HALOGENATION OF 1, 2, 3-TRIAZINES

4, 6-Dimethyl-1, 2, 3-triazine was treated with bromine and chlorine under mild conditions to give the corresponding 5-halo derivatives. The electrophlic addition-elimination mechanism was suggested by the results of reactions using interhalogens such as BrCl, ICl, and IBr as the reagents.

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1986/10/25, Vol.34(10), pp.4432-4434
Hauptverfasser: Kaihoh, Terumitsu, Ohsawa, Akio, Itoh, Takashi, Arai, Heihachiro, Igeta, Hiroshi
Format: Artikel
Sprache:eng
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Zusammenfassung:4, 6-Dimethyl-1, 2, 3-triazine was treated with bromine and chlorine under mild conditions to give the corresponding 5-halo derivatives. The electrophlic addition-elimination mechanism was suggested by the results of reactions using interhalogens such as BrCl, ICl, and IBr as the reagents.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.34.4432