Anthracen- und Phenanthren-Cobalt-Verbindungen mit Trimethylphosphan-Liganden / Anthracene and Phenanthrene Cobalt Compounds Containing Trimethylphosphane Ligands
Anthracene and phenanthrene complexes of zerovalent cobalt, Co(Cl )(PMe , are obtained by substitution of olefin in Co(olefin)(PMe (olefin = propene, cyclopentene). Ethene replaces the η -bonded aromatic molecules. Substitution labile ligands L′ in hydridocobalt complexes CoH(L′)(PMe (L′ = N , C ) g...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1985-10, Vol.40 (10), p.1377-1382 |
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| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
| container_volume | 40 |
| creator | Klein, Hans-Friedrich Ellrich, Klaus Lamac, Susanne Lull, Goetz Zsolnai, Laszlo Hüttner, Gottfried |
| description | Anthracene and phenanthrene complexes of zerovalent cobalt, Co(Cl
)(PMe
, are obtained by substitution of olefin in Co(olefin)(PMe
(olefin = propene, cyclopentene). Ethene replaces the η
-bonded aromatic molecules. Substitution labile ligands L′ in hydridocobalt complexes CoH(L′)(PMe
(L′ = N
, C
) give way to an anthracene or phenanthrene ligand and can in turn be replaced by carbon monoxide. η
-Coordinated anthracene in Co[Sn(C
](C
)(PMe
is not replaced by CO under normal conditions. In η
-coordinated anthracene the bond between coordinated C-atoms in ring positions 2 and 3 is elongated by 8.9 pm when compared with free anthracene, deviations from planarity of six-membered rings are slight. η
-Coordinated anthracene contains a naphthalin-type planar part and. in the coordinated ring with the longer CC-bonds, shows a folding away from the cobalt atom. |
| doi_str_mv | 10.1515/znb-1985-1023 |
| format | Article |
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)(PMe
, are obtained by substitution of olefin in Co(olefin)(PMe
(olefin = propene, cyclopentene). Ethene replaces the η
-bonded aromatic molecules. Substitution labile ligands L′ in hydridocobalt complexes CoH(L′)(PMe
(L′ = N
, C
) give way to an anthracene or phenanthrene ligand and can in turn be replaced by carbon monoxide. η
-Coordinated anthracene in Co[Sn(C
](C
)(PMe
is not replaced by CO under normal conditions. In η
-coordinated anthracene the bond between coordinated C-atoms in ring positions 2 and 3 is elongated by 8.9 pm when compared with free anthracene, deviations from planarity of six-membered rings are slight. η
-Coordinated anthracene contains a naphthalin-type planar part and. in the coordinated ring with the longer CC-bonds, shows a folding away from the cobalt atom.</description><identifier>ISSN: 0932-0776</identifier><identifier>EISSN: 1865-7117</identifier><identifier>DOI: 10.1515/znb-1985-1023</identifier><language>eng</language><publisher>Verlag der Zeitschrift für Naturforschung</publisher><subject>Structure ; Synthesis ; η2-Phenanthrene(trimethylphosphane) Cobalt ; η4- and η2-Anthracene</subject><ispartof>Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1985-10, Vol.40 (10), p.1377-1382</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1757-1f1847034d1eb129f9e8cf667073ef3b57dfe641ece1b24dcc6580cd9cbbd5823</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Klein, Hans-Friedrich</creatorcontrib><creatorcontrib>Ellrich, Klaus</creatorcontrib><creatorcontrib>Lamac, Susanne</creatorcontrib><creatorcontrib>Lull, Goetz</creatorcontrib><creatorcontrib>Zsolnai, Laszlo</creatorcontrib><creatorcontrib>Hüttner, Gottfried</creatorcontrib><title>Anthracen- und Phenanthren-Cobalt-Verbindungen mit Trimethylphosphan-Liganden / Anthracene and Phenanthrene Cobalt Compounds Containing Trimethylphosphane Ligands</title><title>Zeitschrift für Naturforschung. B, A journal of chemical sciences</title><description>Anthracene and phenanthrene complexes of zerovalent cobalt, Co(Cl
)(PMe
, are obtained by substitution of olefin in Co(olefin)(PMe
(olefin = propene, cyclopentene). Ethene replaces the η
-bonded aromatic molecules. Substitution labile ligands L′ in hydridocobalt complexes CoH(L′)(PMe
(L′ = N
, C
) give way to an anthracene or phenanthrene ligand and can in turn be replaced by carbon monoxide. η
-Coordinated anthracene in Co[Sn(C
](C
)(PMe
is not replaced by CO under normal conditions. In η
-coordinated anthracene the bond between coordinated C-atoms in ring positions 2 and 3 is elongated by 8.9 pm when compared with free anthracene, deviations from planarity of six-membered rings are slight. η
-Coordinated anthracene contains a naphthalin-type planar part and. in the coordinated ring with the longer CC-bonds, shows a folding away from the cobalt atom.</description><subject>Structure</subject><subject>Synthesis</subject><subject>η2-Phenanthrene(trimethylphosphane) Cobalt</subject><subject>η4- and η2-Anthracene</subject><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1985</creationdate><recordtype>article</recordtype><recordid>eNptkMlKA0EQhhtRMEaP3vsF2nTN1jMHDyG4QUAP0evQS80Skp7QPYPEx_FJ7WFEED1VUctXf_2EXAO_gRTSxYdVDIo8ZcCj-ITMIM9SJgDEKZnxIo4YFyI7JxfebzmHIkn4jHwubd84qdEyOlhDXxq0ciyFwqpTctezN3SqtWawNVq6b3u6ce0e--a4OzSdPzTSsnVbS2tCe0F_eEjlbx7SCRjC_tCFYz5ktpetbW39F4p0ovpLclbJncer7zgnr_d3m9UjWz8_PK2Wa6ZBpIJBBXkieJwYQAVRURWY6yrLBBcxVrFKhakwSwA1gooSo3WW5lybQitl0jyK54RNXO067x1W5SFoku5YAi9Hg8tgcDkaXI4Gh_nbaf49PIXOYO2GY0jKbTc4G5T-v5dw4BALEX8BrQeHsQ</recordid><startdate>19851001</startdate><enddate>19851001</enddate><creator>Klein, Hans-Friedrich</creator><creator>Ellrich, Klaus</creator><creator>Lamac, Susanne</creator><creator>Lull, Goetz</creator><creator>Zsolnai, Laszlo</creator><creator>Hüttner, Gottfried</creator><general>Verlag der Zeitschrift für Naturforschung</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19851001</creationdate><title>Anthracen- und Phenanthren-Cobalt-Verbindungen mit Trimethylphosphan-Liganden / Anthracene and Phenanthrene Cobalt Compounds Containing Trimethylphosphane Ligands</title><author>Klein, Hans-Friedrich ; Ellrich, Klaus ; Lamac, Susanne ; Lull, Goetz ; Zsolnai, Laszlo ; Hüttner, Gottfried</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1757-1f1847034d1eb129f9e8cf667073ef3b57dfe641ece1b24dcc6580cd9cbbd5823</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1985</creationdate><topic>Structure</topic><topic>Synthesis</topic><topic>η2-Phenanthrene(trimethylphosphane) Cobalt</topic><topic>η4- and η2-Anthracene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Klein, Hans-Friedrich</creatorcontrib><creatorcontrib>Ellrich, Klaus</creatorcontrib><creatorcontrib>Lamac, Susanne</creatorcontrib><creatorcontrib>Lull, Goetz</creatorcontrib><creatorcontrib>Zsolnai, Laszlo</creatorcontrib><creatorcontrib>Hüttner, Gottfried</creatorcontrib><collection>CrossRef</collection><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Klein, Hans-Friedrich</au><au>Ellrich, Klaus</au><au>Lamac, Susanne</au><au>Lull, Goetz</au><au>Zsolnai, Laszlo</au><au>Hüttner, Gottfried</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Anthracen- und Phenanthren-Cobalt-Verbindungen mit Trimethylphosphan-Liganden / Anthracene and Phenanthrene Cobalt Compounds Containing Trimethylphosphane Ligands</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>1985-10-01</date><risdate>1985</risdate><volume>40</volume><issue>10</issue><spage>1377</spage><epage>1382</epage><pages>1377-1382</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>Anthracene and phenanthrene complexes of zerovalent cobalt, Co(Cl
)(PMe
, are obtained by substitution of olefin in Co(olefin)(PMe
(olefin = propene, cyclopentene). Ethene replaces the η
-bonded aromatic molecules. Substitution labile ligands L′ in hydridocobalt complexes CoH(L′)(PMe
(L′ = N
, C
) give way to an anthracene or phenanthrene ligand and can in turn be replaced by carbon monoxide. η
-Coordinated anthracene in Co[Sn(C
](C
)(PMe
is not replaced by CO under normal conditions. In η
-coordinated anthracene the bond between coordinated C-atoms in ring positions 2 and 3 is elongated by 8.9 pm when compared with free anthracene, deviations from planarity of six-membered rings are slight. η
-Coordinated anthracene contains a naphthalin-type planar part and. in the coordinated ring with the longer CC-bonds, shows a folding away from the cobalt atom.</abstract><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/znb-1985-1023</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0932-0776 |
| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1985-10, Vol.40 (10), p.1377-1382 |
| issn | 0932-0776 1865-7117 |
| language | eng |
| recordid | cdi_crossref_primary_10_1515_znb_1985_1023 |
| source | Alma/SFX Local Collection |
| subjects | Structure Synthesis η2-Phenanthrene(trimethylphosphane) Cobalt η4- and η2-Anthracene |
| title | Anthracen- und Phenanthren-Cobalt-Verbindungen mit Trimethylphosphan-Liganden / Anthracene and Phenanthrene Cobalt Compounds Containing Trimethylphosphane Ligands |
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