The Microwave Spectrum of the Bimolecule Trifluoroacetic Acid · · · Cyclopropanecarboxylic Acid

The Microwave Spectrum of the Bimolecule Trifluoroacetic Acid · · · Cyclopropanecarboxylic Acid

We have investigated the microwave spectrum of the bimolecule trifluoroacetic acid • • • cyclo-propanecarboxylic acid in the region 1 to 4 GHz, where the low J transitions of this heavy complex appear. The measured μ -R branch transition frequencies were fitted to determine the rotational constants...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Zeitschrift für Naturforschung. A, A journal of physical sciences A journal of physical sciences, 1997-11, Vol.52 (11), p.803-810
Hauptverfasser: Antolínez, Sonja, Dreizler, Helmut, Storm, Volker, Sutter, Dieter H., Alonso, José L.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 810
container_issue 11
container_start_page 803
container_title Zeitschrift für Naturforschung. A, A journal of physical sciences
container_volume 52
creator Antolínez, Sonja
Dreizler, Helmut
Storm, Volker
Sutter, Dieter H.
Alonso, José L.
description We have investigated the microwave spectrum of the bimolecule trifluoroacetic acid • • • cyclo-propanecarboxylic acid in the region 1 to 4 GHz, where the low J transitions of this heavy complex appear. The measured μ -R branch transition frequencies were fitted to determine the rotational constants and three centrifugal distortion constants. With the assumption that the structures of the subunits remain unchanged upon complexation, the O • • • O distances of the hydrogen bridge bonds are determined as 2.62 A.
doi_str_mv 10.1515/zna-1997-1108
format Article
fullrecord <record><control><sourceid>walterdegruyter_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1515_zna_1997_1108</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1515_zna_1997_11085211803</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2423-22ab1a9c823fb69f10d975a1450981c247abd56c57a9419ebf06c7faaa3830d03</originalsourceid><addsrcrecordid>eNptkM1OwzAMgCMEEmNw5N4XCMRN0yQSlzHxJw1xYJwjN02gU7dUacsoL8adJ6PTdkSyZEv-bNkfIZfArkCAuP7eIAWtJQVg6ohMQOWCSmD6mEyY5illUmWn5KxtV4zxXMhsQorlh0ueKxvDFj9d8to428V-nQSfdGPntlqH2tm-dskyVr7uQwxoXVfZZGarMvn9OcR8sHVoYmhw4yzGInwN9QE6Jyce69ZdHPKUvN3fLeePdPHy8DSfLahNs5TTNMUCUFuVcl_k2gMrtRQImWBawchILEqRWyFRZ6Bd4VlupUdErjgrGZ8Sut87PtO20XnTxGqNcTDAzE6QGQWZnSCzEzTyN3t-i3XnYuneYz-MhVmFPm7GS_-fEymAYpz_AWg9b-c</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>The Microwave Spectrum of the Bimolecule Trifluoroacetic Acid · · · Cyclopropanecarboxylic Acid</title><source>Alma/SFX Local Collection</source><creator>Antolínez, Sonja ; Dreizler, Helmut ; Storm, Volker ; Sutter, Dieter H. ; Alonso, José L.</creator><creatorcontrib>Antolínez, Sonja ; Dreizler, Helmut ; Storm, Volker ; Sutter, Dieter H. ; Alonso, José L.</creatorcontrib><description>We have investigated the microwave spectrum of the bimolecule trifluoroacetic acid • • • cyclo-propanecarboxylic acid in the region 1 to 4 GHz, where the low J transitions of this heavy complex appear. The measured μ -R branch transition frequencies were fitted to determine the rotational constants and three centrifugal distortion constants. With the assumption that the structures of the subunits remain unchanged upon complexation, the O • • • O distances of the hydrogen bridge bonds are determined as 2.62 A.</description><identifier>ISSN: 0932-0784</identifier><identifier>EISSN: 1865-7109</identifier><identifier>DOI: 10.1515/zna-1997-1108</identifier><language>eng</language><publisher>Verlag der Zeitschrift für Naturforschung</publisher><ispartof>Zeitschrift für Naturforschung. A, A journal of physical sciences, 1997-11, Vol.52 (11), p.803-810</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2423-22ab1a9c823fb69f10d975a1450981c247abd56c57a9419ebf06c7faaa3830d03</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Antolínez, Sonja</creatorcontrib><creatorcontrib>Dreizler, Helmut</creatorcontrib><creatorcontrib>Storm, Volker</creatorcontrib><creatorcontrib>Sutter, Dieter H.</creatorcontrib><creatorcontrib>Alonso, José L.</creatorcontrib><title>The Microwave Spectrum of the Bimolecule Trifluoroacetic Acid · · · Cyclopropanecarboxylic Acid</title><title>Zeitschrift für Naturforschung. A, A journal of physical sciences</title><description>We have investigated the microwave spectrum of the bimolecule trifluoroacetic acid • • • cyclo-propanecarboxylic acid in the region 1 to 4 GHz, where the low J transitions of this heavy complex appear. The measured μ -R branch transition frequencies were fitted to determine the rotational constants and three centrifugal distortion constants. With the assumption that the structures of the subunits remain unchanged upon complexation, the O • • • O distances of the hydrogen bridge bonds are determined as 2.62 A.</description><issn>0932-0784</issn><issn>1865-7109</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNptkM1OwzAMgCMEEmNw5N4XCMRN0yQSlzHxJw1xYJwjN02gU7dUacsoL8adJ6PTdkSyZEv-bNkfIZfArkCAuP7eIAWtJQVg6ohMQOWCSmD6mEyY5illUmWn5KxtV4zxXMhsQorlh0ueKxvDFj9d8to428V-nQSfdGPntlqH2tm-dskyVr7uQwxoXVfZZGarMvn9OcR8sHVoYmhw4yzGInwN9QE6Jyce69ZdHPKUvN3fLeePdPHy8DSfLahNs5TTNMUCUFuVcl_k2gMrtRQImWBawchILEqRWyFRZ6Bd4VlupUdErjgrGZ8Sut87PtO20XnTxGqNcTDAzE6QGQWZnSCzEzTyN3t-i3XnYuneYz-MhVmFPm7GS_-fEymAYpz_AWg9b-c</recordid><startdate>19971101</startdate><enddate>19971101</enddate><creator>Antolínez, Sonja</creator><creator>Dreizler, Helmut</creator><creator>Storm, Volker</creator><creator>Sutter, Dieter H.</creator><creator>Alonso, José L.</creator><general>Verlag der Zeitschrift für Naturforschung</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19971101</creationdate><title>The Microwave Spectrum of the Bimolecule Trifluoroacetic Acid · · · Cyclopropanecarboxylic Acid</title><author>Antolínez, Sonja ; Dreizler, Helmut ; Storm, Volker ; Sutter, Dieter H. ; Alonso, José L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2423-22ab1a9c823fb69f10d975a1450981c247abd56c57a9419ebf06c7faaa3830d03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Antolínez, Sonja</creatorcontrib><creatorcontrib>Dreizler, Helmut</creatorcontrib><creatorcontrib>Storm, Volker</creatorcontrib><creatorcontrib>Sutter, Dieter H.</creatorcontrib><creatorcontrib>Alonso, José L.</creatorcontrib><collection>CrossRef</collection><jtitle>Zeitschrift für Naturforschung. A, A journal of physical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Antolínez, Sonja</au><au>Dreizler, Helmut</au><au>Storm, Volker</au><au>Sutter, Dieter H.</au><au>Alonso, José L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Microwave Spectrum of the Bimolecule Trifluoroacetic Acid · · · Cyclopropanecarboxylic Acid</atitle><jtitle>Zeitschrift für Naturforschung. A, A journal of physical sciences</jtitle><date>1997-11-01</date><risdate>1997</risdate><volume>52</volume><issue>11</issue><spage>803</spage><epage>810</epage><pages>803-810</pages><issn>0932-0784</issn><eissn>1865-7109</eissn><abstract>We have investigated the microwave spectrum of the bimolecule trifluoroacetic acid • • • cyclo-propanecarboxylic acid in the region 1 to 4 GHz, where the low J transitions of this heavy complex appear. The measured μ -R branch transition frequencies were fitted to determine the rotational constants and three centrifugal distortion constants. With the assumption that the structures of the subunits remain unchanged upon complexation, the O • • • O distances of the hydrogen bridge bonds are determined as 2.62 A.</abstract><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/zna-1997-1108</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0932-0784
ispartof Zeitschrift für Naturforschung. A, A journal of physical sciences, 1997-11, Vol.52 (11), p.803-810
issn 0932-0784
1865-7109
language eng
recordid cdi_crossref_primary_10_1515_zna_1997_1108
source Alma/SFX Local Collection
title The Microwave Spectrum of the Bimolecule Trifluoroacetic Acid · · · Cyclopropanecarboxylic Acid
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T16%3A30%3A14IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-walterdegruyter_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20Microwave%20Spectrum%20of%20the%20Bimolecule%20Trifluoroacetic%20Acid%20%C2%B7%20%C2%B7%20%C2%B7%20Cyclopropanecarboxylic%20Acid&rft.jtitle=Zeitschrift%20f%C3%BCr%20Naturforschung.%20A,%20A%20journal%20of%20physical%20sciences&rft.au=Antol%C3%ADnez,%20Sonja&rft.date=1997-11-01&rft.volume=52&rft.issue=11&rft.spage=803&rft.epage=810&rft.pages=803-810&rft.issn=0932-0784&rft.eissn=1865-7109&rft_id=info:doi/10.1515/zna-1997-1108&rft_dat=%3Cwalterdegruyter_cross%3E10_1515_zna_1997_11085211803%3C/walterdegruyter_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true