Structure and Magnetic Properties of a Honeycomb-like Copper(II) Complex Containing 4-Aminopyrimidine and Methoxide Bridges

Structure and Magnetic Properties of a Honeycomb-like Copper(II) Complex Containing 4-Aminopyrimidine and Methoxide Bridges

Complexation of Cu(NO3)2 with 4-aminopyrimidine (4APM) in methanol gave [Cu(4APM)(NO3)(OCH3)]n which crystallizes in a trigonal space group . The three-dimensional network affords a tube-like cavity. Magnetic measurements revealed the presence of considerably large antiferromagnetic interaction due...

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Veröffentlicht in:Chemistry letters 2005-04, Vol.34 (4), p.620-621
Hauptverfasser: Osanai, Keita, Ishida, Takayuki, Nogami, Takashi
Format: Artikel
Sprache:eng
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Zusammenfassung:Complexation of Cu(NO3)2 with 4-aminopyrimidine (4APM) in methanol gave [Cu(4APM)(NO3)(OCH3)]n which crystallizes in a trigonal space group . The three-dimensional network affords a tube-like cavity. Magnetic measurements revealed the presence of considerably large antiferromagnetic interaction due to the four-membered Cu2O2 structure.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2005.620