Die Struktur von [(tert-C4H9)3PI][W(CO)4l3] — ein Beitrag zur Diskussion des Akzeptorverhaltens von Iodphosphoniumionen/ The Structure of [(tert-C4H9)3PI][W(CO)4l3] — a Contribution on the Acceptor Properties of Iodophosphonium Ions
The structure of [t-Bu PI][W(CO) ] has been determined by X-ray diffraction. The anion of consists of a CO-capped distorted octahedron. One iodine atom of the anion acts as donor towards the iodophosphonium cation. In the I···I interaction is weaker and the P-I bond is stronger than in t-Bu PI . Str...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1989-01, Vol.44 (1), p.9-12 |
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| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
| container_volume | 44 |
| creator | Kuhn, Norbert Ralf, Jüschke Mont, Wolf-Walther du Bätcher, Michael Bläser, Dieter Boese, Roland |
| description | The structure of [t-Bu
PI][W(CO)
] has been determined by X-ray diffraction. The anion of
consists of a CO-capped distorted octahedron. One iodine atom of the anion acts as donor towards the iodophosphonium cation. In
the I···I interaction is weaker and the P-I bond is stronger than in t-Bu
PI
. Structural features of t-Bu
PI
cations are compared with those of the isoelectronic molecule t-Bu
P = Te. |
| doi_str_mv | 10.1515/znb-1989-0105 |
| format | Article |
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] has been determined by X-ray diffraction. The anion of
consists of a CO-capped distorted octahedron. One iodine atom of the anion acts as donor towards the iodophosphonium cation. In
the I···I interaction is weaker and the P-I bond is stronger than in t-Bu
PI
. Structural features of t-Bu
PI
cations are compared with those of the isoelectronic molecule t-Bu
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PI][W(CO)
] has been determined by X-ray diffraction. The anion of
consists of a CO-capped distorted octahedron. One iodine atom of the anion acts as donor towards the iodophosphonium cation. In
the I···I interaction is weaker and the P-I bond is stronger than in t-Bu
PI
. Structural features of t-Bu
PI
cations are compared with those of the isoelectronic molecule t-Bu
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PI][W(CO)
] has been determined by X-ray diffraction. The anion of
consists of a CO-capped distorted octahedron. One iodine atom of the anion acts as donor towards the iodophosphonium cation. In
the I···I interaction is weaker and the P-I bond is stronger than in t-Bu
PI
. Structural features of t-Bu
PI
cations are compared with those of the isoelectronic molecule t-Bu
P = Te.</abstract><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/znb-1989-0105</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0932-0776 |
| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1989-01, Vol.44 (1), p.9-12 |
| issn | 0932-0776 1865-7117 |
| language | eng |
| recordid | cdi_crossref_primary_10_1515_znb_1989_0105 |
| source | Alma/SFX Local Collection |
| subjects | Iodine-Iodine Interaction Iodophosphonium Ions X-Ray |
| title | Die Struktur von [(tert-C4H9)3PI][W(CO)4l3] — ein Beitrag zur Diskussion des Akzeptorverhaltens von Iodphosphoniumionen/ The Structure of [(tert-C4H9)3PI][W(CO)4l3] — a Contribution on the Acceptor Properties of Iodophosphonium Ions |
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