Darstellung und Kristallstruktur der Verbindungen MnCuX (X = P, As, PxAs1-x) / Preparation and Crystal Structure of Compounds MnCuX (X = P, As, PxAs1-x)

Three new ternary compounds MnCuP, MnCuP As and MnCuAs have been prepared and characterized by X-Ray, DTA and magnetic measurements. They crystallize orthorhombically in the space group P nma (No. 62). The structures were calculated from single crystal data. The melting points were determined by DTA...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1992-07, Vol.47 (7), p.925-928
Hauptverfasser: Mündelein, Joachim, Schuster, Hans-Uwe
Format: Artikel
Sprache:eng
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Zusammenfassung:Three new ternary compounds MnCuP, MnCuP As and MnCuAs have been prepared and characterized by X-Ray, DTA and magnetic measurements. They crystallize orthorhombically in the space group P nma (No. 62). The structures were calculated from single crystal data. The melting points were determined by DTA measurements (MnCuP: 1090°C; MnCuP As : 1000 °C; MnCuAs: 950 °C). MnCuAs appears to show an antiferromagnetic ordering up to 295 K.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-1992-0705