A study of water exchange in wood by means of 2D NMR relaxation correlation and exchange

Two-dimensional T 1-T 2 1H NMR relaxation correlation spectra and T 2-T 2 relaxation exchange spectra for samples of spruce wood across the full moisture content range from 0% to >100% are presented. The T 1-T 2 spectra unambiguously identify water in different environments within the wood that o...

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Veröffentlicht in:Holzforschung 2010-02, Vol.64 (2), p.259-266
Hauptverfasser: Cox, Julia, McDonald, Peter J., Gardiner, Barry A.
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description Two-dimensional T 1-T 2 1H NMR relaxation correlation spectra and T 2-T 2 relaxation exchange spectra for samples of spruce wood across the full moisture content range from 0% to >100% are presented. The T 1-T 2 spectra unambiguously identify water in different environments within the wood that overlap in the corresponding and more traditional one-dimensional T 1 or T 2 experiment. The T 2-T 2 spectra unambiguously reveal the presence of water exchange between the lumen and cell wall above the fibre saturation point in sapwood. An estimate is made of the exchange rate: 1/30 to 1/3 ms-1.
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subjects exchange
nuclear magnetic resonance
relaxation
spruce
water
title A study of water exchange in wood by means of 2D NMR relaxation correlation and exchange
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