Dioxomolybdenum (VI) Compounds of Macrocyclic Schiff base Ligands: Preparation, Characterization and Antibacterial Activity

Dioxomolybdenum (VI) Compounds of Macrocyclic Schiff base Ligands: Preparation, Characterization and Antibacterial Activity

Using di-2-furanylethanedione and 5-bromo-3-methylbenzene-1,2-diamine we prepared a monomeric [MoO2(SL)] with a Schiff base, as well as 4 different compounds using the formulation [MoO2(MSL). We investigate how [MoO2(SL)] reacts with 1,3-diketones. Several characterizations are discussed in this art...

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Veröffentlicht in:Oriental journal of chemistry 2024-05, Vol.40 (1), p.28-39
Hauptverfasser: Katiyar, Shikha, Rao, Devendra Pratap, Verma, Narendra Kumar, Gautam, Amit Kumar, Verma, Ashish, Singh, Chandra Prakash, Shankar, Vijay, Gautam, Yashveer
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container_end_page 39
container_issue 1
container_start_page 28
container_title Oriental journal of chemistry
container_volume 40
creator Katiyar, Shikha
Rao, Devendra Pratap
Verma, Narendra Kumar
Gautam, Amit Kumar
Verma, Ashish
Singh, Chandra Prakash
Shankar, Vijay
Gautam, Yashveer
description Using di-2-furanylethanedione and 5-bromo-3-methylbenzene-1,2-diamine we prepared a monomeric [MoO2(SL)] with a Schiff base, as well as 4 different compounds using the formulation [MoO2(MSL). We investigate how [MoO2(SL)] reacts with 1,3-diketones. Several characterizations are discussed in this article, including molar conductance measurement, elemental analysis, UV-Vis, IR, NMR, and thermal measurements. Molybdenum has a six-coordination number. All five MoO2(VI) compounds have distorted octahedral arrangements. Molybdenum octahedra have four N-atoms and two oxidized O-atoms. Against S. aureus and S. typhi, all synthesized compounds showed moderate activity. The chelation hypothesis is used to define the progression of the antibacterial task.
doi_str_mv 10.13005/ojc/400104
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