Investigations on Steroids. III. Pyrolytic Elimination of the Tertiary 17β-Hydroxyl Group
Pyrolysis of androstane derivatives which contain 17β-hydroxy-17α-methyl grouping was shown to afford three kinds of dehydration products : 17-methyl- 16, 17-methylene, and 17, 17-dimethyl-18-nor- 13-compounds. The last compound was formed by a Wagner-Meerwein type rearrangement.
Gespeichert in:
| Veröffentlicht in: | Chemical & pharmaceutical bulletin 1964/01/25, Vol.12(1), pp.92-100 |
|---|---|
| 1. Verfasser: | |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | Pyrolysis of androstane derivatives which contain 17β-hydroxy-17α-methyl grouping was shown to afford three kinds of dehydration products : 17-methyl- 16, 17-methylene, and 17, 17-dimethyl-18-nor- 13-compounds. The last compound was formed by a Wagner-Meerwein type rearrangement. |
|---|---|
| ISSN: | 0009-2363 1347-5223 |
| DOI: | 10.1248/cpb.12.92 |