Tin Tetra(tert-butoxide) with Acid–Base Additives: Valid Catalyst Precursors for Direct Synthesis of Dimethyl Carbonate from CO2 and CH3OH
Sn(Ot-Bu)4 is a user-friendly precatalyst for the direct synthesis of dimethyl carbonate from CO2 and MeOH. It is far more active than the conventional Bu2Sn(OMe)2 catalysts. The addition of acid and/or base cocatalysts as well as optimization of the CO2 pressure improved the catalytic activity. The...
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| Veröffentlicht in: | Chemistry letters 2011-12, Vol.40 (12), p.1408-1410 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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