Synthesis, Crystal Structure and IR Spectrum studies of 2-(4-Methyl-2-phenyl-4,5-dihydro-oxazol-4-ylmethyl)- isoindole-1,3-dione

Synthesis, Crystal Structure and IR Spectrum studies of 2-(4-Methyl-2-phenyl-4,5-dihydro-oxazol-4-ylmethyl)- isoindole-1,3-dione

The organo-amino compound of title 2-(4-methyl-2-phenyl-4,5-dihydro-oxazol-4-ylmethyl)-isoindole-1,3-dione was synthesized by the mixture of (4-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)methyl-4-methylbenzenesulfonate and isoindoline-1,3-dione in N,N-dimethylformamide with a yield of around 65%. The st...

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Veröffentlicht in:Mediterranean journal of chemistry 2019-09, Vol.9 (2), p.116-124
Hauptverfasser: Anouar, Alami, Dioukhane, Khadim, Aouine, Younas, El Omari, Mohamed, El Ammari, Lahcen, Saadi, Mohamed, Assani, Abderrazzak, Ouarsal, Rachid
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container_issue 2
container_start_page 116
container_title Mediterranean journal of chemistry
container_volume 9
creator Anouar, Alami
Dioukhane, Khadim
Aouine, Younas
El Omari, Mohamed
El Ammari, Lahcen
Saadi, Mohamed
Assani, Abderrazzak
Ouarsal, Rachid
description The organo-amino compound of title 2-(4-methyl-2-phenyl-4,5-dihydro-oxazol-4-ylmethyl)-isoindole-1,3-dione was synthesized by the mixture of (4-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)methyl-4-methylbenzenesulfonate and isoindoline-1,3-dione in N,N-dimethylformamide with a yield of around 65%. The structural study of the compound, C19H16N2O3, is realized using single crystal X-Ray diffraction which shows that this compound crystallizes in the monoclinic system (P21/c, Z = 4) with the unit cell parameters: a = 14.3728 (13) Ã…, b = 9.6829 (10) Ã…, c = 11.8964 (12) Ã… and β = 107.384 (3). The refinement of the structure by the least-squares method with complete matrix leads to the following reliability factors R/Rw are 0.044/0.130.In the crystal, the molecules are linked together by hydrogen bonds and π…π interactions.The Infrared spectroscopic studies show the bands confirming the presence of the groups C=O, C-O, C-N, -CH3, -CH2 and =CH. 
doi_str_mv 10.13171/mjc92190916245aa
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The structural study of the compound, C19H16N2O3, is realized using single crystal X-Ray diffraction which shows that this compound crystallizes in the monoclinic system (P21/c, Z = 4) with the unit cell parameters: a = 14.3728 (13) Ã…, b = 9.6829 (10) Ã…, c = 11.8964 (12) Ã… and β = 107.384 (3). 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