Notizen: Zum Verständnis der zentralen Rolle des Schwefels in Multi-Metall-Aggregaten mit verschiedener Elektronenpopulation: [S2WS2CoS2WS2]n- (n = 2, 3)/On the Central Role of Sulfur in Multi Metal Aggregates with Different Electron Populations: [S2WS2CoS2WS2]n-(n = 2, 3)

Notizen: Zum Verständnis der zentralen Rolle des Schwefels in Multi-Metall-Aggregaten mit verschiedener Elektronenpopulation: [S2WS2CoS2WS2]n- (n = 2, 3)/On the Central Role of Sulfur in Multi Metal Aggregates with Different Electron Populations: [S2WS2CoS2WS2]n-(n = 2, 3)

The hetero metal sulfur aggregates [Co(WS ] (with variable electron population: n = 2, 3) could be isolated as salts and characterized by physical measurements (in-cluding X-ray structure analysis). Experimental and theoretical investigations show that due to a strong metal → ligand electron delocal...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1983-04, Vol.38 (4), p.528-529
Hauptverfasser: Müller, Achim, Hellmann, Winfried, Schimanski, Uwe, Jostes, Rainer, Newton, William E.
Format: Artikel
Sprache:eng
Schlagworte:
Crystal Structure
Electronic Structure
Molecular Structure
Preparation
Thioanions
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container_end_page 529
container_issue 4
container_start_page 528
container_title Zeitschrift für Naturforschung. B, A journal of chemical sciences
container_volume 38
creator Müller, Achim
Hellmann, Winfried
Schimanski, Uwe
Jostes, Rainer
Newton, William E.
description The hetero metal sulfur aggregates [Co(WS ] (with variable electron population: n = 2, 3) could be isolated as salts and characterized by physical measurements (in-cluding X-ray structure analysis). Experimental and theoretical investigations show that due to a strong metal → ligand electron delocalisation WS4 (like MOS ) is a non-innocent ligand and that the additional charge upon reduction is located mainly at the S atoms of the ligand system.
doi_str_mv 10.1515/znb-1983-0424
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subjects Crystal Structure
Electronic Structure
Molecular Structure
Preparation
Thioanions
title Notizen: Zum Verständnis der zentralen Rolle des Schwefels in Multi-Metall-Aggregaten mit verschiedener Elektronenpopulation: [S2WS2CoS2WS2]n- (n = 2, 3)/On the Central Role of Sulfur in Multi Metal Aggregates with Different Electron Populations: [S2WS2CoS2WS2]n-(n = 2, 3)
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