n-Channel Transistor of 1,5-Dibromo-2,6-naphthoquinhydrone

n-Channel Transistor of 1,5-Dibromo-2,6-naphthoquinhydrone

Quinhydrone is regarded as a donor-acceptor complex composed of hydroquinone and quinone. Here we show that 1,5-dibromo-2,6-naphthoquinhydrone shows electron transport in the transistors. The donor and acceptor frontier orbitals are approximately the same, but in addition to the strong acceptor abil...

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Veröffentlicht in:Chemistry letters 2019-03, Vol.48 (3), p.264-266
Hauptverfasser: Sato, Ryonosuke, Yoo, Dongho, Higashino, Toshiki, Mori, Takehiko
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container_end_page 266
container_issue 3
container_start_page 264
container_title Chemistry letters
container_volume 48
creator Sato, Ryonosuke
Yoo, Dongho
Higashino, Toshiki
Mori, Takehiko
description Quinhydrone is regarded as a donor-acceptor complex composed of hydroquinone and quinone. Here we show that 1,5-dibromo-2,6-naphthoquinhydrone shows electron transport in the transistors. The donor and acceptor frontier orbitals are approximately the same, but in addition to the strong acceptor ability of the quinone, enhancing and canceling contributions of the second bridge orbital result in monopolar transport.
doi_str_mv 10.1246/cl.181002
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source Oxford University Press Journals All Titles (1996-Current)
title n-Channel Transistor of 1,5-Dibromo-2,6-naphthoquinhydrone
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