Towards Better Stability and Reversibility of Mn 2+ /Mn 4+ Double Redox Activity in Disordered Rocksalt Oxyfluoride Cathode Materials
Recently discovered cation disordered rocksalt (DRS) materials have shown high reversibility towards Li ions due to facile insertion and extraction in the structure. Nonetheless, issues with manganese containing compounds have been identified due to instabilities of the structure and/or solubility o...
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| creator | Shirazimoghadam, Yasaman El kharbachi, Abdel Fichtner, Maximilian |
| description | Recently discovered cation disordered rocksalt (DRS) materials have shown high reversibility towards Li ions due to facile insertion and extraction in the structure. Nonetheless, issues with manganese containing compounds have been identified due to instabilities of the structure and/or solubility of manganese in the electrolyte. In our study, we combined the use of high-valent cations with partial substitution of fluorine for oxygen anions in DRS-structure phase to achieve optimal Mn
2+
/Mn
4+
double-redox reaction in the composition system Li
2
Mn
x
Ti
1-x
O
2
F (1/3 ≤ x ≤ 1). Four different compositions (Li
2
Mn
III
O
2
F, Li
2
Mn
II
1/3
Mn
III
1/3
Ti
IV
1/3
O
2
F, Li
2
Mn
II
1/2
Ti
IV
1/2
O
2
F and Li
2
Mn
II
1/3
Ti
III
1/3
Ti
IV
1/3
O
2
F) have been synthesized and optimized according to the starting precursors and their oxidation states. By studying the electrochemical behavior of different compounds, we found that Ti
+4
keeps Mn at the second state of charge in the structure which lead to double redox reaction of Mn
2+
/Mn
4+
. Galvanostatic cycling and rate capability tests of the sample with the composition Li
2
Mn
2/3
Ti
1/3
O
2
F showed notable electrochemical kinetics and cycling performance, with initial high discharge capacity of 227 mAh g
-1
in the voltage window of 1.5-4.3 V and 82% coulombic efficiency after 100 cycles.In a further study, synthesis related issues and limitations due to fluorination were examined. In fact, lithium diffusion can be impeded due to preferable strong Li-F bonds. Thus, two more samples based on the Li
2
Mn
2/3
Ti
1/3
O
2
F composition were synthesized and their properties were investigated (Li
1.5
Mn
II
1/3
Mn
III
1/3
Ti
IV
1/3
O
2
F
0.5
and Li
1.25
Mn
II
1/3
Mn
III
1/3
Ti
IV
1/3
O
2
F
0.25
), in order to find the proper amount of fluorine which compromises the structural/chemical stability and electrochemical storage against Li-ions.We will present and discuss the structural characteristics of these selected DRS materials using XRD-Rietveld refinement analysis, energy-dispersive X-ray spectroscopy and scanning electron microscopy. The oxidation states and charge transfer mechanism using a combination of CV and XPS will be also addressed, in which the results approve the double redox mechanism of Mn
2+
/Mn
4+
in agreement with Mn-Ti structural charge compensation. The findings pave the way for designing high capacity electrode materials with multi-electron redox reactions.
Figure 1 |
| doi_str_mv | 10.1149/MA2021-014251mtgabs |
| format | Article |
| fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1149_MA2021_014251mtgabs</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1149_MA2021_014251mtgabs</sourcerecordid><originalsourceid>FETCH-crossref_primary_10_1149_MA2021_014251mtgabs3</originalsourceid><addsrcrecordid>eNqdj01LAzEQhoMoWKu_wMvcy9p87EI91lbxsgi295DdZDWabmQmrd0f4P82xSKePT3D8L4zPIxdC34jRHk7reeSS1FwUcpKbNKLaeiEjaSoRCG5qk5_51KdswuiN87VbCbliH2t46dBS3DnUnIIq2QaH3wawPQWnt3OIfnjJnZQ9yAnMM0oJ7CM2ya4HLJxD_M2-d0h5XtYeopoHbp8IbbvZEKCp_3QhW1Ebx0sTHqNmbXJL70JdMnOugx3deSYqYf79eKxaDESoev0B_qNwUELrg_G-sdY_zVW_2t9AyqrYsU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Towards Better Stability and Reversibility of Mn 2+ /Mn 4+ Double Redox Activity in Disordered Rocksalt Oxyfluoride Cathode Materials</title><source>IOP Publishing Free Content</source><source>Free Full-Text Journals in Chemistry</source><creator>Shirazimoghadam, Yasaman ; El kharbachi, Abdel ; Fichtner, Maximilian</creator><creatorcontrib>Shirazimoghadam, Yasaman ; El kharbachi, Abdel ; Fichtner, Maximilian</creatorcontrib><description>Recently discovered cation disordered rocksalt (DRS) materials have shown high reversibility towards Li ions due to facile insertion and extraction in the structure. Nonetheless, issues with manganese containing compounds have been identified due to instabilities of the structure and/or solubility of manganese in the electrolyte. In our study, we combined the use of high-valent cations with partial substitution of fluorine for oxygen anions in DRS-structure phase to achieve optimal Mn
2+
/Mn
4+
double-redox reaction in the composition system Li
2
Mn
x
Ti
1-x
O
2
F (1/3 ≤ x ≤ 1). Four different compositions (Li
2
Mn
III
O
2
F, Li
2
Mn
II
1/3
Mn
III
1/3
Ti
IV
1/3
O
2
F, Li
2
Mn
II
1/2
Ti
IV
1/2
O
2
F and Li
2
Mn
II
1/3
Ti
III
1/3
Ti
IV
1/3
O
2
F) have been synthesized and optimized according to the starting precursors and their oxidation states. By studying the electrochemical behavior of different compounds, we found that Ti
+4
keeps Mn at the second state of charge in the structure which lead to double redox reaction of Mn
2+
/Mn
4+
. Galvanostatic cycling and rate capability tests of the sample with the composition Li
2
Mn
2/3
Ti
1/3
O
2
F showed notable electrochemical kinetics and cycling performance, with initial high discharge capacity of 227 mAh g
-1
in the voltage window of 1.5-4.3 V and 82% coulombic efficiency after 100 cycles.In a further study, synthesis related issues and limitations due to fluorination were examined. In fact, lithium diffusion can be impeded due to preferable strong Li-F bonds. Thus, two more samples based on the Li
2
Mn
2/3
Ti
1/3
O
2
F composition were synthesized and their properties were investigated (Li
1.5
Mn
II
1/3
Mn
III
1/3
Ti
IV
1/3
O
2
F
0.5
and Li
1.25
Mn
II
1/3
Mn
III
1/3
Ti
IV
1/3
O
2
F
0.25
), in order to find the proper amount of fluorine which compromises the structural/chemical stability and electrochemical storage against Li-ions.We will present and discuss the structural characteristics of these selected DRS materials using XRD-Rietveld refinement analysis, energy-dispersive X-ray spectroscopy and scanning electron microscopy. The oxidation states and charge transfer mechanism using a combination of CV and XPS will be also addressed, in which the results approve the double redox mechanism of Mn
2+
/Mn
4+
in agreement with Mn-Ti structural charge compensation. The findings pave the way for designing high capacity electrode materials with multi-electron redox reactions.
Figure 1</description><identifier>ISSN: 2151-2043</identifier><identifier>EISSN: 2151-2035</identifier><identifier>DOI: 10.1149/MA2021-014251mtgabs</identifier><language>eng</language><ispartof>Meeting abstracts (Electrochemical Society), 2021-05, Vol.MA2021-01 (4), p.251-251</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Shirazimoghadam, Yasaman</creatorcontrib><creatorcontrib>El kharbachi, Abdel</creatorcontrib><creatorcontrib>Fichtner, Maximilian</creatorcontrib><title>Towards Better Stability and Reversibility of Mn 2+ /Mn 4+ Double Redox Activity in Disordered Rocksalt Oxyfluoride Cathode Materials</title><title>Meeting abstracts (Electrochemical Society)</title><description>Recently discovered cation disordered rocksalt (DRS) materials have shown high reversibility towards Li ions due to facile insertion and extraction in the structure. Nonetheless, issues with manganese containing compounds have been identified due to instabilities of the structure and/or solubility of manganese in the electrolyte. In our study, we combined the use of high-valent cations with partial substitution of fluorine for oxygen anions in DRS-structure phase to achieve optimal Mn
2+
/Mn
4+
double-redox reaction in the composition system Li
2
Mn
x
Ti
1-x
O
2
F (1/3 ≤ x ≤ 1). Four different compositions (Li
2
Mn
III
O
2
F, Li
2
Mn
II
1/3
Mn
III
1/3
Ti
IV
1/3
O
2
F, Li
2
Mn
II
1/2
Ti
IV
1/2
O
2
F and Li
2
Mn
II
1/3
Ti
III
1/3
Ti
IV
1/3
O
2
F) have been synthesized and optimized according to the starting precursors and their oxidation states. By studying the electrochemical behavior of different compounds, we found that Ti
+4
keeps Mn at the second state of charge in the structure which lead to double redox reaction of Mn
2+
/Mn
4+
. Galvanostatic cycling and rate capability tests of the sample with the composition Li
2
Mn
2/3
Ti
1/3
O
2
F showed notable electrochemical kinetics and cycling performance, with initial high discharge capacity of 227 mAh g
-1
in the voltage window of 1.5-4.3 V and 82% coulombic efficiency after 100 cycles.In a further study, synthesis related issues and limitations due to fluorination were examined. In fact, lithium diffusion can be impeded due to preferable strong Li-F bonds. Thus, two more samples based on the Li
2
Mn
2/3
Ti
1/3
O
2
F composition were synthesized and their properties were investigated (Li
1.5
Mn
II
1/3
Mn
III
1/3
Ti
IV
1/3
O
2
F
0.5
and Li
1.25
Mn
II
1/3
Mn
III
1/3
Ti
IV
1/3
O
2
F
0.25
), in order to find the proper amount of fluorine which compromises the structural/chemical stability and electrochemical storage against Li-ions.We will present and discuss the structural characteristics of these selected DRS materials using XRD-Rietveld refinement analysis, energy-dispersive X-ray spectroscopy and scanning electron microscopy. The oxidation states and charge transfer mechanism using a combination of CV and XPS will be also addressed, in which the results approve the double redox mechanism of Mn
2+
/Mn
4+
in agreement with Mn-Ti structural charge compensation. The findings pave the way for designing high capacity electrode materials with multi-electron redox reactions.
Figure 1</description><issn>2151-2043</issn><issn>2151-2035</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqdj01LAzEQhoMoWKu_wMvcy9p87EI91lbxsgi295DdZDWabmQmrd0f4P82xSKePT3D8L4zPIxdC34jRHk7reeSS1FwUcpKbNKLaeiEjaSoRCG5qk5_51KdswuiN87VbCbliH2t46dBS3DnUnIIq2QaH3wawPQWnt3OIfnjJnZQ9yAnMM0oJ7CM2ya4HLJxD_M2-d0h5XtYeopoHbp8IbbvZEKCp_3QhW1Ebx0sTHqNmbXJL70JdMnOugx3deSYqYf79eKxaDESoev0B_qNwUELrg_G-sdY_zVW_2t9AyqrYsU</recordid><startdate>20210530</startdate><enddate>20210530</enddate><creator>Shirazimoghadam, Yasaman</creator><creator>El kharbachi, Abdel</creator><creator>Fichtner, Maximilian</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210530</creationdate><title>Towards Better Stability and Reversibility of Mn 2+ /Mn 4+ Double Redox Activity in Disordered Rocksalt Oxyfluoride Cathode Materials</title><author>Shirazimoghadam, Yasaman ; El kharbachi, Abdel ; Fichtner, Maximilian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-crossref_primary_10_1149_MA2021_014251mtgabs3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Shirazimoghadam, Yasaman</creatorcontrib><creatorcontrib>El kharbachi, Abdel</creatorcontrib><creatorcontrib>Fichtner, Maximilian</creatorcontrib><collection>CrossRef</collection><jtitle>Meeting abstracts (Electrochemical Society)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shirazimoghadam, Yasaman</au><au>El kharbachi, Abdel</au><au>Fichtner, Maximilian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Towards Better Stability and Reversibility of Mn 2+ /Mn 4+ Double Redox Activity in Disordered Rocksalt Oxyfluoride Cathode Materials</atitle><jtitle>Meeting abstracts (Electrochemical Society)</jtitle><date>2021-05-30</date><risdate>2021</risdate><volume>MA2021-01</volume><issue>4</issue><spage>251</spage><epage>251</epage><pages>251-251</pages><issn>2151-2043</issn><eissn>2151-2035</eissn><abstract>Recently discovered cation disordered rocksalt (DRS) materials have shown high reversibility towards Li ions due to facile insertion and extraction in the structure. Nonetheless, issues with manganese containing compounds have been identified due to instabilities of the structure and/or solubility of manganese in the electrolyte. In our study, we combined the use of high-valent cations with partial substitution of fluorine for oxygen anions in DRS-structure phase to achieve optimal Mn
2+
/Mn
4+
double-redox reaction in the composition system Li
2
Mn
x
Ti
1-x
O
2
F (1/3 ≤ x ≤ 1). Four different compositions (Li
2
Mn
III
O
2
F, Li
2
Mn
II
1/3
Mn
III
1/3
Ti
IV
1/3
O
2
F, Li
2
Mn
II
1/2
Ti
IV
1/2
O
2
F and Li
2
Mn
II
1/3
Ti
III
1/3
Ti
IV
1/3
O
2
F) have been synthesized and optimized according to the starting precursors and their oxidation states. By studying the electrochemical behavior of different compounds, we found that Ti
+4
keeps Mn at the second state of charge in the structure which lead to double redox reaction of Mn
2+
/Mn
4+
. Galvanostatic cycling and rate capability tests of the sample with the composition Li
2
Mn
2/3
Ti
1/3
O
2
F showed notable electrochemical kinetics and cycling performance, with initial high discharge capacity of 227 mAh g
-1
in the voltage window of 1.5-4.3 V and 82% coulombic efficiency after 100 cycles.In a further study, synthesis related issues and limitations due to fluorination were examined. In fact, lithium diffusion can be impeded due to preferable strong Li-F bonds. Thus, two more samples based on the Li
2
Mn
2/3
Ti
1/3
O
2
F composition were synthesized and their properties were investigated (Li
1.5
Mn
II
1/3
Mn
III
1/3
Ti
IV
1/3
O
2
F
0.5
and Li
1.25
Mn
II
1/3
Mn
III
1/3
Ti
IV
1/3
O
2
F
0.25
), in order to find the proper amount of fluorine which compromises the structural/chemical stability and electrochemical storage against Li-ions.We will present and discuss the structural characteristics of these selected DRS materials using XRD-Rietveld refinement analysis, energy-dispersive X-ray spectroscopy and scanning electron microscopy. The oxidation states and charge transfer mechanism using a combination of CV and XPS will be also addressed, in which the results approve the double redox mechanism of Mn
2+
/Mn
4+
in agreement with Mn-Ti structural charge compensation. The findings pave the way for designing high capacity electrode materials with multi-electron redox reactions.
Figure 1</abstract><doi>10.1149/MA2021-014251mtgabs</doi></addata></record> |
| fulltext | fulltext |
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| ispartof | Meeting abstracts (Electrochemical Society), 2021-05, Vol.MA2021-01 (4), p.251-251 |
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| source | IOP Publishing Free Content; Free Full-Text Journals in Chemistry |
| title | Towards Better Stability and Reversibility of Mn 2+ /Mn 4+ Double Redox Activity in Disordered Rocksalt Oxyfluoride Cathode Materials |
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