Kristallstruktur von MgSO 3 ·H2 O /Crystal Structure of Mg SO 3 ·H 2 O
The crystal structure of MgSO 3 ·H 2 O , space group P2 1 /ln, Z = 4, D x = 2.415 g·cm -3 , a = 4.699(1), b = 12.751(3), c = 5.618(1) Å, β = 90.49(3)°, was determined by single crystal X-ray diffraction. MgSO 3 ·H 2 O crystallizes in the MnSO 3 ·H 2 O type. The structure consists of buckled trans la...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1998-02, Vol.53 (2), p.131-134 |
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| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
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| creator | Buchmeier, Willi Engelen, Bernward Müller, Holger |
| description | The crystal structure of MgSO
3
·H
2
O , space group P2
1
/ln, Z = 4, D
x
= 2.415 g·cm
-3
, a = 4.699(1), b = 12.751(3), c = 5.618(1) Å, β = 90.49(3)°, was determined by single crystal X-ray diffraction. MgSO
3
·H
2
O crystallizes in the MnSO
3
·H
2
O type. The structure consists of buckled trans layers
∞
[MgSO
3
·H
2
O], which are built up from strongly distorted MgO
5
(H
2
O) octahedra sharing four equatorial vertices, and of trigonal pyramidal SO
3
2-
ions. It is closely related to the structures of orthorhombic MnSeO
3
·D
2
O and monoclinic ZnSeO
3
·H
2
O . The Mg-O distances range from 2.051(3) to 2.175(4) Å. The S-O distances (1.543(3), 1.547(3) and 1.493(3) Å) and the O-S-O angles (98.4(2) and 2x 106.0(2)°) correspond to those in MnSO
3
·H
2
O . The distortion of the MO
5
(H
2
O) octahedra (M = Mg, Mn) and of the SO
3
2-
ions is smaller in MgSO
3
·H
2
O , but with greater deviations from m symmetry. The distances between the H-connected
∞
2
[MSO
3
·H
2
O] layers are greater in MgSO
3
·H
2
O , indicating weaker inter-layer hydrogen bonds. The lateral arrangement of the
∞
2
[MSO
3
·H
2
O] layers is nearly the same in both sulfite monohydrates. |
| doi_str_mv | 10.1515/znb-1998-0201 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1515_znb_1998_0201</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1515_znb_1998_0201</sourcerecordid><originalsourceid>FETCH-LOGICAL-c821-17d41ed6be56c08ac2a9d5c3368a122f47b319b0645e6b211a4e1444c0fdd03e3</originalsourceid><addsrcrecordid>eNo10L1OwzAYhWELgUQojOy-AdPv828yoghIRVGGdrccx0GF0CA7RSo3xs6VkQiYzvLoDC8h1wg3qFAtP_cNw6LIGXDAE5JhrhUziOaUZFAIzsAYfU4uUnoBwEJKyEj1GHdpdH2fxnh4HQ-Rfgx7-vS8qamg318VpzVdlvE4G7qZjJ9MoEM3GfqP6KQuyVnn-hSu_nZBtvd327Ji6_phVd6umc85MjStxNDqJijtIXeeu6JVXgidO-S8k6YRWDSgpQq64YhOBpRSeujaFkQQC8J-b30cUoqhs-9x9-bi0SLYuYKdKti5gp0riB9DtE6_</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Kristallstruktur von MgSO 3 ·H2 O /Crystal Structure of Mg SO 3 ·H 2 O</title><source>Alma/SFX Local Collection</source><creator>Buchmeier, Willi ; Engelen, Bernward ; Müller, Holger</creator><creatorcontrib>Buchmeier, Willi ; Engelen, Bernward ; Müller, Holger</creatorcontrib><description>The crystal structure of MgSO
3
·H
2
O , space group P2
1
/ln, Z = 4, D
x
= 2.415 g·cm
-3
, a = 4.699(1), b = 12.751(3), c = 5.618(1) Å, β = 90.49(3)°, was determined by single crystal X-ray diffraction. MgSO
3
·H
2
O crystallizes in the MnSO
3
·H
2
O type. The structure consists of buckled trans layers
∞
[MgSO
3
·H
2
O], which are built up from strongly distorted MgO
5
(H
2
O) octahedra sharing four equatorial vertices, and of trigonal pyramidal SO
3
2-
ions. It is closely related to the structures of orthorhombic MnSeO
3
·D
2
O and monoclinic ZnSeO
3
·H
2
O . The Mg-O distances range from 2.051(3) to 2.175(4) Å. The S-O distances (1.543(3), 1.547(3) and 1.493(3) Å) and the O-S-O angles (98.4(2) and 2x 106.0(2)°) correspond to those in MnSO
3
·H
2
O . The distortion of the MO
5
(H
2
O) octahedra (M = Mg, Mn) and of the SO
3
2-
ions is smaller in MgSO
3
·H
2
O , but with greater deviations from m symmetry. The distances between the H-connected
∞
2
[MSO
3
·H
2
O] layers are greater in MgSO
3
·H
2
O , indicating weaker inter-layer hydrogen bonds. The lateral arrangement of the
∞
2
[MSO
3
·H
2
O] layers is nearly the same in both sulfite monohydrates.</description><identifier>ISSN: 0932-0776</identifier><identifier>EISSN: 1865-7117</identifier><identifier>DOI: 10.1515/znb-1998-0201</identifier><language>eng</language><ispartof>Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1998-02, Vol.53 (2), p.131-134</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c821-17d41ed6be56c08ac2a9d5c3368a122f47b319b0645e6b211a4e1444c0fdd03e3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Buchmeier, Willi</creatorcontrib><creatorcontrib>Engelen, Bernward</creatorcontrib><creatorcontrib>Müller, Holger</creatorcontrib><title>Kristallstruktur von MgSO 3 ·H2 O /Crystal Structure of Mg SO 3 ·H 2 O</title><title>Zeitschrift für Naturforschung. B, A journal of chemical sciences</title><description>The crystal structure of MgSO
3
·H
2
O , space group P2
1
/ln, Z = 4, D
x
= 2.415 g·cm
-3
, a = 4.699(1), b = 12.751(3), c = 5.618(1) Å, β = 90.49(3)°, was determined by single crystal X-ray diffraction. MgSO
3
·H
2
O crystallizes in the MnSO
3
·H
2
O type. The structure consists of buckled trans layers
∞
[MgSO
3
·H
2
O], which are built up from strongly distorted MgO
5
(H
2
O) octahedra sharing four equatorial vertices, and of trigonal pyramidal SO
3
2-
ions. It is closely related to the structures of orthorhombic MnSeO
3
·D
2
O and monoclinic ZnSeO
3
·H
2
O . The Mg-O distances range from 2.051(3) to 2.175(4) Å. The S-O distances (1.543(3), 1.547(3) and 1.493(3) Å) and the O-S-O angles (98.4(2) and 2x 106.0(2)°) correspond to those in MnSO
3
·H
2
O . The distortion of the MO
5
(H
2
O) octahedra (M = Mg, Mn) and of the SO
3
2-
ions is smaller in MgSO
3
·H
2
O , but with greater deviations from m symmetry. The distances between the H-connected
∞
2
[MSO
3
·H
2
O] layers are greater in MgSO
3
·H
2
O , indicating weaker inter-layer hydrogen bonds. The lateral arrangement of the
∞
2
[MSO
3
·H
2
O] layers is nearly the same in both sulfite monohydrates.</description><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNo10L1OwzAYhWELgUQojOy-AdPv828yoghIRVGGdrccx0GF0CA7RSo3xs6VkQiYzvLoDC8h1wg3qFAtP_cNw6LIGXDAE5JhrhUziOaUZFAIzsAYfU4uUnoBwEJKyEj1GHdpdH2fxnh4HQ-Rfgx7-vS8qamg318VpzVdlvE4G7qZjJ9MoEM3GfqP6KQuyVnn-hSu_nZBtvd327Ji6_phVd6umc85MjStxNDqJijtIXeeu6JVXgidO-S8k6YRWDSgpQq64YhOBpRSeujaFkQQC8J-b30cUoqhs-9x9-bi0SLYuYKdKti5gp0riB9DtE6_</recordid><startdate>19980201</startdate><enddate>19980201</enddate><creator>Buchmeier, Willi</creator><creator>Engelen, Bernward</creator><creator>Müller, Holger</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19980201</creationdate><title>Kristallstruktur von MgSO 3 ·H2 O /Crystal Structure of Mg SO 3 ·H 2 O</title><author>Buchmeier, Willi ; Engelen, Bernward ; Müller, Holger</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c821-17d41ed6be56c08ac2a9d5c3368a122f47b319b0645e6b211a4e1444c0fdd03e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Buchmeier, Willi</creatorcontrib><creatorcontrib>Engelen, Bernward</creatorcontrib><creatorcontrib>Müller, Holger</creatorcontrib><collection>CrossRef</collection><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Buchmeier, Willi</au><au>Engelen, Bernward</au><au>Müller, Holger</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kristallstruktur von MgSO 3 ·H2 O /Crystal Structure of Mg SO 3 ·H 2 O</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>1998-02-01</date><risdate>1998</risdate><volume>53</volume><issue>2</issue><spage>131</spage><epage>134</epage><pages>131-134</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>The crystal structure of MgSO
3
·H
2
O , space group P2
1
/ln, Z = 4, D
x
= 2.415 g·cm
-3
, a = 4.699(1), b = 12.751(3), c = 5.618(1) Å, β = 90.49(3)°, was determined by single crystal X-ray diffraction. MgSO
3
·H
2
O crystallizes in the MnSO
3
·H
2
O type. The structure consists of buckled trans layers
∞
[MgSO
3
·H
2
O], which are built up from strongly distorted MgO
5
(H
2
O) octahedra sharing four equatorial vertices, and of trigonal pyramidal SO
3
2-
ions. It is closely related to the structures of orthorhombic MnSeO
3
·D
2
O and monoclinic ZnSeO
3
·H
2
O . The Mg-O distances range from 2.051(3) to 2.175(4) Å. The S-O distances (1.543(3), 1.547(3) and 1.493(3) Å) and the O-S-O angles (98.4(2) and 2x 106.0(2)°) correspond to those in MnSO
3
·H
2
O . The distortion of the MO
5
(H
2
O) octahedra (M = Mg, Mn) and of the SO
3
2-
ions is smaller in MgSO
3
·H
2
O , but with greater deviations from m symmetry. The distances between the H-connected
∞
2
[MSO
3
·H
2
O] layers are greater in MgSO
3
·H
2
O , indicating weaker inter-layer hydrogen bonds. The lateral arrangement of the
∞
2
[MSO
3
·H
2
O] layers is nearly the same in both sulfite monohydrates.</abstract><doi>10.1515/znb-1998-0201</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0932-0776 |
| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1998-02, Vol.53 (2), p.131-134 |
| issn | 0932-0776 1865-7117 |
| language | eng |
| recordid | cdi_crossref_primary_10_1515_znb_1998_0201 |
| source | Alma/SFX Local Collection |
| title | Kristallstruktur von MgSO 3 ·H2 O /Crystal Structure of Mg SO 3 ·H 2 O |
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