Enthalogenierung von Bis(diisopropylamino-chlorboryl)methan: Lösungsmittelabhängige Bildung eines 1,2,4,5-Tetraborinan-und eines 1-Aza-2,4-diborolidin-Derivats / Dehalogenation of Bis(diisopropylamino-chloroboryl)methane: Solvent-dependent Formation of a 1,2,4,5-Tetraborinane and of a 1-Aza-2,4-diborolidine Derivative

Enthalogenierung von Bis(diisopropylamino-chlorboryl)methan: Lösungsmittelabhängige Bildung eines 1,2,4,5-Tetraborinan-und eines 1-Aza-2,4-diborolidin-Derivats / Dehalogenation of Bis(diisopropylamino-chloroboryl)methane: Solvent-dependent Formation of a 1,2,4,5-Tetraborinane and of a 1-Aza-2,4-diborolidine Derivative

Dehalogenation of bis(diisopropylamino-chloroboryl)methane 1 b with sodium/potassium alloy in petroleum ether yields the 1,2,4,5-tetraborinane 2b (38%), whereas in tetrahydrofuran the five-membered 1-aza-2,4-diborolidine derivative 3a (36%) is formed. The constitution of 2b and 3a follows from spect...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1988-06, Vol.43 (6), p.658-664
Hauptverfasser: Fisch, Herbert, Pritzkow, Hans, Siebert, Walter
Format: Artikel
Sprache:eng
Schlagworte:
1-Aza-2
4-diborolidine Derivatives
5-tetraborinane
5-Tetrakis(diisopropylamino-chloroboryl)-1
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container_title Zeitschrift für Naturforschung. B, A journal of chemical sciences
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creator Fisch, Herbert
Pritzkow, Hans
Siebert, Walter
description Dehalogenation of bis(diisopropylamino-chloroboryl)methane 1 b with sodium/potassium alloy in petroleum ether yields the 1,2,4,5-tetraborinane 2b (38%), whereas in tetrahydrofuran the five-membered 1-aza-2,4-diborolidine derivative 3a (36%) is formed. The constitution of 2b and 3a follows from spectroscopic data and has been confirmed by X-ray structure analyses.
doi_str_mv 10.1515/znb-1988-0604
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subjects 1-Aza-2
4-diborolidine Derivatives
5-tetraborinane
5-Tetrakis(diisopropylamino-chloroboryl)-1
title Enthalogenierung von Bis(diisopropylamino-chlorboryl)methan: Lösungsmittelabhängige Bildung eines 1,2,4,5-Tetraborinan-und eines 1-Aza-2,4-diborolidin-Derivats / Dehalogenation of Bis(diisopropylamino-chloroboryl)methane: Solvent-dependent Formation of a 1,2,4,5-Tetraborinane and of a 1-Aza-2,4-diborolidine Derivative
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