A Selective Chemosensor for Mercuric Ions Based on 4-Aminothiophenol-Ruthenium(II) Bis(bipyridine) Complex

A Selective Chemosensor for Mercuric Ions Based on 4-Aminothiophenol-Ruthenium(II) Bis(bipyridine) Complex

A new ruthenium(II) complex (cis-ruthenium-bis[2,2′-bipyridine]-bis[4-aminothiophenol]-bis[hexafluorophosphate]) has been synthesized and characterized using standard analytical and spectroscopic techniques, FTIR, 1H and 13C-NMR, UV/vis, elemental analysis, conductivity measurements, and potentiomet...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:International journal of inorganic chemistry 2011-05, Vol.2011 (2011), p.1-6
Hauptverfasser: al-Khateeb, Mohammad, al-Abdel Hamid, Amer A. G., Tahat, Ziyad A., Qudah, Mahmoud, Obeidat, Safwan M., Rawashdeh, Abdel Monem
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 6
container_issue 2011
container_start_page 1
container_title International journal of inorganic chemistry
container_volume 2011
creator al-Khateeb, Mohammad
al-Abdel Hamid, Amer A. G.
Tahat, Ziyad A.
Qudah, Mahmoud
Obeidat, Safwan M.
Rawashdeh, Abdel Monem
description A new ruthenium(II) complex (cis-ruthenium-bis[2,2′-bipyridine]-bis[4-aminothiophenol]-bis[hexafluorophosphate]) has been synthesized and characterized using standard analytical and spectroscopic techniques, FTIR, 1H and 13C-NMR, UV/vis, elemental analysis, conductivity measurements, and potentiometric titration. Investigation of the synthesized complex with metal ions showed that this complex has photochemical properties that are selective and sensitive toward the presence of mercuric ion in aqueous solution. The detection limit for mercuric ions using UV/vis spectroscopy was estimated to be ~ 0.4 ppm. The results presented herein may have an important implication in the development of a spectroscopic selective detection for mercuric ions in aqueous solution.
doi_str_mv 10.1155/2011/843051
format Article
fullrecord <record><control><sourceid>emarefa_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1155_2011_843051</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>502674</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2381-2b4d71347dcb5a7b25d5c7f437dfabafb3658d9cc930e6e751cdd83f03b52dc53</originalsourceid><addsrcrecordid>eNqFkDtrwzAUhUVpoSHN1LmgMWlxo4cVOWNi-jCkFPqYjS1dYQXbMlLSNv--Di5Ze-Fwz_Bxhg-ha0ruKRVizgil8yTmRNAzNGJkSSJGeHx-6mxxiSYhbEl_fMkkESO0XeF3qEHt7BfgtILGBWiD89j0eQGv9t4qnLk24HURQGPX4jhaNbZ1u8q6roLW1dHbftcXu2-mWTbDaxumpe0O3mrbwgynrulq-LlCF6aoA0z-_hh9Pj58pM_R5vUpS1ebSDGe0IiVsZaUx1KrUhSyZEILJU3MpTZFWZiSL0Sil0otOYEFSEGV1gk3hJeCaSX4GN0Nu8q7EDyYvPO2KfwhpyQ_msqPpvLBVE_fDnRlW11823_gmwGGHgFTnGDRy5Ux_wXvu3H4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A Selective Chemosensor for Mercuric Ions Based on 4-Aminothiophenol-Ruthenium(II) Bis(bipyridine) Complex</title><source>Wiley-Blackwell Open Access Collection</source><source>Alma/SFX Local Collection</source><creator>al-Khateeb, Mohammad ; al-Abdel Hamid, Amer A. G. ; Tahat, Ziyad A. ; Qudah, Mahmoud ; Obeidat, Safwan M. ; Rawashdeh, Abdel Monem</creator><contributor>Wong, W. T.</contributor><creatorcontrib>al-Khateeb, Mohammad ; al-Abdel Hamid, Amer A. G. ; Tahat, Ziyad A. ; Qudah, Mahmoud ; Obeidat, Safwan M. ; Rawashdeh, Abdel Monem ; Wong, W. T.</creatorcontrib><description>A new ruthenium(II) complex (cis-ruthenium-bis[2,2′-bipyridine]-bis[4-aminothiophenol]-bis[hexafluorophosphate]) has been synthesized and characterized using standard analytical and spectroscopic techniques, FTIR, 1H and 13C-NMR, UV/vis, elemental analysis, conductivity measurements, and potentiometric titration. Investigation of the synthesized complex with metal ions showed that this complex has photochemical properties that are selective and sensitive toward the presence of mercuric ion in aqueous solution. The detection limit for mercuric ions using UV/vis spectroscopy was estimated to be ~ 0.4 ppm. The results presented herein may have an important implication in the development of a spectroscopic selective detection for mercuric ions in aqueous solution.</description><identifier>ISSN: 2090-2026</identifier><identifier>EISSN: 2090-2034</identifier><identifier>DOI: 10.1155/2011/843051</identifier><language>eng</language><publisher>Cairo, Egypt: Hindawi Puplishing Corporation</publisher><ispartof>International journal of inorganic chemistry, 2011-05, Vol.2011 (2011), p.1-6</ispartof><rights>Copyright © 2011 Amer A. G. Al Abdel Hamid et al.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2381-2b4d71347dcb5a7b25d5c7f437dfabafb3658d9cc930e6e751cdd83f03b52dc53</citedby><cites>FETCH-LOGICAL-c2381-2b4d71347dcb5a7b25d5c7f437dfabafb3658d9cc930e6e751cdd83f03b52dc53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><contributor>Wong, W. T.</contributor><creatorcontrib>al-Khateeb, Mohammad</creatorcontrib><creatorcontrib>al-Abdel Hamid, Amer A. G.</creatorcontrib><creatorcontrib>Tahat, Ziyad A.</creatorcontrib><creatorcontrib>Qudah, Mahmoud</creatorcontrib><creatorcontrib>Obeidat, Safwan M.</creatorcontrib><creatorcontrib>Rawashdeh, Abdel Monem</creatorcontrib><title>A Selective Chemosensor for Mercuric Ions Based on 4-Aminothiophenol-Ruthenium(II) Bis(bipyridine) Complex</title><title>International journal of inorganic chemistry</title><description>A new ruthenium(II) complex (cis-ruthenium-bis[2,2′-bipyridine]-bis[4-aminothiophenol]-bis[hexafluorophosphate]) has been synthesized and characterized using standard analytical and spectroscopic techniques, FTIR, 1H and 13C-NMR, UV/vis, elemental analysis, conductivity measurements, and potentiometric titration. Investigation of the synthesized complex with metal ions showed that this complex has photochemical properties that are selective and sensitive toward the presence of mercuric ion in aqueous solution. The detection limit for mercuric ions using UV/vis spectroscopy was estimated to be ~ 0.4 ppm. The results presented herein may have an important implication in the development of a spectroscopic selective detection for mercuric ions in aqueous solution.</description><issn>2090-2026</issn><issn>2090-2034</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>RHX</sourceid><recordid>eNqFkDtrwzAUhUVpoSHN1LmgMWlxo4cVOWNi-jCkFPqYjS1dYQXbMlLSNv--Di5Ze-Fwz_Bxhg-ha0ruKRVizgil8yTmRNAzNGJkSSJGeHx-6mxxiSYhbEl_fMkkESO0XeF3qEHt7BfgtILGBWiD89j0eQGv9t4qnLk24HURQGPX4jhaNbZ1u8q6roLW1dHbftcXu2-mWTbDaxumpe0O3mrbwgynrulq-LlCF6aoA0z-_hh9Pj58pM_R5vUpS1ebSDGe0IiVsZaUx1KrUhSyZEILJU3MpTZFWZiSL0Sil0otOYEFSEGV1gk3hJeCaSX4GN0Nu8q7EDyYvPO2KfwhpyQ_msqPpvLBVE_fDnRlW11823_gmwGGHgFTnGDRy5Ux_wXvu3H4</recordid><startdate>20110529</startdate><enddate>20110529</enddate><creator>al-Khateeb, Mohammad</creator><creator>al-Abdel Hamid, Amer A. G.</creator><creator>Tahat, Ziyad A.</creator><creator>Qudah, Mahmoud</creator><creator>Obeidat, Safwan M.</creator><creator>Rawashdeh, Abdel Monem</creator><general>Hindawi Puplishing Corporation</general><general>Hindawi Publishing Corporation</general><scope>ADJCN</scope><scope>AHFXO</scope><scope>RHU</scope><scope>RHW</scope><scope>RHX</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20110529</creationdate><title>A Selective Chemosensor for Mercuric Ions Based on 4-Aminothiophenol-Ruthenium(II) Bis(bipyridine) Complex</title><author>al-Khateeb, Mohammad ; al-Abdel Hamid, Amer A. G. ; Tahat, Ziyad A. ; Qudah, Mahmoud ; Obeidat, Safwan M. ; Rawashdeh, Abdel Monem</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2381-2b4d71347dcb5a7b25d5c7f437dfabafb3658d9cc930e6e751cdd83f03b52dc53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>al-Khateeb, Mohammad</creatorcontrib><creatorcontrib>al-Abdel Hamid, Amer A. G.</creatorcontrib><creatorcontrib>Tahat, Ziyad A.</creatorcontrib><creatorcontrib>Qudah, Mahmoud</creatorcontrib><creatorcontrib>Obeidat, Safwan M.</creatorcontrib><creatorcontrib>Rawashdeh, Abdel Monem</creatorcontrib><collection>الدوريات العلمية والإحصائية - e-Marefa Academic and Statistical Periodicals</collection><collection>معرفة - المحتوى العربي الأكاديمي المتكامل - e-Marefa Academic Complete</collection><collection>Hindawi Publishing Complete</collection><collection>Hindawi Publishing Subscription Journals</collection><collection>Hindawi Publishing Open Access</collection><collection>CrossRef</collection><jtitle>International journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>al-Khateeb, Mohammad</au><au>al-Abdel Hamid, Amer A. G.</au><au>Tahat, Ziyad A.</au><au>Qudah, Mahmoud</au><au>Obeidat, Safwan M.</au><au>Rawashdeh, Abdel Monem</au><au>Wong, W. T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Selective Chemosensor for Mercuric Ions Based on 4-Aminothiophenol-Ruthenium(II) Bis(bipyridine) Complex</atitle><jtitle>International journal of inorganic chemistry</jtitle><date>2011-05-29</date><risdate>2011</risdate><volume>2011</volume><issue>2011</issue><spage>1</spage><epage>6</epage><pages>1-6</pages><issn>2090-2026</issn><eissn>2090-2034</eissn><abstract>A new ruthenium(II) complex (cis-ruthenium-bis[2,2′-bipyridine]-bis[4-aminothiophenol]-bis[hexafluorophosphate]) has been synthesized and characterized using standard analytical and spectroscopic techniques, FTIR, 1H and 13C-NMR, UV/vis, elemental analysis, conductivity measurements, and potentiometric titration. Investigation of the synthesized complex with metal ions showed that this complex has photochemical properties that are selective and sensitive toward the presence of mercuric ion in aqueous solution. The detection limit for mercuric ions using UV/vis spectroscopy was estimated to be ~ 0.4 ppm. The results presented herein may have an important implication in the development of a spectroscopic selective detection for mercuric ions in aqueous solution.</abstract><cop>Cairo, Egypt</cop><pub>Hindawi Puplishing Corporation</pub><doi>10.1155/2011/843051</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 2090-2026
ispartof International journal of inorganic chemistry, 2011-05, Vol.2011 (2011), p.1-6
issn 2090-2026
2090-2034
language eng
recordid cdi_crossref_primary_10_1155_2011_843051
source Wiley-Blackwell Open Access Collection; Alma/SFX Local Collection
title A Selective Chemosensor for Mercuric Ions Based on 4-Aminothiophenol-Ruthenium(II) Bis(bipyridine) Complex
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T16%3A06%3A49IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-emarefa_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20Selective%20Chemosensor%20for%20Mercuric%20Ions%20Based%20on%204-Aminothiophenol-Ruthenium(II)%20Bis(bipyridine)%20Complex&rft.jtitle=International%20journal%20of%20inorganic%20chemistry&rft.au=al-Khateeb,%20Mohammad&rft.date=2011-05-29&rft.volume=2011&rft.issue=2011&rft.spage=1&rft.epage=6&rft.pages=1-6&rft.issn=2090-2026&rft.eissn=2090-2034&rft_id=info:doi/10.1155/2011/843051&rft_dat=%3Cemarefa_cross%3E502674%3C/emarefa_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true