Quadrupole Hyperfine Structure in the Rotational Spectra of Sulfuryl Chloride

Quadrupole Hyperfine Structure in the Rotational Spectra of Sulfuryl Chloride

The nuclear quadrupole coupling of [ Cl, Cl]- and [ Cl, Cl]-sulfuryl chloride, SO Cl was investigated using waveguide microwave Fourier transform (MWFT) spectroscopy. The analysis was performed with direct diagonalization of the Hamiltonian matrix. It was possible to determine the complete coupling...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Zeitschrift für Naturforschung. A, A journal of physical sciences A journal of physical sciences, 1992-11, Vol.47 (11), p.1153-1156
Hauptverfasser: Merke, Ilona, Dreizler, Helmut
Format: Artikel
Sprache:eng
Schlagworte:
Atomic and molecular physics
Exact sciences and technology
Fine and hyperfine structure
Molecular properties and interactions with photons
Physics
Properties of molecules and molecular ions
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 1156
container_issue 11
container_start_page 1153
container_title Zeitschrift für Naturforschung. A, A journal of physical sciences
container_volume 47
creator Merke, Ilona
Dreizler, Helmut
description The nuclear quadrupole coupling of [ Cl, Cl]- and [ Cl, Cl]-sulfuryl chloride, SO Cl was investigated using waveguide microwave Fourier transform (MWFT) spectroscopy. The analysis was performed with direct diagonalization of the Hamiltonian matrix. It was possible to determine the complete coupling tensor with high accuracy. SO Cl : χaa ( Cl1) = χ Cl2) = -33.049(6) MHz, χ ( Cl1) = χ ( Cl2) = 40.356 (9) MHz, χ ( Cl1) = - χ Cl2) = + 52.67 (63) MHz. SO C137C1: xaa ( Cl)= -29.582(17) MHz, χ Cl) = 40.340(25) MHz, χ Cl)= +52.3(14) MHz, χ Cl)= -28.723(18) MHz, χ Cl) = 31.822(28) MHz, χ ,( Cl) = + 37.3(19) MHz. We also determined the quadrupole coupling constants in their principal axes system. In comparison with the structure, the z-axis of the coupling tensor was found to be tilted 2.0° out off the S-Cl bond axis
doi_str_mv 10.1515/zna-1992-1112
format Article
fullrecord <record><control><sourceid>walterdegruyter_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1515_zna_1992_1112</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1515_zna_1992_111247111153</sourcerecordid><originalsourceid>FETCH-LOGICAL-c359t-ab2da11b4a85addc6b1c10acf1937f097cec5dfe70acd27d0676bf95e68cf43c3</originalsourceid><addsrcrecordid>eNptkE1LxDAQhoMouK4evefgNZppmmZz8CCLuoIiunouaT7cLrEt-UDqr7fLiicvM8PwzAvzIHQO9BI48KvvThGQsiAAUBygGSwqTgRQeYhmVLKCULEoj9FJjFtKWcVFOUNPL1mZkIfeW7waBxtc21m8TiHrlIPFbYfTxuLXPqnU9p3yeD1YnYLCvcPr7F0Oo8fLje9Da-wpOnLKR3v22-fo_e72bbkij8_3D8ubR6IZl4mopjAKoCnVgitjdNWABqq0A8mEo1Joq7lxVkw7UwhDK1E1TnJbLbQrmWZzRPa5OvQxBuvqIbSfKow10Hrnop5c1DsX9c7FxF_s-UFFrbwLqtNt_DsqmRQg-YRd77Ev5ZMNxn6EPE5Dve1zmH6P_8eXYqrAGfsBVHR1Ew</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Quadrupole Hyperfine Structure in the Rotational Spectra of Sulfuryl Chloride</title><source>Alma/SFX Local Collection</source><creator>Merke, Ilona ; Dreizler, Helmut</creator><creatorcontrib>Merke, Ilona ; Dreizler, Helmut</creatorcontrib><description>The nuclear quadrupole coupling of [ Cl, Cl]- and [ Cl, Cl]-sulfuryl chloride, SO Cl was investigated using waveguide microwave Fourier transform (MWFT) spectroscopy. The analysis was performed with direct diagonalization of the Hamiltonian matrix. It was possible to determine the complete coupling tensor with high accuracy. SO Cl : χaa ( Cl1) = χ Cl2) = -33.049(6) MHz, χ ( Cl1) = χ ( Cl2) = 40.356 (9) MHz, χ ( Cl1) = - χ Cl2) = + 52.67 (63) MHz. SO C137C1: xaa ( Cl)= -29.582(17) MHz, χ Cl) = 40.340(25) MHz, χ Cl)= +52.3(14) MHz, χ Cl)= -28.723(18) MHz, χ Cl) = 31.822(28) MHz, χ ,( Cl) = + 37.3(19) MHz. We also determined the quadrupole coupling constants in their principal axes system. In comparison with the structure, the z-axis of the coupling tensor was found to be tilted 2.0° out off the S-Cl bond axis</description><identifier>ISSN: 0932-0784</identifier><identifier>EISSN: 1865-7109</identifier><identifier>DOI: 10.1515/zna-1992-1112</identifier><identifier>CODEN: ZNASEI</identifier><language>eng</language><publisher>Tübingen: Verlag der Zeitschrift für Naturforschung</publisher><subject>Atomic and molecular physics ; Exact sciences and technology ; Fine and hyperfine structure ; Molecular properties and interactions with photons ; Physics ; Properties of molecules and molecular ions</subject><ispartof>Zeitschrift für Naturforschung. A, A journal of physical sciences, 1992-11, Vol.47 (11), p.1153-1156</ispartof><rights>1993 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-ab2da11b4a85addc6b1c10acf1937f097cec5dfe70acd27d0676bf95e68cf43c3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=4397195$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Merke, Ilona</creatorcontrib><creatorcontrib>Dreizler, Helmut</creatorcontrib><title>Quadrupole Hyperfine Structure in the Rotational Spectra of Sulfuryl Chloride</title><title>Zeitschrift für Naturforschung. A, A journal of physical sciences</title><description>The nuclear quadrupole coupling of [ Cl, Cl]- and [ Cl, Cl]-sulfuryl chloride, SO Cl was investigated using waveguide microwave Fourier transform (MWFT) spectroscopy. The analysis was performed with direct diagonalization of the Hamiltonian matrix. It was possible to determine the complete coupling tensor with high accuracy. SO Cl : χaa ( Cl1) = χ Cl2) = -33.049(6) MHz, χ ( Cl1) = χ ( Cl2) = 40.356 (9) MHz, χ ( Cl1) = - χ Cl2) = + 52.67 (63) MHz. SO C137C1: xaa ( Cl)= -29.582(17) MHz, χ Cl) = 40.340(25) MHz, χ Cl)= +52.3(14) MHz, χ Cl)= -28.723(18) MHz, χ Cl) = 31.822(28) MHz, χ ,( Cl) = + 37.3(19) MHz. We also determined the quadrupole coupling constants in their principal axes system. In comparison with the structure, the z-axis of the coupling tensor was found to be tilted 2.0° out off the S-Cl bond axis</description><subject>Atomic and molecular physics</subject><subject>Exact sciences and technology</subject><subject>Fine and hyperfine structure</subject><subject>Molecular properties and interactions with photons</subject><subject>Physics</subject><subject>Properties of molecules and molecular ions</subject><issn>0932-0784</issn><issn>1865-7109</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1992</creationdate><recordtype>article</recordtype><recordid>eNptkE1LxDAQhoMouK4evefgNZppmmZz8CCLuoIiunouaT7cLrEt-UDqr7fLiicvM8PwzAvzIHQO9BI48KvvThGQsiAAUBygGSwqTgRQeYhmVLKCULEoj9FJjFtKWcVFOUNPL1mZkIfeW7waBxtc21m8TiHrlIPFbYfTxuLXPqnU9p3yeD1YnYLCvcPr7F0Oo8fLje9Da-wpOnLKR3v22-fo_e72bbkij8_3D8ubR6IZl4mopjAKoCnVgitjdNWABqq0A8mEo1Joq7lxVkw7UwhDK1E1TnJbLbQrmWZzRPa5OvQxBuvqIbSfKow10Hrnop5c1DsX9c7FxF_s-UFFrbwLqtNt_DsqmRQg-YRd77Ev5ZMNxn6EPE5Dve1zmH6P_8eXYqrAGfsBVHR1Ew</recordid><startdate>19921101</startdate><enddate>19921101</enddate><creator>Merke, Ilona</creator><creator>Dreizler, Helmut</creator><general>Verlag der Zeitschrift für Naturforschung</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19921101</creationdate><title>Quadrupole Hyperfine Structure in the Rotational Spectra of Sulfuryl Chloride</title><author>Merke, Ilona ; Dreizler, Helmut</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-ab2da11b4a85addc6b1c10acf1937f097cec5dfe70acd27d0676bf95e68cf43c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1992</creationdate><topic>Atomic and molecular physics</topic><topic>Exact sciences and technology</topic><topic>Fine and hyperfine structure</topic><topic>Molecular properties and interactions with photons</topic><topic>Physics</topic><topic>Properties of molecules and molecular ions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Merke, Ilona</creatorcontrib><creatorcontrib>Dreizler, Helmut</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Zeitschrift für Naturforschung. A, A journal of physical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Merke, Ilona</au><au>Dreizler, Helmut</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Quadrupole Hyperfine Structure in the Rotational Spectra of Sulfuryl Chloride</atitle><jtitle>Zeitschrift für Naturforschung. A, A journal of physical sciences</jtitle><date>1992-11-01</date><risdate>1992</risdate><volume>47</volume><issue>11</issue><spage>1153</spage><epage>1156</epage><pages>1153-1156</pages><issn>0932-0784</issn><eissn>1865-7109</eissn><coden>ZNASEI</coden><abstract>The nuclear quadrupole coupling of [ Cl, Cl]- and [ Cl, Cl]-sulfuryl chloride, SO Cl was investigated using waveguide microwave Fourier transform (MWFT) spectroscopy. The analysis was performed with direct diagonalization of the Hamiltonian matrix. It was possible to determine the complete coupling tensor with high accuracy. SO Cl : χaa ( Cl1) = χ Cl2) = -33.049(6) MHz, χ ( Cl1) = χ ( Cl2) = 40.356 (9) MHz, χ ( Cl1) = - χ Cl2) = + 52.67 (63) MHz. SO C137C1: xaa ( Cl)= -29.582(17) MHz, χ Cl) = 40.340(25) MHz, χ Cl)= +52.3(14) MHz, χ Cl)= -28.723(18) MHz, χ Cl) = 31.822(28) MHz, χ ,( Cl) = + 37.3(19) MHz. We also determined the quadrupole coupling constants in their principal axes system. In comparison with the structure, the z-axis of the coupling tensor was found to be tilted 2.0° out off the S-Cl bond axis</abstract><cop>Tübingen</cop><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/zna-1992-1112</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0932-0784
ispartof Zeitschrift für Naturforschung. A, A journal of physical sciences, 1992-11, Vol.47 (11), p.1153-1156
issn 0932-0784
1865-7109
language eng
recordid cdi_crossref_primary_10_1515_zna_1992_1112
source Alma/SFX Local Collection
subjects Atomic and molecular physics
Exact sciences and technology
Fine and hyperfine structure
Molecular properties and interactions with photons
Physics
Properties of molecules and molecular ions
title Quadrupole Hyperfine Structure in the Rotational Spectra of Sulfuryl Chloride
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-30T18%3A51%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-walterdegruyter_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Quadrupole%20Hyperfine%20Structure%20in%20the%20Rotational%20Spectra%20of%20Sulfuryl%20Chloride&rft.jtitle=Zeitschrift%20f%C3%BCr%20Naturforschung.%20A,%20A%20journal%20of%20physical%20sciences&rft.au=Merke,%20Ilona&rft.date=1992-11-01&rft.volume=47&rft.issue=11&rft.spage=1153&rft.epage=1156&rft.pages=1153-1156&rft.issn=0932-0784&rft.eissn=1865-7109&rft.coden=ZNASEI&rft_id=info:doi/10.1515/zna-1992-1112&rft_dat=%3Cwalterdegruyter_cross%3E10_1515_zna_1992_111247111153%3C/walterdegruyter_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true