Thermal Rearrangement of 3-Allyloxy-1,2-Benzisothiazole 1,1-Dioxides: An Unusual Inversion of Products of Sigmatropic [3,3]-Shift to Give the [1,3]-Isomers
3-Allyloxy-1,2-benzisothiazole 1,1-dioxides 4 isomerize thermally to give [3,3]- and [1,3]-products 5, 6 of sigmatropic shift, of which the former reacts further to give solely the [1,3]-isomer.
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| Veröffentlicht in: | Journal of chemical research 1999-12, Vol.23 (12), p.704-705 |
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| container_end_page | 705 |
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| container_issue | 12 |
| container_start_page | 704 |
| container_title | Journal of chemical research |
| container_volume | 23 |
| creator | Cristiano, M. Lurdes S. Brigas, Amadeu F. Johnstone, Robert A. W. Loureiro, Rui M. S. Pena, Paula C. A. |
| description | 3-Allyloxy-1,2-benzisothiazole 1,1-dioxides 4 isomerize thermally to give [3,3]- and [1,3]-products 5, 6 of sigmatropic shift, of which the former reacts further to give solely the [1,3]-isomer. |
| doi_str_mv | 10.1177/174751989902301210 |
| format | Article |
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| identifier | ISSN: 1747-5198 |
| ispartof | Journal of chemical research, 1999-12, Vol.23 (12), p.704-705 |
| issn | 1747-5198 2047-6507 |
| language | eng |
| recordid | cdi_crossref_primary_10_1177_174751989902301210 |
| source | Sage Journals GOLD Open Access 2024 |
| title | Thermal Rearrangement of 3-Allyloxy-1,2-Benzisothiazole 1,1-Dioxides: An Unusual Inversion of Products of Sigmatropic [3,3]-Shift to Give the [1,3]-Isomers |
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