THE USE OF A VERSATILE BUILDING BLOCK HAVING TWO CHIRAL CENTERS A TOTAL SYNTHESIS OF (-)-OUDEMANSIN

(-)-Oudemansin (4) has been synthesized from the chiral synthon 2 obtained by microbiological asymmetric reduction of the prochiral β-keto ester 1.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical & pharmaceutical bulletin 1984/03/25, Vol.32(3), pp.1242-1243
Hauptverfasser:	Akita, Hiroyuki, Koshiji, Hiroko, Furuichi, Akiya, Horikoshi, Koki, Oishi, Takeshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Noncondensed benzenic compounds Organic chemistry Preparations and properties α-methyl β-hydroxy ester
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	(-)-Oudemansin (4) has been synthesized from the chiral synthon 2 obtained by microbiological asymmetric reduction of the prochiral β-keto ester 1.
ISSN:	0009-2363 1347-5223
DOI:	10.1248/cpb.32.1242