A New Method for α-Selective Glycosylation Using a Donor, Glycosyl Methyldiphenylphosphonium Iodide, without Any Assistance of Acid Promoters

A mild and highly α-selective glycosylation of several glycosyl acceptors was performed with an in situ formed glycosyl donor, benzyl-protected glycosyl methyldiphenylphosphonium iodide, to afford the corresponding α-disaccharides in high yields in CH2Cl2 at room temperature without any assistance o...

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Veröffentlicht in:Chemistry letters 2003, Vol.32 (10), p.900-901
Hauptverfasser: Mukaiyama, Teruaki, Kobashi, Yohei, Shintou, Taichi
Format: Artikel
Sprache:eng
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