Dinitrosylvanadiumkomplexe: [VL 4 (NO) 2 ]X, L = NCMe, THF, OCMe 2 ; X = Cl, Br, I / Dinitrosylvanadium Complexes: [VL 4 (NO) 2 ]X, L = NCMe, THF, OCMe 2 ; X = Cl, Br, I
The reaction between complexes [VH(CO) 6-n p n ] (n = 2, p n = Ph 2 P(CH 2 ) 2 PPh 2 ; n = 3, p n = MeC(CH 2 PPh 2 ) 3 ) and [CoX(NO) 2 ] 2 in THF, acetonitrile or acetone, L, yields the products cis-[VL 4 (NO) 2 ]X and [Co(CO) 3-m p n (NO)] (m = 0-3) via the intermediates [V(CO) 5-n p n (NO)] and [...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1984-12, Vol.39 (12), p.1647-1653 |
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| container_end_page | 1653 |
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| container_issue | 12 |
| container_start_page | 1647 |
| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
| container_volume | 39 |
| creator | Naumann, Fritz Rehder, Dieter |
| description | The reaction between complexes [VH(CO)
6-n
p
n
] (n = 2, p
n
= Ph
2
P(CH
2
)
2
PPh
2
; n = 3, p
n
= MeC(CH
2
PPh
2
)
3
) and [CoX(NO)
2
]
2
in THF, acetonitrile or acetone, L, yields the products cis-[VL
4
(NO)
2
]X and [Co(CO)
3-m
p
n
(NO)] (m = 0-3) via the intermediates [V(CO)
5-n
p
n
(NO)] and [V(X)L
3
(NO)]X. Exclusion of X from the first coordination sphere is based on the absence of any halogen dependence of the
51
V shielding. Optimized procedures for the preparation of the hydridovanadium and dinitrosylcobalt complexes are described. |
| doi_str_mv | 10.1515/znb-1984-1204 |
| format | Article |
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6-n
p
n
] (n = 2, p
n
= Ph
2
P(CH
2
)
2
PPh
2
; n = 3, p
n
= MeC(CH
2
PPh
2
)
3
) and [CoX(NO)
2
]
2
in THF, acetonitrile or acetone, L, yields the products cis-[VL
4
(NO)
2
]X and [Co(CO)
3-m
p
n
(NO)] (m = 0-3) via the intermediates [V(CO)
5-n
p
n
(NO)] and [V(X)L
3
(NO)]X. Exclusion of X from the first coordination sphere is based on the absence of any halogen dependence of the
51
V shielding. Optimized procedures for the preparation of the hydridovanadium and dinitrosylcobalt complexes are described.</description><identifier>ISSN: 0932-0776</identifier><identifier>EISSN: 1865-7117</identifier><identifier>DOI: 10.1515/znb-1984-1204</identifier><language>eng</language><ispartof>Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1984-12, Vol.39 (12), p.1647-1653</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c824-c0b0ea4ad56a108d02a71ea253851064027baec19d3e02040d13ca5ea3e3e5143</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Naumann, Fritz</creatorcontrib><creatorcontrib>Rehder, Dieter</creatorcontrib><title>Dinitrosylvanadiumkomplexe: [VL 4 (NO) 2 ]X, L = NCMe, THF, OCMe 2 ; X = Cl, Br, I / Dinitrosylvanadium Complexes: [VL 4 (NO) 2 ]X, L = NCMe, THF, OCMe 2 ; X = Cl, Br, I</title><title>Zeitschrift für Naturforschung. B, A journal of chemical sciences</title><description>The reaction between complexes [VH(CO)
6-n
p
n
] (n = 2, p
n
= Ph
2
P(CH
2
)
2
PPh
2
; n = 3, p
n
= MeC(CH
2
PPh
2
)
3
) and [CoX(NO)
2
]
2
in THF, acetonitrile or acetone, L, yields the products cis-[VL
4
(NO)
2
]X and [Co(CO)
3-m
p
n
(NO)] (m = 0-3) via the intermediates [V(CO)
5-n
p
n
(NO)] and [V(X)L
3
(NO)]X. Exclusion of X from the first coordination sphere is based on the absence of any halogen dependence of the
51
V shielding. Optimized procedures for the preparation of the hydridovanadium and dinitrosylcobalt complexes are described.</description><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1984</creationdate><recordtype>article</recordtype><recordid>eNqdkEtLw0AUhQdRMFaX7u9SIWPvnUceiosarS3EZlOkIBImyRSi6YOMivUf-S9NsTt3ru7hHvg4fIydEl6QJt3_Whac4khxEqj2mEdRoHlIFO4zD2MpOIZhcMiOnHtBpFgp9Nj3bb2s39qV2zQfZmmq-n3xulqsG_tpL-HpMQUFZ5PsHAQ8z3xI4RomyYP1YToa-pB1sWuuYNb9k8aHm9aHMfThLxSSHdX9F3vMDuamcfZkd3tsOrybJiOeZvfjZJDyMhKKl1igNcpUOjCEUYXChGSN0DLShIFCERbGlhRX0mKnCSuSpdHWSCutJiV7jP9iy26_a-08X7f1wrSbnDDfas47zflWc77VLH8AK4tmKw</recordid><startdate>19841201</startdate><enddate>19841201</enddate><creator>Naumann, Fritz</creator><creator>Rehder, Dieter</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19841201</creationdate><title>Dinitrosylvanadiumkomplexe: [VL 4 (NO) 2 ]X, L = NCMe, THF, OCMe 2 ; X = Cl, Br, I / Dinitrosylvanadium Complexes: [VL 4 (NO) 2 ]X, L = NCMe, THF, OCMe 2 ; X = Cl, Br, I</title><author>Naumann, Fritz ; Rehder, Dieter</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c824-c0b0ea4ad56a108d02a71ea253851064027baec19d3e02040d13ca5ea3e3e5143</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1984</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Naumann, Fritz</creatorcontrib><creatorcontrib>Rehder, Dieter</creatorcontrib><collection>CrossRef</collection><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Naumann, Fritz</au><au>Rehder, Dieter</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dinitrosylvanadiumkomplexe: [VL 4 (NO) 2 ]X, L = NCMe, THF, OCMe 2 ; X = Cl, Br, I / Dinitrosylvanadium Complexes: [VL 4 (NO) 2 ]X, L = NCMe, THF, OCMe 2 ; X = Cl, Br, I</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>1984-12-01</date><risdate>1984</risdate><volume>39</volume><issue>12</issue><spage>1647</spage><epage>1653</epage><pages>1647-1653</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>The reaction between complexes [VH(CO)
6-n
p
n
] (n = 2, p
n
= Ph
2
P(CH
2
)
2
PPh
2
; n = 3, p
n
= MeC(CH
2
PPh
2
)
3
) and [CoX(NO)
2
]
2
in THF, acetonitrile or acetone, L, yields the products cis-[VL
4
(NO)
2
]X and [Co(CO)
3-m
p
n
(NO)] (m = 0-3) via the intermediates [V(CO)
5-n
p
n
(NO)] and [V(X)L
3
(NO)]X. Exclusion of X from the first coordination sphere is based on the absence of any halogen dependence of the
51
V shielding. Optimized procedures for the preparation of the hydridovanadium and dinitrosylcobalt complexes are described.</abstract><doi>10.1515/znb-1984-1204</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0932-0776 |
| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1984-12, Vol.39 (12), p.1647-1653 |
| issn | 0932-0776 1865-7117 |
| language | eng |
| recordid | cdi_crossref_primary_10_1515_znb_1984_1204 |
| source | Alma/SFX Local Collection |
| title | Dinitrosylvanadiumkomplexe: [VL 4 (NO) 2 ]X, L = NCMe, THF, OCMe 2 ; X = Cl, Br, I / Dinitrosylvanadium Complexes: [VL 4 (NO) 2 ]X, L = NCMe, THF, OCMe 2 ; X = Cl, Br, I |
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