Stepwise Preparation of Linear π-Conjugated Bis(terpyridine)metal Polymer Chains at Gold Surface

Stepwise Preparation of Linear π-Conjugated Bis(terpyridine)metal Polymer Chains at Gold Surface

Defect-free structures of a film composed of linear redox polymer chains were prepared using stepwise complexation of Fe(II) and/or Co(II/III) ions with azobenzene-bridged bis(tpy) (tpy = 2,2′:6′,2″-terpyridine) ligands, tpy–AB–tpy, on tpy-terminated SAM on gold. This method realizes a formation of...

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Veröffentlicht in:Chemistry letters 2005-04, Vol.34 (4), p.534-535
Hauptverfasser: Kanaizuka, Katsuhiko, Murata, Masaki, Nishimori, Yoshihiko, Mori, Ichiro, Nishio, Kazuyuki, Masuda, Hideki, Nishihara, Hiroshi
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container_end_page 535
container_issue 4
container_start_page 534
container_title Chemistry letters
container_volume 34
creator Kanaizuka, Katsuhiko
Murata, Masaki
Nishimori, Yoshihiko
Mori, Ichiro
Nishio, Kazuyuki
Masuda, Hideki
Nishihara, Hiroshi
description Defect-free structures of a film composed of linear redox polymer chains were prepared using stepwise complexation of Fe(II) and/or Co(II/III) ions with azobenzene-bridged bis(tpy) (tpy = 2,2′:6′,2″-terpyridine) ligands, tpy–AB–tpy, on tpy-terminated SAM on gold. This method realizes a formation of desired number of polymer units (for example, 47-mer of Co(tpy)2) and a desired sequence of Co–Fe heterometal structures in the polymer chain (for example, 10-mer of Co(tpy)2 plus 5-mer of Fe(tpy)2).
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source Oxford University Press Journals All Titles (1996-Current)
title Stepwise Preparation of Linear π-Conjugated Bis(terpyridine)metal Polymer Chains at Gold Surface
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