Zwei-und dreikernige Fluorooxoanionen des Vanadins. Kristallstrukturen von Cs(NMe4)[V2O2F8(H2O)] und (Na,K)(NMe4)2[V3O3F12] / Di- and Trinuclear Fluorooxoanions of Vanadium. Crystal Structures of Cs(NMe4)[VO2F8(H2O)] and (Na,K)(NMe4)2[V3O3F12]
From aqueous HF solutions the following fluorooxo complexes have been crystallized and characterized: A (NMe [V ] (1), A = Na. K; K (NMe )[V ]·H O (2); Cs(NMe )[V (H O)] (3) and NMe [VOF ] (4). The structures of 1 and 3 have been determined. Crystal data: 1c, hexagonal, space group P6 /m . a = 1695....
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1989-04, Vol.44 (4), p.383-388 |
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| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
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| creator | Hilbers, Martin Leimkühler, Manfred Mattes, Rainer |
| description | From aqueous HF solutions the following fluorooxo complexes have been crystallized and characterized: A
(NMe
[V
] (1), A
= Na. K; K
(NMe
)[V
]·H
O (2); Cs(NMe
)[V
(H
O)] (3) and NMe
[VOF
] (4). The structures of 1 and 3 have been determined.
Crystal data: 1c, hexagonal, space group P6
/m . a = 1695.0(9), c = 1248.1(5) pm. Z = 6: 1803 reflections. R = 0.045. 3, orthorhombic. space group Pnma, a = 2152.8(7), b = 751.5(2), c = 850.7(2) pm, Z = 4; 1379 reflections, R = 0.030. 1 contains a trimeric, cyclic anion with asymmetrically bonded μ-fluoroligands and terminal V = O groups in the same plane; the anion of 3 is a fluorobridged dimer with unequally coordinated vanadium atoms with terminal V = O groups. The preparation of these com pounds establishes the presence of VOF
(H
O)
species in aqueous solutions. |
| doi_str_mv | 10.1515/znb-1989-0403 |
| format | Article |
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(NMe
[V
] (1), A
= Na. K; K
(NMe
)[V
]·H
O (2); Cs(NMe
)[V
(H
O)] (3) and NMe
[VOF
] (4). The structures of 1 and 3 have been determined.
Crystal data: 1c, hexagonal, space group P6
/m . a = 1695.0(9), c = 1248.1(5) pm. Z = 6: 1803 reflections. R = 0.045. 3, orthorhombic. space group Pnma, a = 2152.8(7), b = 751.5(2), c = 850.7(2) pm, Z = 4; 1379 reflections, R = 0.030. 1 contains a trimeric, cyclic anion with asymmetrically bonded μ-fluoroligands and terminal V = O groups in the same plane; the anion of 3 is a fluorobridged dimer with unequally coordinated vanadium atoms with terminal V = O groups. The preparation of these com pounds establishes the presence of VOF
(H
O)
species in aqueous solutions.</description><identifier>ISSN: 0932-0776</identifier><identifier>EISSN: 1865-7117</identifier><identifier>DOI: 10.1515/znb-1989-0403</identifier><language>eng</language><publisher>Verlag der Zeitschrift für Naturforschung</publisher><subject>Crystal Structure ; Fluorooxovanadates(V)</subject><ispartof>Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1989-04, Vol.44 (4), p.383-388</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2393-734e03646deb5cfb1de8945704081f22897a96d37fe4d24da01ba336077ac0313</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Hilbers, Martin</creatorcontrib><creatorcontrib>Leimkühler, Manfred</creatorcontrib><creatorcontrib>Mattes, Rainer</creatorcontrib><title>Zwei-und dreikernige Fluorooxoanionen des Vanadins. Kristallstrukturen von Cs(NMe4)[V2O2F8(H2O)] und (Na,K)(NMe4)2[V3O3F12] / Di- and Trinuclear Fluorooxoanions of Vanadium. Crystal Structures of Cs(NMe4)[VO2F8(H2O)] and (Na,K)(NMe4)2[V3O3F12]</title><title>Zeitschrift für Naturforschung. B, A journal of chemical sciences</title><description>From aqueous HF solutions the following fluorooxo complexes have been crystallized and characterized: A
(NMe
[V
] (1), A
= Na. K; K
(NMe
)[V
]·H
O (2); Cs(NMe
)[V
(H
O)] (3) and NMe
[VOF
] (4). The structures of 1 and 3 have been determined.
Crystal data: 1c, hexagonal, space group P6
/m . a = 1695.0(9), c = 1248.1(5) pm. Z = 6: 1803 reflections. R = 0.045. 3, orthorhombic. space group Pnma, a = 2152.8(7), b = 751.5(2), c = 850.7(2) pm, Z = 4; 1379 reflections, R = 0.030. 1 contains a trimeric, cyclic anion with asymmetrically bonded μ-fluoroligands and terminal V = O groups in the same plane; the anion of 3 is a fluorobridged dimer with unequally coordinated vanadium atoms with terminal V = O groups. The preparation of these com pounds establishes the presence of VOF
(H
O)
species in aqueous solutions.</description><subject>Crystal Structure</subject><subject>Fluorooxovanadates(V)</subject><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNp1kUtLAzEUhYMoWB9L91m2YGpe88KVVKvS2i7ULiwypJOMpB0TSTpq_dv-ATNWUERX98I9936XcwA4ILhLIhIdvZkZIlmaIcwx2wAtksYRSghJNkELZ4winCTxNtjxfo4xyTjHLfB-96I0qo2E0im9UM7oBwX7VW2dta9WGG2NMlAqDyfCCKmN78KB034pqsovXb1Y1i4Inq2BPd8eXSnemU7omPbT9gUdd-5hc7s9EoeDznpKpxM2Zn1C7-ERPNUIiiC4cdrURaWE-8X20JZf5PqxC3tu1ZDhdSAXDflz_g3-wRX_cvfAVikqr_a_6i647Z_d9C7QcHx-2TsZooKyjKGEcYVZzGOpZlFRzohUacajJLibkpLSNEtEFkuWlIpLyqXAZCYYi4PLosCMsF2A1ncLZ713qsyfnH4UbpUTnDeJ5SGxvEksbxIL-uO1_kVUS-WkenD1KjT53NbOhE__3uOcs5SxDzD0mZw</recordid><startdate>19890401</startdate><enddate>19890401</enddate><creator>Hilbers, Martin</creator><creator>Leimkühler, Manfred</creator><creator>Mattes, Rainer</creator><general>Verlag der Zeitschrift für Naturforschung</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19890401</creationdate><title>Zwei-und dreikernige Fluorooxoanionen des Vanadins. Kristallstrukturen von Cs(NMe4)[V2O2F8(H2O)] und (Na,K)(NMe4)2[V3O3F12] / Di- and Trinuclear Fluorooxoanions of Vanadium. Crystal Structures of Cs(NMe4)[VO2F8(H2O)] and (Na,K)(NMe4)2[V3O3F12]</title><author>Hilbers, Martin ; Leimkühler, Manfred ; Mattes, Rainer</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2393-734e03646deb5cfb1de8945704081f22897a96d37fe4d24da01ba336077ac0313</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>Crystal Structure</topic><topic>Fluorooxovanadates(V)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hilbers, Martin</creatorcontrib><creatorcontrib>Leimkühler, Manfred</creatorcontrib><creatorcontrib>Mattes, Rainer</creatorcontrib><collection>CrossRef</collection><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hilbers, Martin</au><au>Leimkühler, Manfred</au><au>Mattes, Rainer</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Zwei-und dreikernige Fluorooxoanionen des Vanadins. Kristallstrukturen von Cs(NMe4)[V2O2F8(H2O)] und (Na,K)(NMe4)2[V3O3F12] / Di- and Trinuclear Fluorooxoanions of Vanadium. Crystal Structures of Cs(NMe4)[VO2F8(H2O)] and (Na,K)(NMe4)2[V3O3F12]</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>1989-04-01</date><risdate>1989</risdate><volume>44</volume><issue>4</issue><spage>383</spage><epage>388</epage><pages>383-388</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>From aqueous HF solutions the following fluorooxo complexes have been crystallized and characterized: A
(NMe
[V
] (1), A
= Na. K; K
(NMe
)[V
]·H
O (2); Cs(NMe
)[V
(H
O)] (3) and NMe
[VOF
] (4). The structures of 1 and 3 have been determined.
Crystal data: 1c, hexagonal, space group P6
/m . a = 1695.0(9), c = 1248.1(5) pm. Z = 6: 1803 reflections. R = 0.045. 3, orthorhombic. space group Pnma, a = 2152.8(7), b = 751.5(2), c = 850.7(2) pm, Z = 4; 1379 reflections, R = 0.030. 1 contains a trimeric, cyclic anion with asymmetrically bonded μ-fluoroligands and terminal V = O groups in the same plane; the anion of 3 is a fluorobridged dimer with unequally coordinated vanadium atoms with terminal V = O groups. The preparation of these com pounds establishes the presence of VOF
(H
O)
species in aqueous solutions.</abstract><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/znb-1989-0403</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0932-0776 |
| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1989-04, Vol.44 (4), p.383-388 |
| issn | 0932-0776 1865-7117 |
| language | eng |
| recordid | cdi_crossref_primary_10_1515_znb_1989_0403 |
| source | Alma/SFX Local Collection |
| subjects | Crystal Structure Fluorooxovanadates(V) |
| title | Zwei-und dreikernige Fluorooxoanionen des Vanadins. Kristallstrukturen von Cs(NMe4)[V2O2F8(H2O)] und (Na,K)(NMe4)2[V3O3F12] / Di- and Trinuclear Fluorooxoanions of Vanadium. Crystal Structures of Cs(NMe4)[VO2F8(H2O)] and (Na,K)(NMe4)2[V3O3F12] |
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