SYNTHESES OF VALIDAMINE, EPI-VALIDAMINE, AND VALIENAMINE, THREE OPTICALLY ACTIVE PSEUDO-AMINO-SUGARS, FROM D-GLUCOSE

Using as a key reaction a Michael-type addition reaction to nitroolefins or a substitution reaction for an acetoxyl residue at the β-position of the nitro group in pseudo-nitro-sugar, three optically active pseudo-amino-sugars: validamine, epi-validamine, and valienamine, were synthesized from D-glu...

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Veröffentlicht in:	Chemical & pharmaceutical bulletin 1988/10/25, Vol.36(10), pp.4236-4239
Hauptverfasser:	Yoshikawa, Masayuki, Cha, Bae Cheon, Okaichi, Yoshihiko, Takinami, Yoshihiko, Yokokawa, Yoshihiro, Kitagawa, Isao
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides Carbohydrates. Nucleosides and nucleotides Chemistry epivalidamine Exact sciences and technology Michael-type addition Organic chemistry Preparations and properties pseudo-amino-sugar optically active pseudo-amino-sugar synthesis pseudo-nitro-sugar validamine valienamine
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