Comparative Studies on the Stability of a Chelate-Ring Unit in Dynamic Aspects. Chelate-Rings of the Cu(II) Complexes Composed of [N-(Glycyl)], [N-(β-Alanyl)], and [N-(2-Aminoethyl)] Moieties

The kinetic stability of a chelate-ring unit in Cu(H−1GlyGly), Cu(H−1β-AlaGly), and Cu(EDMA) complexes has been inspected by stopped-flow spectroscopy. Those three Cu(II) complexes reacted with cysteine (CysH) or penicillamine (PesH) to form primarily ternary complexes, formulated as Cu(H−1L)(Rs−);...

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2004-04, Vol.77 (4), p.699-707
Hauptverfasser: Hanaki, Akira, Ozawa, Toshihiko, Funahashi, Yasuhiro, Odani, Akira
Format: Artikel
Sprache:eng
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