The γ-Silicon Effect. II. The Substituent Effect on the Solvolysis of 3-(Aryldimethylsilyl)-2,2-dimethylpropyl p-Bromobenzenesulfonates

Solvolysis rates of 3-(aryldimethylsilyl)-2,2-dimethylpropyl p-bromobenzenesulfonates were determined in 60% (v/v) aqueous ethanol (60E) and 97% (w/w) aqueous 2,2,2-trifluoroethanol (97Tw) at 50 °C. The effects of aryl substituents at the silyl atom on these solvolyses were correlated with unexalted...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Bulletin of the Chemical Society of Japan 1999-05, Vol.72 (5), p.1043-1047
Hauptverfasser:	Nakashima, Tohru, Fujiyama, Ryoji, Fujio, Mizue, Tsuno, Yuho
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!