Effect of cooling rate of KOH activation process on activated carbons

Activated carbon was fabricated from rice husks by KOH activation. The effect of the initial cooling rate of activation on the pore structure in the activated carbon fabricated by KOH activation was investigated. The specific surface area of the activated carbon increased from 1813 to 2418 m2/g with...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Transactions of the Materials Research Society of Japan 2012/03/01, Vol.37(1), pp.57-60
Hauptverfasser: Tanaka, Hiroe, Toda, Ikumi, Maruyama, Hayato, Ono, Hiroki, Ohshio, Shigeo, Akasaka, Hiroki, Tanaka, Yoshihisa, Himeno, Syuji, Kokubu, Toshinori, Saitoh, Hidetoshi
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 60
container_issue 1
container_start_page 57
container_title Transactions of the Materials Research Society of Japan
container_volume 37
creator Tanaka, Hiroe
Toda, Ikumi
Maruyama, Hayato
Ono, Hiroki
Ohshio, Shigeo
Akasaka, Hiroki
Tanaka, Yoshihisa
Himeno, Syuji
Kokubu, Toshinori
Saitoh, Hidetoshi
description Activated carbon was fabricated from rice husks by KOH activation. The effect of the initial cooling rate of activation on the pore structure in the activated carbon fabricated by KOH activation was investigated. The specific surface area of the activated carbon increased from 1813 to 2418 m2/g with increasing the cooling rate from 3 to 32 ºC/min. The micropore diameter in the activated carbons was distributed approximately 0.6 and 1.1 nm. The micropore volume increased from 0.86 to 1.29 cm3/g with increasing initial cooling rate. The proportion of the volume Vmicro to the total pore volume Vtotal was calculated to be in the range from 90 to 96 %. Thus, the micropore structure of the activated carbon was strongly affected on the initial cooling rate on alkali activation.
doi_str_mv 10.14723/tmrsj.37.57
format Article
fullrecord <record><control><sourceid>jstage_cross</sourceid><recordid>TN_cdi_crossref_primary_10_14723_tmrsj_37_57</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>article_tmrsj_37_1_37_57_article_char_en</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3407-474424558c521616f7ae55db053f062dcd7a9625f07d89991135f1d96a7f477d3</originalsourceid><addsrcrecordid>eNpFkM1KAzEUhYMoWGp3PkAewBnzf2c2gpTRioVudB3S_NQZ2klJguDbW9tSV-eec797Fwehe0pqKoDxx7JLeag51BKu0ITRpqmokuQaTShvWMWFam_RLOeBEEIJMNHICeq6ELwtOAZsY9z24wYnU_yff18tsLGl_zaljyPep2h9zvgwnlPvsDVpHcd8h26C2WY_O-sUfb50H_NFtVy9vs2fl5XlgkAlQAgmpGysZFRRFcB4Kd2aSB6IYs46MK1iMhBwTdu2lHIZqGuVgSAAHJ-ih9Nfm2LOyQe9T_3OpB9NiT62oI8taA5awgF_OuFDLmbjL7BJpbdb_8_S08FlYb9M0n7kv3g3ZpE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Effect of cooling rate of KOH activation process on activated carbons</title><source>EZB-FREE-00999 freely available EZB journals</source><creator>Tanaka, Hiroe ; Toda, Ikumi ; Maruyama, Hayato ; Ono, Hiroki ; Ohshio, Shigeo ; Akasaka, Hiroki ; Tanaka, Yoshihisa ; Himeno, Syuji ; Kokubu, Toshinori ; Saitoh, Hidetoshi</creator><creatorcontrib>Tanaka, Hiroe ; Toda, Ikumi ; Maruyama, Hayato ; Ono, Hiroki ; Ohshio, Shigeo ; Akasaka, Hiroki ; Tanaka, Yoshihisa ; Himeno, Syuji ; Kokubu, Toshinori ; Saitoh, Hidetoshi</creatorcontrib><description>Activated carbon was fabricated from rice husks by KOH activation. The effect of the initial cooling rate of activation on the pore structure in the activated carbon fabricated by KOH activation was investigated. The specific surface area of the activated carbon increased from 1813 to 2418 m2/g with increasing the cooling rate from 3 to 32 ºC/min. The micropore diameter in the activated carbons was distributed approximately 0.6 and 1.1 nm. The micropore volume increased from 0.86 to 1.29 cm3/g with increasing initial cooling rate. The proportion of the volume Vmicro to the total pore volume Vtotal was calculated to be in the range from 90 to 96 %. Thus, the micropore structure of the activated carbon was strongly affected on the initial cooling rate on alkali activation.</description><identifier>ISSN: 1382-3469</identifier><identifier>EISSN: 2188-1650</identifier><identifier>DOI: 10.14723/tmrsj.37.57</identifier><language>eng</language><publisher>The Materials Research Society of Japan</publisher><subject>Activated Carbon ; KOH activation ; micro-pore ; Rice husk ; Specific surface area</subject><ispartof>Transactions of the Materials Research Society of Japan, 2012/03/01, Vol.37(1), pp.57-60</ispartof><rights>2012 The Materials Research Society of Japan</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3407-474424558c521616f7ae55db053f062dcd7a9625f07d89991135f1d96a7f477d3</citedby><cites>FETCH-LOGICAL-c3407-474424558c521616f7ae55db053f062dcd7a9625f07d89991135f1d96a7f477d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Tanaka, Hiroe</creatorcontrib><creatorcontrib>Toda, Ikumi</creatorcontrib><creatorcontrib>Maruyama, Hayato</creatorcontrib><creatorcontrib>Ono, Hiroki</creatorcontrib><creatorcontrib>Ohshio, Shigeo</creatorcontrib><creatorcontrib>Akasaka, Hiroki</creatorcontrib><creatorcontrib>Tanaka, Yoshihisa</creatorcontrib><creatorcontrib>Himeno, Syuji</creatorcontrib><creatorcontrib>Kokubu, Toshinori</creatorcontrib><creatorcontrib>Saitoh, Hidetoshi</creatorcontrib><title>Effect of cooling rate of KOH activation process on activated carbons</title><title>Transactions of the Materials Research Society of Japan</title><addtitle>Trans. Mat. Res. Soc. Japan</addtitle><description>Activated carbon was fabricated from rice husks by KOH activation. The effect of the initial cooling rate of activation on the pore structure in the activated carbon fabricated by KOH activation was investigated. The specific surface area of the activated carbon increased from 1813 to 2418 m2/g with increasing the cooling rate from 3 to 32 ºC/min. The micropore diameter in the activated carbons was distributed approximately 0.6 and 1.1 nm. The micropore volume increased from 0.86 to 1.29 cm3/g with increasing initial cooling rate. The proportion of the volume Vmicro to the total pore volume Vtotal was calculated to be in the range from 90 to 96 %. Thus, the micropore structure of the activated carbon was strongly affected on the initial cooling rate on alkali activation.</description><subject>Activated Carbon</subject><subject>KOH activation</subject><subject>micro-pore</subject><subject>Rice husk</subject><subject>Specific surface area</subject><issn>1382-3469</issn><issn>2188-1650</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNpFkM1KAzEUhYMoWGp3PkAewBnzf2c2gpTRioVudB3S_NQZ2klJguDbW9tSV-eec797Fwehe0pqKoDxx7JLeag51BKu0ITRpqmokuQaTShvWMWFam_RLOeBEEIJMNHICeq6ELwtOAZsY9z24wYnU_yff18tsLGl_zaljyPep2h9zvgwnlPvsDVpHcd8h26C2WY_O-sUfb50H_NFtVy9vs2fl5XlgkAlQAgmpGysZFRRFcB4Kd2aSB6IYs46MK1iMhBwTdu2lHIZqGuVgSAAHJ-ih9Nfm2LOyQe9T_3OpB9NiT62oI8taA5awgF_OuFDLmbjL7BJpbdb_8_S08FlYb9M0n7kv3g3ZpE</recordid><startdate>2012</startdate><enddate>2012</enddate><creator>Tanaka, Hiroe</creator><creator>Toda, Ikumi</creator><creator>Maruyama, Hayato</creator><creator>Ono, Hiroki</creator><creator>Ohshio, Shigeo</creator><creator>Akasaka, Hiroki</creator><creator>Tanaka, Yoshihisa</creator><creator>Himeno, Syuji</creator><creator>Kokubu, Toshinori</creator><creator>Saitoh, Hidetoshi</creator><general>The Materials Research Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2012</creationdate><title>Effect of cooling rate of KOH activation process on activated carbons</title><author>Tanaka, Hiroe ; Toda, Ikumi ; Maruyama, Hayato ; Ono, Hiroki ; Ohshio, Shigeo ; Akasaka, Hiroki ; Tanaka, Yoshihisa ; Himeno, Syuji ; Kokubu, Toshinori ; Saitoh, Hidetoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3407-474424558c521616f7ae55db053f062dcd7a9625f07d89991135f1d96a7f477d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Activated Carbon</topic><topic>KOH activation</topic><topic>micro-pore</topic><topic>Rice husk</topic><topic>Specific surface area</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tanaka, Hiroe</creatorcontrib><creatorcontrib>Toda, Ikumi</creatorcontrib><creatorcontrib>Maruyama, Hayato</creatorcontrib><creatorcontrib>Ono, Hiroki</creatorcontrib><creatorcontrib>Ohshio, Shigeo</creatorcontrib><creatorcontrib>Akasaka, Hiroki</creatorcontrib><creatorcontrib>Tanaka, Yoshihisa</creatorcontrib><creatorcontrib>Himeno, Syuji</creatorcontrib><creatorcontrib>Kokubu, Toshinori</creatorcontrib><creatorcontrib>Saitoh, Hidetoshi</creatorcontrib><collection>CrossRef</collection><jtitle>Transactions of the Materials Research Society of Japan</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tanaka, Hiroe</au><au>Toda, Ikumi</au><au>Maruyama, Hayato</au><au>Ono, Hiroki</au><au>Ohshio, Shigeo</au><au>Akasaka, Hiroki</au><au>Tanaka, Yoshihisa</au><au>Himeno, Syuji</au><au>Kokubu, Toshinori</au><au>Saitoh, Hidetoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of cooling rate of KOH activation process on activated carbons</atitle><jtitle>Transactions of the Materials Research Society of Japan</jtitle><addtitle>Trans. Mat. Res. Soc. Japan</addtitle><date>2012</date><risdate>2012</risdate><volume>37</volume><issue>1</issue><spage>57</spage><epage>60</epage><pages>57-60</pages><issn>1382-3469</issn><eissn>2188-1650</eissn><abstract>Activated carbon was fabricated from rice husks by KOH activation. The effect of the initial cooling rate of activation on the pore structure in the activated carbon fabricated by KOH activation was investigated. The specific surface area of the activated carbon increased from 1813 to 2418 m2/g with increasing the cooling rate from 3 to 32 ºC/min. The micropore diameter in the activated carbons was distributed approximately 0.6 and 1.1 nm. The micropore volume increased from 0.86 to 1.29 cm3/g with increasing initial cooling rate. The proportion of the volume Vmicro to the total pore volume Vtotal was calculated to be in the range from 90 to 96 %. Thus, the micropore structure of the activated carbon was strongly affected on the initial cooling rate on alkali activation.</abstract><pub>The Materials Research Society of Japan</pub><doi>10.14723/tmrsj.37.57</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1382-3469
ispartof Transactions of the Materials Research Society of Japan, 2012/03/01, Vol.37(1), pp.57-60
issn 1382-3469
2188-1650
language eng
recordid cdi_crossref_primary_10_14723_tmrsj_37_57
source EZB-FREE-00999 freely available EZB journals
subjects Activated Carbon
KOH activation
micro-pore
Rice husk
Specific surface area
title Effect of cooling rate of KOH activation process on activated carbons
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T01%3A42%3A18IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-jstage_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Effect%20of%20cooling%20rate%20of%20KOH%20activation%20process%20on%20activated%20carbons&rft.jtitle=Transactions%20of%20the%20Materials%20Research%20Society%20of%20Japan&rft.au=Tanaka,%20Hiroe&rft.date=2012&rft.volume=37&rft.issue=1&rft.spage=57&rft.epage=60&rft.pages=57-60&rft.issn=1382-3469&rft.eissn=2188-1650&rft_id=info:doi/10.14723/tmrsj.37.57&rft_dat=%3Cjstage_cross%3Earticle_tmrsj_37_1_37_57_article_char_en%3C/jstage_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true