Click Chemistry on Curdlan: A Regioselective and Quantitative Approach to Develop Artificial β-1,3-Glucans with Various Functional Appendages

Click Chemistry on Curdlan: A Regioselective and Quantitative Approach to Develop Artificial β-1,3-Glucans with Various Functional Appendages

β-1,3-Glucans having various functional appendages (lactoside, ferrocene, pyrene, etc.) can be prepared in an convenient, quantitative, and regioselective manner through chemo-selective [3 + 2]-cycloadditions between 6-azido-6-deoxy-curdlan and various functional modules with a terminal alkyne.

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Veröffentlicht in:Chemistry letters 2006-01, Vol.35 (1), p.82-83
Hauptverfasser: Hasegawa, Teruaki, Umeda, Mariko, Numata, Munenori, Fujisawa, Tomohisa, Haraguchi, Shuichi, Sakurai, Kazuo, Shinkai, Seiji
Format: Artikel
Sprache:eng
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Zusammenfassung:β-1,3-Glucans having various functional appendages (lactoside, ferrocene, pyrene, etc.) can be prepared in an convenient, quantitative, and regioselective manner through chemo-selective [3 + 2]-cycloadditions between 6-azido-6-deoxy-curdlan and various functional modules with a terminal alkyne.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2006.82