2
-pyrazolato zirconium compound.</abstract><doi>10.1515/znb-2002-0709</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0932-0776 |
| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 2002-07, Vol.57 (7), p.773-776 |
| issn | 0932-0776 1865-7117 |
| language | eng |
| recordid | cdi_crossref_primary_10_1515_znb_2002_0709 |
| source | Alma/SFX Local Collection |
| title | A Homoleptic Zirconium Complex with Four Bulky η 2 -Pyrazolato Ligands |
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